4-(norborn-5-en-2-yl)butanoic acid | 6707-06-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4-(norborn-5-en-2-yl)butanoic acid
• 英文别名: 5-Norbornen-2-buttersaeure；4-{Bicyclo[2.2.1]hept-5-en-2-yl}butanoic acid；4-(2-bicyclo[2.2.1]hept-5-enyl)butanoic acid
• CAS: 6707-06-8
• 化学式: C₁₁H₁₆O₂
• 分子量: 180.247
• InChiKey: ORMSKUPWIJWKPT-UHFFFAOYSA-N

物化性质

• 沸点：
  312.8±11.0 °C(Predicted)
• 密度：
  1.100±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(norborn-5-en-2-yl)butanoic acid 在 硫酸 作用下， 反应 20.0h， 以0.15 g的产率得到4-(2-exo-hydroxynorborn-2-endo-yl)butyric acid spiro-δ-lactone
  参考文献：
  名称：

  Sadikun, Amirin bin; Davies, David I., Journal of the Chemical Society. Perkin transactions I, 1982, # 10, p. 2461 - 2466

  摘要：

  DOI：
• 作为产物：
  描述：

  3-(norborn-5-en-2-yl)propyl cyanide 在 氢氧化钾 作用下， 反应 60.0h， 以73%的产率得到4-(norborn-5-en-2-yl)butanoic acid
  参考文献：
  名称：

  Sadikun, Amirin bin; Davies, David I., Journal of the Chemical Society. Perkin transactions I, 1982, # 10, p. 2461 - 2466

  摘要：

  DOI：

文献信息

• Fluorine free photopatternable phenol functional group containing polymer compositions
  申请人：PROMERUS, LLC

  公开号：US10054854B2

  公开（公告）日：2018-08-21

  Various polycycloolefinic polymers containing phenolic pendent groups and compositions thereof useful for forming self-imageable films encompassing such polymers are disclosed. Such polymers encompass norbornene-type repeating units containing phenolic pendent groups which contain very low levels of fluorine containing monomers. The films formed from such polymer compositions provide self imageable, low-k, thermally stable layers for use in microelectronic and optoelectronic devices.

  本发明公开了各种含酚醛悬垂基团的聚环烯烃聚合物及其用于形成包含此类聚合物的自成像薄膜的组合物。此类聚合物包含降冰片烯类重复单元，其中含有含氟单体含量极低的酚醛悬垂基团。由此类聚合物组合物形成的薄膜具有自成像、低 K 值、热稳定的特性，可用于微电子和光电设备。
• Nadic anhydride polymers and photosensitive compositions derived therefrom
  申请人：PROMERUS, LLC

  公开号：US10591818B2

  公开（公告）日：2020-03-17

  Various vinyl addition polymers of nadic anhydride are disclosed. Examples of such polymers include copolymers and terpolymers of nadic anhydride with a wide variety of norbornene-type monomers. The nadic anhydride polymers are found to be useful in forming a wide variety of photosensitive compositions, both positive and negative, which are capable of forming high resolution imagable films exhibiting excellent dielectric properties (low-k) and thermal properties, and thus are useful in the fabrication of a variety of microelectronic and optoelectronic devices, among others.

  本文公开了纳丁酸酐的各种乙烯基加成聚合物。此类聚合物的例子包括纳丁酸酐与各种降冰片烯类单体的共聚物和三元共聚物。我们发现萘酸酐聚合物可用于形成各种光敏组合物，包括正性和负性组合物，这些组合物能够形成高分辨率的可成像薄膜，表现出优异的介电性能（低 K 值）和热性能，因此可用于制造各种微电子和光电设备等。
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof
  申请人：Imuta Junichi

  公开号：US20090137757A1

  公开（公告）日：2009-05-28

  A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
• METHOD FOR PURIFYING POLYMER AND POLYMER
  申请人：Sunaga Tadahiro

  公开号：US20120208976A1

  公开（公告）日：2012-08-16

  Disclosed is a method for purifying a polymer in which a solution containing a cyclic olefin polymer having at least a repeating structural unit [A] represented by the general formula (1) and a metal component is brought into contact with an organic compound having a basic functional group and an acidic functional group, and then the resulting solution is brought into contact with a basic adsorbent to remove the metal component contained in the solution.
• FLUORINE FREE PHOTOPATTERNABLE PHENOL FUNCTIONAL GROUP CONTAINING POLYMER COMPOSITIONS
  申请人：PROMERUS, LLC

  公开号：US20170097566A1

  公开（公告）日：2017-04-06

  Various polycycloolefinic polymers containing phenolic pendent groups and compositions thereof useful for forming self-imageable films encompassing such polymers are disclosed. Such polymers encompass norbornene-type repeating units containing phenolic pendent groups which contain very low levels of fluorine containing monomers. The films formed from such polymer compositions provide self imageable, low-k, thermally stable layers for use in microelectronic and optoelectronic devices.