4-butoxy-triphenylamine | 1241951-83-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-butoxy-triphenylamine
• 英文别名: 4-butoxy-N,N-diphenylaniline
• CAS: 1241951-83-6
• 化学式: C₂₂H₂₃NO
• 分子量: 317.431
• InChiKey: SMCRJIHETXGOEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-butoxy-triphenylamine 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 四氯化碳 为溶剂， 反应 24.0h， 以98%的产率得到N,N-bis(4-bromophenyl)-N-(4-butoxyphenyl)-amine
  参考文献：
  名称：

  The effect of anchoring group number on the performance of dye-sensitized solar cells

  摘要：

  Novel dyes comprising a triphenylamine donor, thiophene conjugated bridge and different numbers of anchor groups (cyanoacrylic acid acceptor) were synthesized and employed as photosensitizers in dyesensitized solar cells. The absorbance of the dyes in solution was red shifted and the first oxidation potential decreased with increasing butoxy group:anchor group ratio. Solar cells based on the dyes exhibited energy conversion efficiencies of 6.7-7.4% at 100 mW cm(-2). Increasing butoxy group:anchor group ratio resulted in higher open-circuit voltage and higher efficiency. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.03.034
• 作为产物：
  描述：

  对溴丁氧基苯 、 二苯胺 在 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 1,1'-双(二苯基膦)二茂铁 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 72.5h， 以83%的产率得到4-butoxy-triphenylamine
  参考文献：
  名称：

  The effect of anchoring group number on the performance of dye-sensitized solar cells

  摘要：

  Novel dyes comprising a triphenylamine donor, thiophene conjugated bridge and different numbers of anchor groups (cyanoacrylic acid acceptor) were synthesized and employed as photosensitizers in dyesensitized solar cells. The absorbance of the dyes in solution was red shifted and the first oxidation potential decreased with increasing butoxy group:anchor group ratio. Solar cells based on the dyes exhibited energy conversion efficiencies of 6.7-7.4% at 100 mW cm(-2). Increasing butoxy group:anchor group ratio resulted in higher open-circuit voltage and higher efficiency. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.03.034

文献信息

• The effect of anchoring group number on the performance of dye-sensitized solar cells
  作者：Huixia Shang、Yanhong Luo、Xiaozhi Guo、Xiaoming Huang、Xiaowei Zhan、Kejian Jiang、Qingbo Meng

  DOI：10.1016/j.dyepig.2010.03.034

  日期：2010.11

  Novel dyes comprising a triphenylamine donor, thiophene conjugated bridge and different numbers of anchor groups (cyanoacrylic acid acceptor) were synthesized and employed as photosensitizers in dyesensitized solar cells. The absorbance of the dyes in solution was red shifted and the first oxidation potential decreased with increasing butoxy group:anchor group ratio. Solar cells based on the dyes exhibited energy conversion efficiencies of 6.7-7.4% at 100 mW cm(-2). Increasing butoxy group:anchor group ratio resulted in higher open-circuit voltage and higher efficiency. (C) 2010 Elsevier Ltd. All rights reserved.