benzyl methyl trithiocarbonate | 82843-64-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyl methyl trithiocarbonate
• 英文别名: Methyl-benzyl-trithiocarbonat；Benzylsulfanyl(methylsulfanyl)methanethione
• CAS: 82843-64-9
• 化学式: C₉H₁₀S₃
• 分子量: 214.376
• InChiKey: QOJCZLRNMVPBKJ-UHFFFAOYSA-N

物化性质

• 沸点：
  139-141 °C(Press: 0.66 Torr)
• 密度：
  1.248±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  82.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  methyl chlorodithioformate 、 苄硫醇 在 sodium hydroxide 作用下， 以 苯 为溶剂， 生成 benzyl methyl trithiocarbonate
  参考文献：
  名称：

  The Synthesis of Organic Trithiocarbonates¹

  摘要：

  DOI：

  10.1021/jo01068a097

文献信息

• Triethylamine-catalyzed one-pot synthesis of trithiocarbonates from carbon disulfide, thiols, and alkyl halides in water
  作者：Barahman Movassagh、Mohammad Soleiman-Beigi

  DOI：10.1007/s00706-008-0864-x

  日期：2008.8

  Symmetrical and unsymmetrical trithiocarbonates were prepared by a simple and efficient one-pot reaction of thiols, carbon disulfide, and alkyl halides in the presence of triethylamine in water at room temperature.

  对称和不对称的三硫代碳酸酯是通过在室温下在水中存在三乙胺的情况下，简单，高效地一锅反应硫醇，二硫化碳和烷基卤来制备的。
• Synthesis and Lithiation of 2-Alkylthio- and 2-Arylthio-1,3-dithiolanes
  作者：Shigeo Tanimoto、Tatsuo Oida、Hideyuki Ikehira、Masaya Okano

  DOI：10.1246/bcsj.55.1977

  日期：1982.6

  Several 2-alkylthio- and 2-arylthio-1,3-dithiolanes were synthesized by the reaction of 2-ethoxy-1,3-dithiolane with aliphatic and aromatic thiols in the presence of ZnCl2. The lithiation of 2-alkylthio-1,3-dithiolanes with butyllithium in tetrahydrofuran followed by the addition of alkyl halides gave unsymmetrical dialkyl trithiocarbonates in moderately good yields.

  在 ZnCl2 存在下，通过 2-乙氧基-1,3-dithiolane 与脂肪族和芳香族硫醇的反应合成了几种 2-烷硫基-和 2-芳硫基-1,3-dithiolanes。在四氢呋喃中用丁基锂将 2-烷硫基-1,3-二硫戊烷锂化，然后加入卤代烷，得到不对称的三硫代碳酸二烷基酯，产率适中。
• Zinc Thiolate Complexes [ZnL <i> _n </i> (SR)] ⁺ with Azamacrocyclic Ligands, Part II: Mechanism of the Reaction with CS ₂
  作者：Johannes Notni、Stephan Schenk、Arne Roth、Winfried Plass、Helmar Görls、Ute Uhlemann、Angela Walter、Michael Schmitt、Jürgen Popp、Susana Chatzipapadopoulos、Thomas Emmler、Hergen Breitzke、Jörg Leppert、Gerd Buntkowsky、Kristian Kempe、Ernst Anders

  DOI：10.1002/ejic.200500948

  日期：2006.7

  The thiolate complexes Zn(15]aneN(4))(S-CH2-C6H5)]ClO4 (1) (15aneN(4) = 1,4,8,12-tetraazacyclopentadecane) and Zn(i-14]aneN(4))(S-CH2-C6H5)ICIO4 (2) (i-14aneN(4) = 1, 4,7, 11 -tetraazacyclotetradecane) have been reacted with carbon disulfide. The trithiocarbonate complexes Zn(15]aneN(4))S-C(S)-S-CH2-C6H5]CIO4 1a, monoclinic, space group P2(1)/n, Z = 8, a = 13,2338(1) angstrom, b = 12.9251(2) angstrom

  硫醇盐配合物 Zn(15]aneN(4))(S-CH2-C6H5)]ClO4 (1) (15aneN(4) = 1,4,8,12-四氮杂环十五烷) 和 Zn(i-14]aneN(4) ))(S- - )ICIO4 (2) (i-14aneN(4) = 1, 4,7, 11 -四氮杂环十四烷）已与二硫化碳反应。三硫代碳酸酯配合物 Zn(15]aneN(4))SC(S)-S- - ]CIO4 1a，单斜晶系，空间群 P2(1)/n，Z = 8，a = 13,2338(1) 埃, b = 12.9251(2) 埃，c = 30.1669(4) 埃，β = 101.463(1) 度，V = 5057.1(1) 埃(3) 和 Zn(i14]aneN(4))SC(S)- S- - ]CIO4 2a，正交，空间群 P2(1)2(1)2(1)，Z = 8，a = 9.9936(1)
• TANIMOTO, SHIGEO;OIDA, TATSUO;IKEHIRA, HIDEYUKI;OKANO, MASAYA, BULL. CHEM. SOC. JAP., 1982, 55, N 6, 1977-1978
  作者：TANIMOTO, SHIGEO、OIDA, TATSUO、IKEHIRA, HIDEYUKI、OKANO, MASAYA

  DOI：——

  日期：——
• Energetic Feedstock for Additive Manufacturing
  申请人：Lynntech, Inc.

  公开号：US20210276931A1

  公开（公告）日：2021-09-09

  The present invention comprises formulations and method for additive manufacturing comprising: a pot-stable photo-curable polymer; one or more fillers; and one or more additives, wherein the formulation cures into a polymer in six hours or less upon exposure to light. In certain examples, the additive manufacturing is a moldless method of additive manufacturing by preparing a formulation comprising: a pot-stable photo-curable polymer, one or more fillers, and one or more additives, and exposing the formulation to light in an amount that substantially cures the polymer in 6 hours or less.