[3',6'-Bis(4-tert-butylphenyl)-10-tri(propan-2-yl)silylspiro[3,11-dithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene-7,9'-fluorene]-4-yl]-tri(propan-2-yl)silane | 1415888-28-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: [3',6'-Bis(4-tert-butylphenyl)-10-tri(propan-2-yl)silylspiro[3,11-dithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene-7,9'-fluorene]-4-yl]-tri(propan-2-yl)silane
• 英文别名: [3',6'-bis(4-tert-butylphenyl)-10-tri(propan-2-yl)silylspiro[3,11-dithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene-7,9'-fluorene]-4-yl]-tri(propan-2-yl)silane
• CAS: 1415888-28-6
• 化学式: C₅₉H₇₆S₂Si₂
• 分子量: 905.555
• InChiKey: FNZFCMXMQMVAPZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.85
• 重原子数：
  63
• 可旋转键数：
  12
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [3',6'-Bis(4-tert-butylphenyl)-10-tri(propan-2-yl)silylspiro[3,11-dithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene-7,9'-fluorene]-4-yl]-tri(propan-2-yl)silane 在 N-溴代丁二酰亚胺(NBS) 、 四丁基氟化铵 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  A Novel Amine-Free Dianchoring Organic Dye for Efficient Dye-Sensitized Solar Cells

  摘要：

  An amine-free oligothiophene-based dye (BTB) featuring a tailor-made dianchoring function, a spiro-configured central unit, and bulky end-capping TIPS groups to diminish intermolecular interactions and to suppress aggregation-induced self-quenching was synthesized to achieve efficient dye-sensitized solar cells with a high power conversion efficiency of 6.52%.

  DOI：

  10.1021/ol303121z
• 作为产物：
  描述：

  (3,3'-dibromo-[2,2'-bithiophene]-5,5'-diyl)bis(triisopropylsilane) 在 正丁基锂 、 溶剂黄146 作用下， 以 四氢呋喃 为溶剂， 反应 5.5h， 生成 [3',6'-Bis(4-tert-butylphenyl)-10-tri(propan-2-yl)silylspiro[3,11-dithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene-7,9'-fluorene]-4-yl]-tri(propan-2-yl)silane
  参考文献：
  名称：

  A Novel Amine-Free Dianchoring Organic Dye for Efficient Dye-Sensitized Solar Cells

  摘要：

  An amine-free oligothiophene-based dye (BTB) featuring a tailor-made dianchoring function, a spiro-configured central unit, and bulky end-capping TIPS groups to diminish intermolecular interactions and to suppress aggregation-induced self-quenching was synthesized to achieve efficient dye-sensitized solar cells with a high power conversion efficiency of 6.52%.

  DOI：

  10.1021/ol303121z

文献信息

• A Novel Amine-Free Dianchoring Organic Dye for Efficient Dye-Sensitized Solar Cells
  作者：Hao-Chun Ting、Chih-Hung Tsai、Jia-Hong Chen、Li-Yen Lin、Shu-Hua Chou、Ken-Tsung Wong、Tsung-Wei Huang、Chung-Chih Wu

  DOI：10.1021/ol303121z

  日期：2012.12.21

  An amine-free oligothiophene-based dye (BTB) featuring a tailor-made dianchoring function, a spiro-configured central unit, and bulky end-capping TIPS groups to diminish intermolecular interactions and to suppress aggregation-induced self-quenching was synthesized to achieve efficient dye-sensitized solar cells with a high power conversion efficiency of 6.52%.