diisodecylcyclohexane-1,4-diester | 313504-70-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: diisodecylcyclohexane-1,4-diester
• 英文别名: 1,4-DINCH；cyclohexane-1,4-dicarboxylic acid bis(7-methyloctyl) ester；Di(isononyl)cyclohexane-1,4-dicarboxylate；bis(7-methyloctyl) cyclohexane-1,4-dicarboxylate
• CAS: 313504-70-0
• 化学式: C₂₆H₄₈O₄
• 分子量: 424.665
• InChiKey: RCJYKEBCIPMBED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  30
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  异壬醇 、 1,4-环己烷二羧酸二甲酯 在 titanium(IV) isopropylate 作用下， 以Di(isononyl)cyclohexane-1,4-dicarboxylate (cis 3%, trans 97%) was obtained with a purity of 99.7% in the same manner as in Example 1的产率得到diisodecylcyclohexane-1,4-diester
  参考文献：
  名称：

  Method of Preparing of 60% or More CIS-DI(C4-C20)Alkyl Cyclohexane-1,4-Dicarboxylate

  摘要：

  提供了一种制备60％或更多顺式二（C4-C20）烷基环己烷-1,4-二羧酸酯的方法，该方法对PVC树脂具有优越的增塑性能。与基于邻苯二甲酸酯或对苯二甲酸酯的芳香酯衍生物不同，使用60％或更多的顺式二甲基环己烷-1,4-二羧酸酯作为起始材料。将60％或更多的顺式二甲基环己烷-1,4-二羧酸酯与（C4-C20）一次醇进行酯交换反应，制备60％或更多的顺式二（C4-C20）烷基环己烷-1,4-二羧酸酯。在酯交换反应期间产生的甲醇副产物被除去，蒸发的一些一次醇被回收。因此制备的60％或更多顺式二（C4-C20）烷基环己烷-1,4-二羧酸酯具有优越的增塑特性，包括对PVC树脂的良好增塑效率，高吸收率，凝胶后良好的产品透明度，长期使用时较少向表面渗出等特点。

  公开号：

  US20110263770A1

文献信息

• Foamable compositions which comprise isononyl benzoate
  申请人：Grass Michael

  公开号：US20050049341A1

  公开（公告）日：2005-03-03

  Compositions for producing foamed products which comprise a chlorinated polymer such as PVC and at least one isomeric nonyl benzoate as a plasticizer, the use of these compositions, and products produced therefrom including PVC-containing floorcoverings, synthetic leather, and wallcoverings.

  本发明涉及一种用于生产发泡产品的组合物，其中包括氯化聚合物，例如PVC和至少一种异构的壬基苯甲酸酯作为增塑剂，以及这些组合物的使用和由其生产的产品，包括含有PVC的地板覆盖物、合成皮革和墙面覆盖物。
• Method of Preparing of 60% or More CIS-DI(C4-C20)Alkyl Cyclohexane-1,4-Dicarboxylate
  申请人：Yoon Kyong-jun

  公开号：US20110263770A1

  公开（公告）日：2011-10-27

  Provided is a method for preparing 60% or more cis-di(C4-C20)alkyl cyclohexane-1,4-dicarboxy-late which exhibits superior plasticizing property for PVC resin. Instead of a phthalate- or terephthalate-based aromatic ester derivative, 60% or more cis-dimethyl cyclo-hexane-1,4-dicarboxylate is used as a starting material. The 60% or more cis-dimethyl cyclohexane-1,4-dicarboxylate is subjected to transesterification with (C4-C20) primary alcohol to prepare 60% or more cis-di(C4-C20)alkyl cyclohexane-1,4-dicarboxylate. Methanol produced as a byproduct during the transesterification is removed and some of the primary alcohol, which is evaporated, is recycled. Thus prepared 60% or more cis-di(C4-C20)alkyl cyclohexane-1,4-dicarboxylate exhibits superior plasticizer characteristics, including good plasticizing efficiency for PVC resin, high absorption rate, good product transparency after gelling, less bleeding toward the surface upon long-term use, and the like.

  提供了一种制备60％或更多顺式二（C4-C20）烷基环己烷-1,4-二羧酸酯的方法，该方法对PVC树脂具有优越的增塑性能。与基于邻苯二甲酸酯或对苯二甲酸酯的芳香酯衍生物不同，使用60％或更多的顺式二甲基环己烷-1,4-二羧酸酯作为起始材料。将60％或更多的顺式二甲基环己烷-1,4-二羧酸酯与（C4-C20）一次醇进行酯交换反应，制备60％或更多的顺式二（C4-C20）烷基环己烷-1,4-二羧酸酯。在酯交换反应期间产生的甲醇副产物被除去，蒸发的一些一次醇被回收。因此制备的60％或更多顺式二（C4-C20）烷基环己烷-1,4-二羧酸酯具有优越的增塑特性，包括对PVC树脂的良好增塑效率，高吸收率，凝胶后良好的产品透明度，长期使用时较少向表面渗出等特点。
• Method of preparing of 60% or more CIS-DI(C4-C20)alkyl cyclohexane-1,4-dicarboxylate
  申请人：Hanwha Chemical Corporation

