triethylammonium aqua[2,2'-(3,6-dioxaoctane-1,8-diyldioxy)diphenolato-κ2-O,O']-(nitrato-κ2-O,O')dioxouranium(VI) | 429674-27-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: triethylammonium aqua[2,2'-(3,6-dioxaoctane-1,8-diyldioxy)diphenolato-κ2-O,O']-(nitrato-κ2-O,O')dioxouranium(VI)
• CAS: 429674-27-1
• 化学式: C₆H₁₆N*C₁₈H₂₂NO₁₂U
• 分子量: 784.601
• InChiKey: RLBJHUJDHRNGLK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  uranyl nirate hexahydrate 、 1,8-bis(2-hydroxyphenoxy)-3,6-dioxaoctane 、 三乙胺 以 氯仿 、 乙腈 为溶剂， 生成 triethylammonium aqua[2,2'-(3,6-dioxaoctane-1,8-diyldioxy)diphenolato-κ2-O,O']-(nitrato-κ2-O,O')dioxouranium(VI)
  参考文献：
  名称：

  First- and second- sphere coordination of the uranyl ion by bis[2-(2-hydroxyphenoxy)ethoxy]ethane

  摘要：

  Uranyl nitrate hexahydrate reacts with bis[2-(2-hydroxyphenoxy)ethoxy]ethane (C18H22O6), denoted LH2 hereafter, in the presence of triethylamine to give triethylammonium aqua[2,2'-(3,6-dioxaoctane-1,8-diyldioxy)diphenolato-kappa(2)O,O']-(nitrato-kappa(2) O,O')dioxouranium(VI), (Et3NH)[UO2(H2O)L-(NO3)], which possesses a symmetry plane. The uranyl ion is coordinated to the two phenoxide O atoms, a nitrate ion and a water molecule (first sphere); the water molecule is itself held in the crown ether chain by hydrogen-bonding interactions, thus ensuring second-sphere coordination by the ligand L.

  DOI：

  10.1107/s0108270101019047