1-aminopyridinium perchlorate | 28460-20-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-aminopyridinium perchlorate
• 英文别名: N-aminopyridinium perchlorate；pyridin-1-ium-1-amine;perchlorate
• CAS: 28460-20-0
• 化学式: C₅H₇N₂*ClO₄
• 分子量: 194.575
• InChiKey: MMUOFIXPOAIOLD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -5.07
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  104
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1-aminopyridinium perchlorate 在 氧气 、 氧化亚氮 作用下， 以 乙腈 为溶剂， 反应 0.08h， 以90%的产率得到高氯酸,吡啶
  参考文献：
  名称：

  Radical Scavenging by N -Aminoazaaromatics

  摘要：

  N-Aminoazaaromatics were found to react with nitric oxide in the presence of oxygen to afford deaminated products in high yields. The reaction proceeded almost instantaneously in various solvents including water, and one to two equivalent of NO was consumed depending upon the amount of oxygen coexisted, and 1 equivalent of N2O was released in the reaction. In addition, N-aminoazoles were deaminated by potassium superoxide to give parent azoles in good yields. Two equivalents of superoxide was consumed, and about half equivalents of both nitrite and nitrate ion were released. The results demonstrated that N-aminoazoles have ability to protect the biological system against the oxidation promoted by radicals such as nitrogen oxides and superoxide. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0968-0896(00)00118-8
• 作为产物：
  描述：

  吡啶 在 hydroxylamine-O-sulfonic acid 、 高氯酸 作用下， 以 水 、 乙醇 为溶剂， 反应 3.0h， 以45%的产率得到1-aminopyridinium perchlorate
  参考文献：
  名称：

  用氧化还原活性胺捕获和释放电化学二氧化碳

  摘要：

  化石燃料燃烧产生的人为二氧化碳 (CO 2 ) 排放是全球气候变化和海洋酸化的主要原因。已经提议实施碳捕获和储存技术以减轻这种温室气体在大气中的积累。在这些技术中，直接空气捕获被认为是一种可行的 CO 2去除工具，可以实现净负排放。然而，由于在高浓度的分子氧和水的存在下CO 2的超稀浓度，从空气中分离CO 2特别具有挑战性。在这里，我们报告了一个强大的电化学氧化还原活性胺系统，展示了高电子利用率（即，摩尔 CO2 /摩尔电子）高达1.25，在水溶液中每个胺捕获两个CO 2分子，每摩尔CO 2的功为101 kJ e。直接从作为原料气的环境空气中捕获 CO 2的电子利用率为 0.78。

  DOI：

  10.1021/jacs.1c10656

文献信息

• Selective dimerizations of substituted N-aminopyridinium salts and their benzologs
  作者：S. Batori、G. Hajos、P. Sandor、A. Messmer

  DOI：10.1021/jo00274a020

  日期：1989.6
• Hanna; Girges, Arzneimittel-Forschung/Drug Research, 1994, vol. 44, # 1, p. 46 - 50
  作者：Hanna、Girges

  DOI：——

  日期：——
• KATRITZKY A. R.; SUWINSKI J. W., TETRAHEDRON <TETR-AB>, 1975, 31, NO 13-14, 1549-1556
  作者：KATRITZKY A. R.、 SUWINSKI J. W.

  DOI：——

  日期：——
• Gawinecki, R., Journal fuer Praktische Chemie (Leipzig), 1988, vol. 330, # 5, p. 759 - 765
  作者：Gawinecki, R.

  DOI：——

  日期：——
• Radical Scavenging by N -Aminoazaaromatics
  作者：Takashi Itoh、Michiko Miyazaki、Hiromi Maeta、Yûji Matsuya、Kazuhiro Nagata、Akio Ohsawa

  DOI：10.1016/s0968-0896(00)00118-8

  日期：2000.8

  N-Aminoazaaromatics were found to react with nitric oxide in the presence of oxygen to afford deaminated products in high yields. The reaction proceeded almost instantaneously in various solvents including water, and one to two equivalent of NO was consumed depending upon the amount of oxygen coexisted, and 1 equivalent of N2O was released in the reaction. In addition, N-aminoazoles were deaminated by potassium superoxide to give parent azoles in good yields. Two equivalents of superoxide was consumed, and about half equivalents of both nitrite and nitrate ion were released. The results demonstrated that N-aminoazoles have ability to protect the biological system against the oxidation promoted by radicals such as nitrogen oxides and superoxide. (C) 2000 Elsevier Science Ltd. All rights reserved.