Co(4,4'-diethyl-3,3',5,5'-tetramethyl-2,2'-dipyrrolylmethene(-1H))2 | 106847-17-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Co(4,4'-diethyl-3,3',5,5'-tetramethyl-2,2'-dipyrrolylmethene(-1H))2
• CAS: 106847-17-0
• 化学式: C₃₄H₄₆CoN₄
• 分子量: 569.759
• InChiKey: OPRWVTMRWWTACP-KNGYMQEQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) acetate 、 1,3,7,9-tetramethyl-2,8-diethyl-4,6-dipyrrin hydrobromide 以 乙醇 、 氨 为溶剂， 生成 Co(4,4'-diethyl-3,3',5,5'-tetramethyl-2,2'-dipyrrolylmethene(-1H))2
  参考文献：
  名称：

  Johnson, A. W.; Kay, J. T.; Markham, E., Journal of the Chemical Society

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: SVol.B1, 24, page 50 - 53
  作者：

  DOI：——

  日期：——
• Trends in formation and stability of homo- and heteroligand d-metal complexes with 2,2′-dipyrrolylmethenes in dimethylformamide
  作者：E. V. Rumyantsev、A. Desoki、E. V. Antina

  DOI：10.1134/s0036023609110084

  日期：2009.11

  The reactions of symmetric and nonsymmetric alkyl-substituted 2,2'-dipyrrolylmethenes with Cu(II), Ni(II), Co(II), Zn(II), Cd(II), and Hg(II) acetates in dimethylformamide solutions at 298.15 K were studied. The formation of hetero- and homoligand complexes was observed in the systems studied depending on the concentration conditions and the nature of the complexing metal. The stepped and complete constants of formation for metal complexes were determined. The key trends of the influence of the metal and ligand nature on the stabilization of the complexes were established.