  公开号：US08299292B2

  公开（公告）日：2012-10-30

  Provided is a method for preparing 60% or more cis-di(C4-C20)alkyl cyclohexane-1,4-dicarboxylate which exhibits superior plasticizing property for PVC resin. Instead of a phthalate- or terephthalate-based aromatic ester derivative, 60% or more cis-dimethyl cyclohexane-1,4-dicarboxylate is used as a starting material. The 60% or more cis-dimethyl cyclohexane-1,4-dicarboxylate is subjected to transesterification with (C4-C20) primary alcohol to prepare 60% or more cis-di(C4-C20)alkyl cyclohexane-1,4-dicarboxylate. Methanol produced as a byproduct during the transesterification is removed and some of the primary alcohol, which is evaporated, is recycled. Thus prepared 60% or more cis-di(C4-C20)alkyl cyclohexane-1,4-dicarboxylate exhibits superior plasticizer characteristics, including good plasticizing efficiency for PVC resin, high absorption rate, good product transparency after gelling, less bleeding toward the surface upon long-term use, and the like.

  提供了一种制备60%或以上的顺式二(C4-C20)烷基环己烷-1,4-二羧酸酯的方法，该酯具有优异的PVC树脂增塑性能。该方法使用60%或以上的顺式二甲基环己烷-1,4-二羧酸酯作为起始物，而不是基于邻苯二甲酸酯或对苯二甲酸酯的芳香酯衍生物。将60%或以上的顺式二甲基环己烷-1,4-二羧酸酯与(C4-C20)一级醇进行酯交换反应，制备60%或以上的顺式二(C4-C20)烷基环己烷-1,4-二羧酸酯。在酯交换反应过程中产生的甲醇副产物被去除，并回收部分蒸发的一级醇。因此制备的60%或以上的顺式二(C4-C20)烷基环己烷-1,4-二羧酸酯具有优异的增塑性能，包括对PVC树脂的良好增塑效率、高吸收率、凝胶后良好的产品透明度、长期使用时少向表面渗出等特点。
• CYCLOHEXANE POLYCARBOXYLIC ACID DERIVATIVES AS PLASTICIZERS FOR ADHESIVES AND SEALANTS
  申请人：Mack Helmut

  公开号：US20110232825A1

  公开（公告）日：2011-09-29

  The invention provides an adhesive or sealant comprising at least (A) one compound selected from the group consisting of silylated polyurethanes, silylated polyureas, silylated polyethers, silylated polysulfides and silyl-terminated acrylates, and at least (B) one cyclohexane polycarboxylic acid derivative. The composition has enhanced extensibility with good adhesion properties and high tensile strength. A process is disclosed for preparing the adhesive or sealant, and also disclosed is the use thereof for producing material bonds between parts to be joined.

  本发明提供了一种粘合剂或密封剂，包括至少（A）从包括硅化聚氨酯、硅化聚氨基甲酸酯、硅化聚醚、硅化聚硫化物和硅基终止丙烯酸酯的群组中选择的一种化合物，以及至少（B）一种环己烷聚羧酸衍生物。该组合物具有良好的粘附性和高拉伸强度的增强延展性。还公开了制备粘合剂或密封剂的过程，并公开了将其用于在要连接的零件之间产生材料粘结的用途。
• CURABLE COMPOSITION
  申请人：Kaneka Corporation

  公开号：EP3115419A1

  公开（公告）日：2017-01-11

  The present invention provides a curable composition comprising an organic polymer having a reactive silyl group that is applicable to a sealant and an adhesive by improving depth curability, curing retardation after storage, and tensile properties. A curable composition comprising (A) an organic polymer having a reactive silyl group; (B) at least one ester compound (except for compounds having a methyl ester group) selected from the group consisting of isophthalic acid ester compounds, terephthalic acid ester compounds, 1,3-cyclohexanedicarboxylic acid ester compounds, and 1,4-cyclohexanedicarboxylic acid ester compounds; and (C) a compound having a methyl ester group.

  本发明提供了一种由具有活性硅基的有机聚合物组成的可固化组合物，通过改善深度 固化、储存后固化延迟和拉伸性能，适用于密封剂和粘合剂。一种可固化组合物，包含(A)具有活性硅基的有机聚合物；(B)至少一种酯类化合物（具有甲基酯基的化合物除外），选自间苯二甲酸酯类化合物、对苯二甲酸酯类化合物、1,3-环己烷二羧酸酯类化合物和 1,4-环己烷二羧酸酯类化合物组成的组；以及(C)具有甲基酯基的化合物。