6-(4'-cyanobiphenyl-4-yloxy)hexyl phosphate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 6-(4'-cyanobiphenyl-4-yloxy)hexyl phosphate
• 英文别名: 6-[4-(4-Cyanophenyl)phenoxy]hexyl dihydrogen phosphate；6-[4-(4-cyanophenyl)phenoxy]hexyl dihydrogen phosphate
• 化学式: C₁₉H₂₂NO₅P
• 分子量: 375.361
• InChiKey: CWMYLWBJMRISBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  26
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  99.8
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  氰基联苯酚 在 四氮唑 、 双氧水 、 potassium carbonate 、 三乙胺 、 三氟乙酸 作用下， 以 四氢呋喃 、 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 6.5h， 生成 6-(4'-cyanobiphenyl-4-yloxy)hexyl phosphate
  参考文献：
  名称：

  Organic−Inorganic Hybrid Liquid Crystals:  Thermotropic Mesophases Formed by Hybridization of Liquid-Crystalline Phosphates and Monodispersed α-Fe₂O₃ Particles

  摘要：

  A novel organic-inorganic hybrid thermotropic liquid crystal (LC) is developed by the hybridization of an organic phosphate having a mesogenic core and monodispersed alpha-Fe2O3 particles with different shapes through the specific adsorption of the phosphate group to the surfaces parallel to the c-axis of the alpha-Fe2O3. The hybrid LC shows thermotropic nematic or cubic liquid-crystallinity in wide ranges of temperatures. Variable-temperature small-angle X-ray measurements reveal that the spontaneous formation of periodic structure by the hybridization induces the thermotropic liquid crystallinity. This technique would lead development of novel types of dynamic functional materials with multi-responsiveness to magnetic and electric fields.

  DOI：

  10.1021/ja054232f

文献信息

• Organic−Inorganic Hybrid Liquid Crystals:  Thermotropic Mesophases Formed by Hybridization of Liquid-Crystalline Phosphates and Monodispersed α-Fe₂O₃ Particles
  作者：Kiyoshi Kanie、Atsushi Muramatsu

  DOI：10.1021/ja054232f

  日期：2005.8.24

  A novel organic-inorganic hybrid thermotropic liquid crystal (LC) is developed by the hybridization of an organic phosphate having a mesogenic core and monodispersed alpha-Fe2O3 particles with different shapes through the specific adsorption of the phosphate group to the surfaces parallel to the c-axis of the alpha-Fe2O3. The hybrid LC shows thermotropic nematic or cubic liquid-crystallinity in wide ranges of temperatures. Variable-temperature small-angle X-ray measurements reveal that the spontaneous formation of periodic structure by the hybridization induces the thermotropic liquid crystallinity. This technique would lead development of novel types of dynamic functional materials with multi-responsiveness to magnetic and electric fields.