4-{4-[4-(4-tert-Butyl-phenoxy)-benzenesulfonyl]-phenoxy}-phenol | 917868-82-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-{4-[4-(4-tert-Butyl-phenoxy)-benzenesulfonyl]-phenoxy}-phenol
• 英文别名: 4-{4-[4-(4-tert-Butylphenoxy)benzene-1-sulfonyl]phenoxy}phenol；4-[4-[4-(4-tert-butylphenoxy)phenyl]sulfonylphenoxy]phenol
• CAS: 917868-82-7
• 化学式: C₂₈H₂₆O₅S
• 分子量: 474.577
• InChiKey: PXVJCATZNSUGNW-UHFFFAOYSA-N

物化性质

• 沸点：
  623.8±55.0 °C(Predicted)
• 密度：
  1.235±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  34
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  81.2
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-fluoro-4'-(4''-methoxyphenyloxy)diphenyl sulfone 、 4-{4-[4-(4-tert-Butyl-phenoxy)-benzenesulfonyl]-phenoxy}-phenol 在 potassium carbonate 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 4.0h， 以94%的产率得到1-(tert-butyl)-4-(4-((4-(4-(4-((4-(4-methoxyphenoxy)phenyl)sulfonyl)phenoxy)phenoxy)phenyl)sulfonyl)phenoxy)benzene
  参考文献：
  名称：

  Self-Assembled Lamellar Nanostructures of Wholly Aromatic Rod−Rod-Type Block Molecules

  摘要：

  Wholly aromatic rod-rod type di- and triblock molecules, oligo(ether sulfone)-b-oligo(ether ketone)s (OES-OEK), were synthesized to study a solid-state self-assembled nanostructure. The OES and OEK segments in the block molecules form segregated crystalline domains. The energy-filtering transmission electron microscopy images revealed that the di- and triblock OES-OEK co-oligomers formed lamellar nanostructures with a periodicity of similar to 9 and 13 nm, respectively.

  DOI：

  10.1021/ol061929c
• 作为产物：
  描述：

  4,4'-二氟二苯砜 在 三溴化硼 、 potassium carbonate 作用下， 以 二氯甲烷 、 N,N-二甲基乙酰胺 为溶剂， 反应 13.0h， 生成 4-{4-[4-(4-tert-Butyl-phenoxy)-benzenesulfonyl]-phenoxy}-phenol
  参考文献：
  名称：

  Self-Assembled Lamellar Nanostructures of Wholly Aromatic Rod−Rod-Type Block Molecules

  摘要：

  Wholly aromatic rod-rod type di- and triblock molecules, oligo(ether sulfone)-b-oligo(ether ketone)s (OES-OEK), were synthesized to study a solid-state self-assembled nanostructure. The OES and OEK segments in the block molecules form segregated crystalline domains. The energy-filtering transmission electron microscopy images revealed that the di- and triblock OES-OEK co-oligomers formed lamellar nanostructures with a periodicity of similar to 9 and 13 nm, respectively.

  DOI：

  10.1021/ol061929c

文献信息

• Self-Assembled Lamellar Nanostructures of Wholly Aromatic Rod−Rod-Type Block Molecules
  作者：Teruaki Hayakawa、Raita Goseki、Masa-aki Kakimoto、Masatoshi Tokita、Junji Watanabe、Yonngui Liao、Shin Horiuchi

  DOI：10.1021/ol061929c

  日期：2006.11.1

  Wholly aromatic rod-rod type di- and triblock molecules, oligo(ether sulfone)-b-oligo(ether ketone)s (OES-OEK), were synthesized to study a solid-state self-assembled nanostructure. The OES and OEK segments in the block molecules form segregated crystalline domains. The energy-filtering transmission electron microscopy images revealed that the di- and triblock OES-OEK co-oligomers formed lamellar nanostructures with a periodicity of similar to 9 and 13 nm, respectively.