4-(trifluoromethyl)phthalonitrile | 1483-45-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(trifluoromethyl)phthalonitrile
• 英文别名: 4-trifluoromethylphthalodinitrile；4-(trifluoromethyl)benzene-1,2-dicarbonitrile
• CAS: 1483-45-0
• 化学式: C₉H₃F₃N₂
• 分子量: 196.131
• InChiKey: OJEIRAZFJSKHFE-UHFFFAOYSA-N

物化性质

• 熔点：
  113-114 °C
• 沸点：
  299.7±40.0 °C(Predicted)
• 密度：
  1.37±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-(trifluoromethyl)phthalonitrile 在 氨 、 sodium methylate 作用下， 以 甲醇 为溶剂， 以90%的产率得到1,3-diimino-5-trifluoromethyl-1,3-dihydroisoindole
  参考文献：
  名称：

  Pawlowski, Georg; Hanack, Michael, Synthetic Communications, 1981, vol. 11, # 5, p. 351 - 364

  摘要：

  DOI：
• 作为产物：
  描述：

  5-(三氟甲基)异吲哚啉-1,3-二酮 在 氨 、 三氯氧磷 作用下， 以 吡啶 为溶剂， 反应 42.0h， 生成 4-(trifluoromethyl)phthalonitrile
  参考文献：
  名称：

  Pawlowski, Georg; Hanack, Michael, Synthetic Communications, 1981, vol. 11, # 5, p. 351 - 364

  摘要：

  DOI：

文献信息

• Copper Nanoparticles from Copper Aluminum Hydrotalcite: An Efficient Catalyst for Acceptor- and Oxidant-Free Dehydrogenation of Amines and Alcohols
  作者：Dandu Damodara、Racha Arundhathi、Pravin R. Likhar

  DOI：10.1002/adsc.201300453

  日期：2014.1.13

  An efficient and simple process for the preparation of stable nanocopper(0) on alumina [Cu(0)/Al2O3] from the inorganic composite precursor copper aluminum hydrotalcite (Cu‐Al HT) by a chemical reduction method is described. Cu(0)/Al2O3 was employed as an efficient catalyst in the acceptor‐ and oxidant‐free dehydrogenation of various amines and alcohols to their corresponding dehydrogenated products

  描述了一种通过化学还原方法从无机复合材料前体铜铝水滑石（Cu-Al HT）制备氧化铝[Cu（0）/ Al 2 O 3 ]上稳定的纳米铜（0）的有效且简单的方法。Cu（0）/ Al 2 O 3用作各种胺和醇类的无受体和无氧化剂脱氢反应为其相应的脱氢产物的有效催化剂，收率非常好。通过研究最多五个循环的胺和醇脱氢中的可回收性和可重复使用性，评估了Cu（0）/ Al 2 O 3的稳定性。
• 顔料組成物、着色組成物及び着色硬化性組成物
  申请人：住友化学株式会社

  公开号：JP2018012834A

  公开（公告）日：2018-01-25

  【課題】耐光性の改善されたカラーフィルタの形成に用いることができる顔料組成物、着色組成物及び着色硬化性組成物の提供。【解決手段】式（Ｉ）で表される化合物と、キノフタロン化合物、式（Ｉ）で表される化合物以外のイソインドリン化合物または緑色着色剤とを含む顔料組成物。［Ｌ1は、−ＣＯ−又は−ＳＯ2−；Ｒ1〜Ｒ5及びＲ12〜Ｒ13は夫々独立に、Ｈ、−ＣＯ−Ｒ102等；Ｒ2とＲ3、Ｒ3とＲ4、Ｒ4とＲ5及びＲ12とＲ13は、夫々結合して環を形成してもよい；Ｒ11及びＲ101は、夫々独立に、置換／非置換のよいＣ１〜４０の炭化水素基又は置換／非置換の複素環基；Ｒ102は、Ｈ、置換／非置換のＣ１〜４０の炭化水素基又は置換／非置換の複素環基］【選択図】なし

