| 183323-85-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 183323-85-5
• 化学式: C₄H₈O*C₅₈H₅₄CuLiN₂O₄P₂S₂
• 分子量: 1111.75
• InChiKey: YDRZGMZJHAROJB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 copper dichloride 以 四氢呋喃 为溶剂， 以56%的产率得到1,3-benzoxazole-2-thiolate;copper(1+);triphenylphosphane
  参考文献：
  名称：

  Role of bifunctional N/S bridging in the association of metals; syntheses and structures of heterobimetallic [Ph₃P)₂CuL₂Li(thf)₂]·thf and tetrameric [{CuL(PPh₃)}₄](L = 1,3-benzoxazoline-2-thionate, thf = tetrahydrofuran)

  摘要：

  Nucleophilic substitution of the cp (eta-C5H5) ligand of [Cu(cp)(PPh(3))] with LiL (L = 1,3-benzoxazoline-2-thionate) gave the heterobimetallic complex [(Ph(3)P)(2)CuL(2)Li(thf)(2)]. thf 1 (thf = tetrahydrofuran), the ligand-transfer reaction of which with CuCl2 generated the tetrameric cage complex [{CuL(PPh(3))}(4)] 2. The crystal structures of these complexes revealed that the association of the metal centres occurs by a variety of ligand co-ordination modes (mu-S, N; N, mu-S; mu(3)-S). Electrochemical measurements have been used to probe the nature of the species present in solution.

  DOI：

  10.1039/dt9960003793
• 作为产物：
  描述：

  正丁基锂 、 四氢呋喃 、 2-巯基苯并恶唑 、 copper(1+);cyclopenta-1,3-diene;triphenylphosphane 以 四氢呋喃 、 正己烷 为溶剂， 以24%的产率得到
  参考文献：
  名称：

  Role of bifunctional N/S bridging in the association of metals; syntheses and structures of heterobimetallic [Ph₃P)₂CuL₂Li(thf)₂]·thf and tetrameric [{CuL(PPh₃)}₄](L = 1,3-benzoxazoline-2-thionate, thf = tetrahydrofuran)

  摘要：

  Nucleophilic substitution of the cp (eta-C5H5) ligand of [Cu(cp)(PPh(3))] with LiL (L = 1,3-benzoxazoline-2-thionate) gave the heterobimetallic complex [(Ph(3)P)(2)CuL(2)Li(thf)(2)]. thf 1 (thf = tetrahydrofuran), the ligand-transfer reaction of which with CuCl2 generated the tetrameric cage complex [{CuL(PPh(3))}(4)] 2. The crystal structures of these complexes revealed that the association of the metal centres occurs by a variety of ligand co-ordination modes (mu-S, N; N, mu-S; mu(3)-S). Electrochemical measurements have been used to probe the nature of the species present in solution.

  DOI：

  10.1039/dt9960003793