tris-(2-N-benzyl-N-methylaminoethyl)amine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris-(2-N-benzyl-N-methylaminoethyl)amine
• 英文别名: tris(N-benzyl-N-methylaminoethyl)amine；N-benzyl-N',N'-bis[2-[benzyl(methyl)amino]ethyl]-N-methylethane-1,2-diamine
• 化学式: C₃₀H₄₂N₄
• 分子量: 458.69
• InChiKey: BZTQITJQNZUYOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  34
• 可旋转键数：
  15
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tris-(2-N-benzyl-N-methylaminoethyl)amine 在 palladium dihydroxide 氢气 作用下， 以 甲醇 为溶剂， 反应 20.0h， 以90%的产率得到三[2-(甲基氨基)乙基]胺
  参考文献：
  名称：

  Covalently supported porphyrins as ligands for the preparation of heme a3/CuB binuclear active site analogues of heme–copper terminal oxidases and metallation under mild conditions

  摘要：

  新型共价支撑的双核卟啉已被制备，作为血红素-铜氧化酶中铁-铜（血红素a3/CuB）活性位点的潜在结构和/或功能配体，并且在温和反应条件下将铁和铜引入一个卟啉的工艺已被开发。

  DOI：

  10.1039/a707785h
• 作为产物：
  描述：

  聚合甲醛 、 tris(2-benzylaminoethyl)amine 在 甲酸 作用下， 反应 12.0h， 以76%的产率得到tris-(2-N-benzyl-N-methylaminoethyl)amine
  参考文献：
  名称：

  Covalently supported porphyrins as ligands for the preparation of heme a3/CuB binuclear active site analogues of heme–copper terminal oxidases and metallation under mild conditions

  摘要：

  新型共价支撑的双核卟啉已被制备，作为血红素-铜氧化酶中铁-铜（血红素a3/CuB）活性位点的潜在结构和/或功能配体，并且在温和反应条件下将铁和铜引入一个卟啉的工艺已被开发。

  DOI：

  10.1039/a707785h

文献信息

• Near infrared ray absorbent composition, near infrared ray cut filter, solid image pickup element, and camera module
  申请人：FUJIFILM Corporation

  公开号：US10215898B2

  公开（公告）日：2019-02-26

  Provided are a near infrared ray absorbent composition which can form a cured film having excellent near infrared ray shielding properties, a near infrared ray cut filter, a manufacturing method of a near infrared ray cut filter, a solid image pickup element, and a camera module. The near infrared ray absorbent composition includes a copper complex that is other than a copper phthalocyanine complex and has a maximum absorption wavelength in a wavelength range of 700 to 1,200 nm and in which a molar light absorption coefficient at the maximum absorption wavelength is greater than or equal to 100 (L/mol·cm).

  提供了一种近红外线吸收组合物，可以形成具有优异近红外线屏蔽性能的固化膜，一种近红外线切割滤光片，一种近红外线切割滤光片的制造方法，一种固态图像拾取元件和一种摄像头模块。该近红外线吸收组合物包括一种铜络合物，该铜络合物不同于铜酞菁络合物，在波长范围为700至1,200纳米的范围内具有最大吸收波长，并且在最大吸收波长处的摩尔光吸收系数大于或等于100（L/mol·cm）。
• Nitritereduction by copper complexes
  作者：John G. Woollard-Shore、Jason P. Holland、Michael W. Jones、Jonathan R. Dilworth

  DOI：10.1039/b913463h

  日期：——

  nitrogen atoms, catalytic studies on the conversion of NO2− anions into NO and N2O gases revealed an excellent correlation between the initial rate of conversion and the experimental reduction potential as measured by cyclic voltammetry. Initial catalytic investigations reveal that these simple model complexes display a wide range of catalytic turnover rates, conversion yields and product gas compositions

  一系列 铜 已合成了配合物作为催化还原苯的潜在试剂。 亚硝酸盐阴离子。配体和相应的铜通过使用一系列技术（包括X射线晶体学，NMR，微分析，质谱，红外光谱，电化学研究和密度泛函理论计算）对复合物进行了表征。对于具有接合到赤道施主氮原子简单脂族取代基，对NO的转化催化研究复合物2 -阴离子成不N 2 O气体显示出初始转化率与通过循环伏安法测得的实验还原电位之间具有极好的相关性。初步的催化研究表明，这些简单的模型络合物显示出广泛的催化转化率，转化率和产物气体组成。总体而言，结果表明，需要进一步研究设计和使用铜 配合物作为亚硝酸盐还原催化剂是必要的。
• Near infrared radiation-absorbing composition, near infrared radiation cut-off filter and production method therefor, and camera module and production method therefor
  申请人：FUJIFILM Corporation

  公开号：US10184052B2

  公开（公告）日：2019-01-22

  An object of the present invention is to provide a near infrared radiation-absorbing composition having favorable shielding properties in a near infrared range when used to produce cured films, a near infrared radiation cut-off filter and a production method therefor, and a camera module and a production method therefor. The near infrared radiation-absorbing composition including a copper complex formed by reacting a compound (A) having two or more coordinating atoms that form bonds using unshared electron pairs with a copper component.

  本发明的目的是提供一种在用于生产固化薄膜时在近红外范围内具有良好屏蔽性能的近红外辐射吸收组合物、一种近红外辐射截止滤光片及其生产方法，以及一种相机模组及其生产方法。近红外辐射吸收组合物包括铜络合物，该铜络合物是由具有两个或两个以上配位原子的化合物（A）与铜成分反应形成的，该化合物具有两个或两个以上配位原子，这些配位原子利用未共享电子对形成键。
• NEAR INFRARED RAY ABSORBENT COMPOSITION, NEAR INFRARED RAY CUT FILTER, SOLID IMAGE PICKUP ELEMENT, AND CAMERA MODULE
  申请人：FUJIFILM Corporation

  公开号：US20170227690A1

  公开（公告）日：2017-08-10

  Provided are a near infrared ray absorbent composition which can form a cured film having excellent near infrared ray shielding properties, a near infrared ray cut filter, a manufacturing method of a near infrared ray cut filter, a solid image pickup element, and a camera module. The near infrared ray absorbent composition includes a copper complex that is other than a copper phthalocyanine complex and has a maximum absorption wavelength in a wavelength range of 700 to 1,200 nm and in which a molar light absorption coefficient at the maximum absorption wavelength is greater than or equal to 100 (L/mol·cm).
• Covalently supported porphyrins as ligands for the preparation of heme a3/CuB binuclear active site analogues of heme–copper terminal oxidases and metallation under mild conditions
  作者：Jin-Ook Baeg

  DOI：10.1039/a707785h

  日期：——

  New covalently supported binucleating porphyrins have been prepared as potential structural and/or functional ligands for the iron–copper (heme a3/CuB) active sites of heme–copper oxidases, and the introduction of iron and copper into one porphyrin under mild reaction conditions has been developed.

  新型共价支撑的双核卟啉已被制备，作为血红素-铜氧化酶中铁-铜（血红素a3/CuB）活性位点的潜在结构和/或功能配体，并且在温和反应条件下将铁和铜引入一个卟啉的工艺已被开发。