Methyl 2,6-dimethyltetradecanoate | 135756-66-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Methyl 2,6-dimethyltetradecanoate
• 英文别名: 2,6-Dimethyl-tetradecansaeuremethylester；Formyl 2,6-dimethyl-tetradecanoate
• CAS: 135756-66-0
• 化学式: C₁₇H₃₄O₂
• 分子量: 270.456
• InChiKey: GEHLQHHIWRFUCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  19
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-甲基-1-癸醇 在 氢氧化钾 、 lithium aluminium tetrahydride 、 triphenylphosphine dibromide 1:1 addition complex 作用下， 以 乙醚 、 乙醇 、 二氯甲烷 为溶剂， 生成 Methyl 2,6-dimethyltetradecanoate
  参考文献：
  名称：

  Identification of male-specific volatiles from nearctic and neotropical stink bugs (Heteroptera: Pentatomidae)

  摘要：

  Males of the Central American stink bug species, Euschistus obscurus, produce an attractant pheromone composed of a blend of compounds characteristic of North American Euschistus spp. and the South American soybean pest, E. heros. The range of E. obscurus extends into the southern United States, the species is easy to rear, and males produce an exceptionally large quantity of pheromone (>0.5 mug/day/male). These factors made E. obscurus useful for characterizing the novel pheromone components of E. heros without importing this pest species into the United States. Euschistus obscurus males produce methyl (2E,4Z)-decadienoate (61 %) in abundance, which is characteristic of North American species, and methyl 2,6,10-trimethyltridecanoate (27 %), the main male-specific ester of E. heros. The chirality of Euschistus spp. methyl-branched esters, and field activity of synthetic formulations, remain to be determined.

  DOI：

  10.1007/bf02059746

文献信息

• Identification of male-specific volatiles from nearctic and neotropical stink bugs (Heteroptera: Pentatomidae)
  作者：J. R. Aldrich、J. E. Oliver、W. R. Lusby、J. P. Kochansky、M. Borges

  DOI：10.1007/bf02059746

  日期：1994.5

  Males of the Central American stink bug species, Euschistus obscurus, produce an attractant pheromone composed of a blend of compounds characteristic of North American Euschistus spp. and the South American soybean pest, E. heros. The range of E. obscurus extends into the southern United States, the species is easy to rear, and males produce an exceptionally large quantity of pheromone (>0.5 mug/day/male). These factors made E. obscurus useful for characterizing the novel pheromone components of E. heros without importing this pest species into the United States. Euschistus obscurus males produce methyl (2E,4Z)-decadienoate (61 %) in abundance, which is characteristic of North American species, and methyl 2,6,10-trimethyltridecanoate (27 %), the main male-specific ester of E. heros. The chirality of Euschistus spp. methyl-branched esters, and field activity of synthetic formulations, remain to be determined.