ReH3{PMe2Ph}4 | 79245-24-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ReH3{PMe2Ph}4
• CAS: 79245-24-2
• 化学式: C₃₂H₄₇P₄Re
• 分子量: 741.827
• InChiKey: ZHUDZZSOCAUBGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.41
• 重原子数：
  37.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  ReH3{PMe2Ph}4 在 氢气 作用下， 以 异辛烷 为溶剂， 生成 ReH7(PMe2Ph)3
  参考文献：
  名称：

  在主要的光化学反应中不能消除H 2的多元醇配合物的确定性例子。PR 3从[ReH 3（PR 3）4 ]和[ReH 5（PR 3）3 ]络合物中光解离

  摘要：

  与大多数单体相反，对复合物[ReH 5 L 3 ]（LPMe 2 Ph，PMePh 2，PPh 3）和[ReH 3（PMe 2 Ph）4 ]进行辐照可在初级光化学反应中有效地损失磷化氢。在光解过程中会损失H 2的多羟基配合物。[ReH 5 L 3 ]配合物的366 nm量子产率为0.13-0.18；[ReH 3（PMe 2 Ph）4 ]引起的PMe 2 Ph损失的366 nm量子产率为0.4。在H 2气氛下，[ReH 3（PMe 2 Ph）4 ]在光解后转化为[ReH 5（PMe 2 Ph）3 ]；五氢化物又损失另一当量的膦，得到相应的[ReH 7 L 2 ]配合物。七氢化物本身是光敏的，并反应生成[Re 2 H 8 L 4 ]和[Re 2 H 6 L 5二聚体的混合物。[ReH 5 L 2 ]络合物脱气溶液的光解导致[ReH 7 L 2 ]，[ReH 3L 4，[Re 2 H 8 L 4

  DOI：

  10.1016/s0022-328x(00)86632-2
• 作为产物：
  描述：

  在 dibutylamine 作用下， 以 乙腈 为溶剂， 生成 ReH3{PMe2Ph}4
  参考文献：
  名称：

  Kristjánsdóttir, S. Sóley; Loendorf, Amy J.; Norton, Jack R., Inorganic Chemistry, 1991, vol. 30, # 23, p. 4470 - 4471

  摘要：

  DOI：

文献信息

• N-bonded enolatorhenium(I) complexes having dimethylphenylphosphine ligands as active key intermediates in catalytic Knoevenagel and Michael reactions
  作者：Masafumi Hirano、Miwa Hirai、Yuji Ito、Tsutomu Tsurumaki、Atsushi Baba、Atsushi Fukuoka、Sanshiro Komiya

  DOI：10.1016/s0022-328x(98)00768-2

  日期：1998.10

  Enolatorhenium(I) complexes cis-Re(NCCRCO2R')(NCCHRCO2R')(PMe2Ph)(4) (R = H, R' = Me (2a); R = H, R' = Et (2b); R = H, R' = n-Bu (2c); R = Me, R' = Et (2d)) are prepared by the reaction of ReH(N-2)(PMe2Ph)(4) (1) with alkyl cyanoalkyl carboxylate. X-ray structure analysis of 2b shows that it has an octahedral Re geometry, where mutually cis enolato and ester ligands bind to the rhenium via cyano groups. Reaction of 2b with benzaldehyde gives Re(NCCHCO3Et)[NC(EtO2C)C-CHPh]-(PMe2Ph)(4) (4), which is also derived from the ligand exchange reaction of 2b with ethyl (E)-2-cyano-3-phenylpropenoate. These rhenium(I) complexes 1, 2, and 4 catalyze Knoevenagel and Michael reactions under neutral and mild conditions. A possible mechanism for the Knoevenagel reaction has been proposed. (C) 1998 Elsevier Science S.A. All rights reserved.
• Synthesis and structure of hydridobis(ethylene) and hydrido dinitrogen complexes of rhenium(I) having dimethylphenylphosphine ligands
  作者：Sanshiro Komiya、Atsushi Baba

  DOI：10.1021/om00055a024

  日期：1991.9

  mer-Hydridobis(ethylene)tris(dimethylphenylphosphine)rhenium(I) (1) and cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I) (2) have been prepared by the reaction of mer-trichlorotris(dimethylphenylphosphine)rhenium(I) with ethyllithium and n-propyllithium, respectively. X-ray structure analysis reveals that both complexes are octahedral, and in the former complex the two coordinated ethylenes occupy sites perpendicular to each other in cis positions and in the latter complex hydrido and dinitrogen ligands in cis positions. The coordinated ethylene and dinitrogen can be smoothly displaced by dihydrogen to give known trihydrido- or pentahydridorhenium complexes. Crystal data for 1: space group P1BAR, Z = 2, a = 9.285 (3) angstrom, b = 19.229 (5) angstrom, c = 9.044 (3) angstrom, alpha = 93.47 (3)-degrees, beta = 120.16 (2)-degrees, gamma = 90.23 (3)-degrees, V = 1392.5 (8) angstrom 3 , R = 0.0653, R(w) = 0.0641, based on 3959 reflections with F > 3-sigma(F). Crystal data for 2: space group P2(1)/a, Z = 4, a = 27.49 (1) angstrom, b = 10.113 (2) angstrom, c = 12.235 (6) angstrom, beta = 91.94 (4)-degrees, V = 3424 (2) angstrom 3, R = 0.0464, R(w) = 0.0533, based on 4129 reflections with F > 3-sigma(F).
• Lunder, Diane M.; Green, Mark A.; Streib, William E., Inorganic Chemistry, 1989, vol. 28, # 25, p. 4527 - 4531
  作者：Lunder, Diane M.、Green, Mark A.、Streib, William E.、Caulton, Kenneth G.

  DOI：——

  日期：——