[Cd(4,4'-(isopropylidenebis(p-phenyleneoxy))diacetato)(H2O)2](n) | 1216883-10-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cd(4,4'-(isopropylidenebis(p-phenyleneoxy))diacetato)(H2O)2](n)
• CAS: 1216883-10-1
• 化学式: C₁₉H₂₂CdO₈
• 分子量: 490.789
• InChiKey: CBJKIBCTDVVZHR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Cd(4,4'-(isopropylidenebis(p-phenyleneoxy))diacetato)(H2O)2](n) 以 neat (no solvent) 为溶剂， 生成 cadmium(II) oxide
  参考文献：
  名称：

  Syntheses and structural characterization of three coordination polymers of Cd(II), Zn(II) and Pb(II) with the “V” shape ligand 4,4′-[isopropylidenebis(p-phenyleneoxy)]diacetic acid

  摘要：

  Three new inorganic-organic coordination polymers based on a "V" shape linking unit 4,4'-[isopropylidenebis(p-phenyleneoxy)]diaceticacid (H(2)L) and Cd(II), Zn(II) and Pb(II) ions, [Cd(L)(H(2)O)(2)](n) (1), [Zn(2)(L)(3)-(H(2)O)(6)center dot 6H(2)O](n) (2) and [Pb(2)Na(2)(L)(3)(DMF)(4)(H(2)O)(2)center dot 2H(2)O](n), (3), have been prepared and structurally characterized by single-crystal X-ray diffraction analysis. Complex 1 is a 1 D zig-zag chain coordination polymer, which is connected by strong hydrogen-bond interactions to result in a 3D network. In complex 2, an infinite 2D (6, 3) network with large hexagonal cavities was created. The whole 2D structure is a noninter-penetrating framework stacked by hydrogen-bonding interactions. Complex 3 is a novel 3D heterometallic coordination polymer, which possesses three different types of isolated channels. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.11.018
• 作为产物：
  描述：

  4,4'-异亚丙基二苯氧基乙酸 、 cadmium(II) acetate dihydrate 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 以40%的产率得到[Cd(4,4'-(isopropylidenebis(p-phenyleneoxy))diacetato)(H2O)2](n)
  参考文献：
  名称：

  Syntheses and structural characterization of three coordination polymers of Cd(II), Zn(II) and Pb(II) with the “V” shape ligand 4,4′-[isopropylidenebis(p-phenyleneoxy)]diacetic acid

  摘要：

  Three new inorganic-organic coordination polymers based on a "V" shape linking unit 4,4'-[isopropylidenebis(p-phenyleneoxy)]diaceticacid (H(2)L) and Cd(II), Zn(II) and Pb(II) ions, [Cd(L)(H(2)O)(2)](n) (1), [Zn(2)(L)(3)-(H(2)O)(6)center dot 6H(2)O](n) (2) and [Pb(2)Na(2)(L)(3)(DMF)(4)(H(2)O)(2)center dot 2H(2)O](n), (3), have been prepared and structurally characterized by single-crystal X-ray diffraction analysis. Complex 1 is a 1 D zig-zag chain coordination polymer, which is connected by strong hydrogen-bond interactions to result in a 3D network. In complex 2, an infinite 2D (6, 3) network with large hexagonal cavities was created. The whole 2D structure is a noninter-penetrating framework stacked by hydrogen-bonding interactions. Complex 3 is a novel 3D heterometallic coordination polymer, which possesses three different types of isolated channels. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.11.018