(μ-N,N'-bis(4-pyridyl formamide)-1,4-benzene)silver(I)azide | 1359754-59-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (μ-N,N'-bis(4-pyridyl formamide)-1,4-benzene)silver(I)azide
• CAS: 1359754-59-8；1386996-42-4
• 化学式: Ag*C₁₈H₁₄N₄O₂*N₃
• 分子量: 468.223
• InChiKey: KIIHCNKOSIARMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.84
• 重原子数：
  28.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  142.68
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (μ-N,N'-bis(4-pyridyl formamide)-1,4-benzene)silver(I)azide 以 neat (no solvent) 为溶剂， 生成 银
  参考文献：
  名称：

  Solid state irreversible anion-exchange on one-dimensional silver(I) coordination polymer nanostructures

  摘要：

  A new one-dimensional silver(I) coordination polymer [Ag(mu-bpfb)(NO3)](n) (1), bpfb = N, N'-bis(4-pyridylformamide)-1,4-benzene, has been synthesized and characterized by IR, NMR spectroscopy and single crystal X-ray crystallography. Nanorods compound 1 were obtained by sonochemical process and characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The nitrate ions of compound 1 in nanostructure exchange with perchlorate, thiocyanate and azide anions by the solid state reaction. Three new compounds [Ag(mu-bpfb)(ClO4)](n) (2), [Ag(mu-bpfb)(SCN)](n) (3) and [Ag(mu-bpfb)(N-3)](n) (4), were characterized by IR spectroscopy, X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The silver nanoparticles were obtained from direct calcination of compounds 1-4 nanostructures in an electrical furnace at 673 K. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.12.032
• 作为产物：
  描述：

  N,N’-(1,4-亚苯基)二异烟酰胺 以 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 生成 (μ-N,N'-bis(4-pyridyl formamide)-1,4-benzene)silver(I)azide
  参考文献：
  名称：

  Solid state irreversible anion-exchange on one-dimensional silver(I) coordination polymer nanostructures

  摘要：

  A new one-dimensional silver(I) coordination polymer [Ag(mu-bpfb)(NO3)](n) (1), bpfb = N, N'-bis(4-pyridylformamide)-1,4-benzene, has been synthesized and characterized by IR, NMR spectroscopy and single crystal X-ray crystallography. Nanorods compound 1 were obtained by sonochemical process and characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The nitrate ions of compound 1 in nanostructure exchange with perchlorate, thiocyanate and azide anions by the solid state reaction. Three new compounds [Ag(mu-bpfb)(ClO4)](n) (2), [Ag(mu-bpfb)(SCN)](n) (3) and [Ag(mu-bpfb)(N-3)](n) (4), were characterized by IR spectroscopy, X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The silver nanoparticles were obtained from direct calcination of compounds 1-4 nanostructures in an electrical furnace at 673 K. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.12.032