  提供耐光性改善的颜料组成物、着色组成物和着色硬化性组成物，可用于形成改进的耐光性彩色滤光片。所述颜料组成物包括由式（I）表示的化合物、喹诺酮化合物、不包括式（I）表示的化合物的异噁啉化合物或绿色着色剂。【L1为- CO-或-SO2-；R1至R5和R12至R13各自独立地是H、-CO-R102等；R2和R3、R3和R4、R4和R5以及R12和R13可以结合形成环；R11和R101各自独立地是取代/非取代的C1-40烃基或取代/非取代的复杂环基；R102是H、取代/非取代的C1-40烃基或取代/非取代的复杂环基】。【选择图】无
• 化合物及び着色組成物
  申请人：住友化学株式会社

  公开号：JP2017137490A

  公开（公告）日：2017-08-10

  【課題】本発明は、カラーフィルタ等に用いることができる新たな着色組成物を提供する。【解決手段】式（Ｉ）で表される化合物及び樹脂を含む着色組成物。【選択図】なし

  【问题】本发明提供了一种可用于彩色滤光片等的新型着色组合物。【解决方法】包含由式（I）表示的化合物和树脂的着色组合物。【选定图】无
• 2-IMINOPYRROLIDINE DERIVATES
  申请人：Eisai R&D Management Co., Ltd.

  公开号：EP1391451B1

  公开（公告）日：2011-11-23
• Study of Substituent Effects on the Photoconductivity of Soluble 2,(3)- and 1,(4)-Substituted Phthalocyaninato- and Naphthalocyaninatotitanium(IV) Oxides
  作者：Götz Winter、Heino Heckmann、Peter Haisch、Wolfgang Eberhardt、Michael Hanack、Larry Lüer、Hans-Joachim Egelhaaf、Dieter Oelkrug

  DOI：10.1021/ja981644y

  日期：1998.11.1

  Soluble alkyl (II, 8a,b), fluoroalkyl,(4a), and fluoroalkoxy (4b,c, 8c) 1,(4)- or 2,(3)-substituted phthalocyaninato- and linear 2,(3)- and-angular 1,(2)-annulated naphthalocyaninatotitanium(IV) oxides 10, 12, and 14 were synthesized and characterized with regard to their spectroscopic, photophysical, and photochemical properties. While alkyl- and fluoroalkoxy-substituted compounds are highly soluble in nonpolar solvents, e.g., hexane, fluoroalkyl-substituted compounds are better soluble in polar aprotic solvents such as acetone. The stability against photooxidation in solution is' enhanced on going-from alkylated phthalocyanines 1,(4)-(C(5)H(11))(8)PcTiO (8a), 1,(4)-(C(6)H(13))(8)PcTiO (4b), and 2,(3)-(C(4)H(9))(8)PcTiO (II) to fluorinated phthalocyanines 2,(3)-(CF(3))(4)PcTiO (4a), 2,(3)-(CF(3)CH(2)O)(4)PcTiO (4b), and 2,(3)-(CF(3)CH(2)O)(8)PcTiO (4c), from phthalocyanines to naphthalocyanines (tert-butyl)(4)-2,(3)-NcTiO (10), 1,(2)-NcTiO (12), and (tert-butyl)(4)-1,(2)-NdTiO (14), and on going from 2,(3)-substituted 4a-c to 1,(4)-substituted phthalocyanines 8a-c. Thin films of these compounds, prepared by either vacuum deposition or spin casting, are classified into three types according to increasing intermolecular pi-pi interactions. Type alpha films, characterized:by absence of exciton splitting, are formed from 1,(4)-substituted phthalocyanines 8a-c. These films show low dark conductivities and photoconductivities and are considerably sensitive to photooxidation. Type beta films, characterized by weak exciton splitting, are formed from fluorinated phthalocyanines 4a-c as well as from rapidly deposited 2,(3)-substituted phthalocyanines II and the unsubstituted PcTiO (I). These films show enhanced photoconductivity and are generally more stable against photooxidation than type alpha films. Type gamma films, formed by slow deposition of II, 10 and unsubstituted phthalocyanine I, are classified by a largely red-shifted B-band absorbing in the near-IR. These films are highly photosensitive as well as stabilized against photooxidation. Steady-state photoconductivities and dark conductivities in thin films are strongly dependent on oxygen partial pressure. Alkylated PcTiO's such as 8a, 8b, and II are found to be p-type conductors (positive oxygen influence on conductivities) like unsubstituted PcTiO (I), whereas angularly annulated naphthalocyanines such as 12 and 14 as well as fluorinated PcTiO's 4a-c are n-type conductors (negative oxygen influence on conductivity). These findings are rationalized by comparison with experimental and theoretical literature data.