[3-di(propan-2-yl)phosphanylphenyl]-triphenylboranuide;tetrabutylazanium | 651329-77-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [3-di(propan-2-yl)phosphanylphenyl]-triphenylboranuide;tetrabutylazanium
• CAS: 651329-77-0
• 化学式: C₁₆H₃₆N*C₃₀H₃₃BP
• 分子量: 677.845
• InChiKey: NGRKCMOTJHVDSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.99
• 重原子数：
  49.0
• 可旋转键数：
  19.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  (1,5-cyclooctadiene)dimethylplatinum(II) 、 [3-di(propan-2-yl)phosphanylphenyl]-triphenylboranuide;tetrabutylazanium 以 not given 为溶剂， 生成 (NBu4)2((Ph3BP(m-iPr2))2PtMe2)
  参考文献：
  名称：

  Coordinating Anions:  (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis

  摘要：

  Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis. This report describes the synthesis of a new class of monodentate tertiary phosphines built upon the commonly employed tetraphenylborate anion. These new phosphines are highly stable and strongly electron-releasing and readily coordinate transition metals. Moreover, they are promising reagents for catalysis, as demonstrated by their ability to promote the Suzuki cross-coupling of aryl chloride substrates.

  DOI：

  10.1021/ic0350234
• 作为产物：
  描述：

  四氢呋喃 、 (3-Bromophenyl)di(propan-2-yl)phosphane 、 三苯基硼烷 、 四丁基溴化铵 、 叔丁基锂 以 四氢呋喃 为溶剂， 生成 [3-di(propan-2-yl)phosphanylphenyl]-triphenylboranuide;tetrabutylazanium
  参考文献：
  名称：

  Coordinating Anions:  (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis

  摘要：

  Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis. This report describes the synthesis of a new class of monodentate tertiary phosphines built upon the commonly employed tetraphenylborate anion. These new phosphines are highly stable and strongly electron-releasing and readily coordinate transition metals. Moreover, they are promising reagents for catalysis, as demonstrated by their ability to promote the Suzuki cross-coupling of aryl chloride substrates.

  DOI：

  10.1021/ic0350234