[5,15-bis(ethynyl)-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc | 1200931-08-3

• 分子结构分类: 有机化合物
• 英文名称: [5,15-bis(ethynyl)-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc
• CAS: 1200931-08-3
• 化学式: C₈₄H₁₁₆N₄O₄Zn
• 分子量: 1311.26
• InChiKey: DTBALWLVJULACI-SJZYTJADSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  氯三己基硅烷 、 [5,15-bis(ethynyl)-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 6.25h， 以46%的产率得到[5-ethynyl-15-(trihexylsilanyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc
  参考文献：
  名称：

  Dye Sensitized Solar Cells: TiO₂ Sensitization with a Bodipy-Porphyrin Antenna System

  摘要：

  A zinc porphyrin derivative (2) and zinc porphyrin-bodipy dyad (3) have been prepared and applied to dye-sensitized solar cells (DSSCs). On the basis of absorption and fluorescence excitation spectra, dyad 3 efficiently (transfers energy from the bodipy to zinc porphyrin constituent. The 3-sensitized solar cell demonstrates higher solar spectral coverage, based oil incident photon to Current efficiency (IPCE) spectral and an improved power conversion efficiency (eta = 1.55%) compared to that of the 2-sensitized cell (eta = 0.84%). The better performance of the 3-sensitized cell is attributed largely to the gain in spectral absorbance provided by the bodipy constituent of 3. Also evident, however, are secondary effects reflecting (a) fill-factor improvement and (b) a slight gain in porphyrin red-edge absorbance due to bodipy-conjugate formation.

  DOI：

  10.1021/la9031927
• 作为产物：
  描述：

  [5,15-bis-[(trimethylsilanyl)ethynyl]-10,20-bis[2,6-di(dodecyloxy)phenyl]porphynato]zinc 在 四丁基氟化铵 作用下， 以