[(3,5-di-tert-butylpyrazolato)AlCl(3,5-di-tert-butyl-N-CHC(SiMe3)-pyrazolato)] | 356784-41-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [(3,5-di-tert-butylpyrazolato)AlCl(3,5-di-tert-butyl-N-CHC(SiMe3)-pyrazolato)]
• 英文别名: chloroaluminum(2+);3,5-ditert-butylpyrazol-2-ide;2-(3,5-ditert-butylpyrazol-1-yl)ethenyl-trimethylsilane
• CAS: 356784-41-3
• 化学式: C₂₇H₄₈AlClN₄Si
• 分子量: 519.225
• InChiKey: AHSWQWWCUCMOLE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(η1,η1-3,5-tBu2pz)(μ-Al)Cl2]2 以 甲苯 为溶剂， 生成 [(3,5-di-tert-butylpyrazolato)AlCl(3,5-di-tert-butyl-N-CHC(SiMe3)-pyrazolato)]
  参考文献：
  名称：

  An Unusual Monomeric Alkenyl-Substituted Pyrazolato Aluminum Dichloride and Its Derivatives with Both Terminal and η²-Pyrazolato Ligands

  摘要：

  The facile formation of the unusual monomeric alkenyl-substituted pyrazolato aluminum dichloride [(3,5-Bu-t(2)-N-CH=C(SiMe3)-pz)AlCl2] (2; 3,5-(t)Bu(2)pz = 3,5-di-tert-butylpyrazolato) was achieved in high yield by reacting dimeric pyrazolato aluminum dichloride [eta (1)-eta (1)-3,5-(t)Bu(2)pz(mu -Al)Cl-2](2) (1) with 2 equiv of trimethylsilylethine. The addition of 1 and 2 equiv of K[3,5-(t)Bu(2)pz] to 2, respectively, resulted in the formation of two novel complexes, [(3,5-Bu-t(2)-N-CH=C(SiMe3)-pz)AlCl(3,5-(t)Bu(2)pz)] (3) and [(3,5-Bu-t(2)-N-CH=C(SiMe3)-pz)Al(eta (1)-3,5-(t)Bu(2)pz)(eta (2)-3,5-(t)Bu(2)pz)] (4), for which crystallographic data are presented. The coordination of the pyrazolato ligand in 3 represents an extreme example of a "slipped" eta (2)-coordination.

  DOI：

  10.1021/om010271y