bis(6-bromo-2-pyridyl)methane | 112575-16-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: bis(6-bromo-2-pyridyl)methane
• 英文别名: Bis(6-bromopyridin-2-yl)methane；2-bromo-6-[(6-bromopyridin-2-yl)methyl]pyridine
• CAS: 112575-16-3
• 化学式: C₁₁H₈Br₂N₂
• 分子量: 328.006
• InChiKey: AZUFZIHFAYSGDN-UHFFFAOYSA-N

物化性质

• 沸点：
  397.1±37.0 °C(Predicted)
• 密度：
  1.747±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(6-bromo-2-pyridyl)methane 在 selenium(IV) oxide 作用下， 以 溶剂黄146 为溶剂， 反应 22.0h， 以72%的产率得到双(6-溴吡啶-2-基)甲酮
  参考文献：
  名称：

  Nitrile-stabilized carbanions. Nucleophilic substitution reactions on bromopyridines

  摘要：

  DOI：

  10.1021/jo00239a018
• 作为产物：
  描述：

  bis(6-bromo-2-pyrydil)acetonitrile 在 盐酸 作用下， 以 乙醇 为溶剂， 反应 8.0h， 以81%的产率得到bis(6-bromo-2-pyridyl)methane
  参考文献：
  名称：

  Nitrile-stabilized carbanions. Nucleophilic substitution reactions on bromopyridines

  摘要：

  DOI：

  10.1021/jo00239a018

文献信息

• NEWKOME, GEORGE R.;JOO, YOUNG J.;EVANS, DAVID W.;PAPPALARDO, SEBASTIANO;F+, J. ORG. CHEM., 53,(1988) N 4, 786-790
  作者：NEWKOME, GEORGE R.、JOO, YOUNG J.、EVANS, DAVID W.、PAPPALARDO, SEBASTIANO、F+

  DOI：——

  日期：——
• Organic Electroluminescent Device
  申请人：Ise Toshihiro

  公开号：US20080001530A1

  公开（公告）日：2008-01-03

  An organic electroluminescent device having a pair of electrodes and at least one organic layer including a light-emitting layer interposed between the pair of electrodes, in which the organic layer contains at least one compound represented by formula (I): wherein Z 1 and Z 2 each independently represent a nitrogen-containing heterocycle coordinated with the platinum through a nitrogen atom; Q 1 and Q 2 each independently represent a group bonded with the platinum through a carbon atom, an oxygen atom, a sulfur atom, a nitrogen atom or a phosphorous atom; Q 1 and Q 2 each represent a structure different from each other; L 1 and L 2 each independently represent a single bond or a linking group; and n represents 0 or 1.
• PLATINUM COMPLEX COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Ise Toshihiro

  公开号：US20090128008A1

  公开（公告）日：2009-05-21

  An organic electroluminescent device is provided and has at least one organic layer between a pair of electrodes. The organic compound contains a compound represented by the following formula (I): Z 1 and Z 2 each represents a nitrogen-containing aromatic 6-membered ring coordinating to platinum atom at the nitrogen atom, Q represents a nitrogen-containing aromatic 5-membered ring having one or two nitrogen atoms, L 1 and L 2 each represents a single bond or a divalent group, and n represents 0 or 1.
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Murakami Takeshi

  公开号：US20090167157A1

  公开（公告）日：2009-07-02

  An organic electroluminescent device is provided and has an organic layer between a pair of electrodes, the organic layer containing a compound represented by formula (I). Z 1 and Z 2 each represent an atom group coordinating with palladium; Q represents a nitrogen-containing heterocycle; L 1 and L 2 each represent a single bond or a divalent linking group; and n is 0 or 1.
• LIGHT-EMITTING DEVICE
  申请人：ISE Toshihiro

  公开号：US20090309490A1

  公开（公告）日：2009-12-17

  An organic electroluminescent device having a pair of electrodes and at least one organic layer including a light-emitting layer interposed between the pair of electrodes, in which the organic layer contains at least one platinum complex compound having a quadridentate ligand containing a partial structure represented by formula (I): wherein Z 1 represents a nitrogen-containing heterocycle coordinated to the platinum through a nitrogen atom; L 1 represents a single bond or a linking group; R 1 , R 3 and R 4 each independently represent a hydrogen atom or a substituent; and R 2 represents a substituent.