4-戊烷-2-基苯胺 | 30273-14-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-戊烷-2-基苯胺
• 英文名称: (+/-)-4-(1-methyl-butyl)-aniline
• 英文别名: 4-(1-methyl-butyl)-aniline；(+/-)-4-(1-Methyl-butyl)-anilin；4-(1-Methyl-butyl)-anilin；4-(2'-pentyl)aniline；Methyl-propyl-<4-amino-phenyl>-methan；4-<1-Methyl-butyl>-anilin；Benzenamine, 4-(1-methylbutyl)-；4-pentan-2-ylaniline
• CAS: 30273-14-4
• 化学式: C₁₁H₁₇N
• 分子量: 163.263
• InChiKey: AKSSDFIINGVZJQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-戊烷-2-基苯胺 生成 4-仲戊基酚
  参考文献：
  名称：

  Revision of species of the “Oligia” semicana group (Lepidoptera: Noctuidae) with descriptions of a new genus and 12 new species

  摘要：

  AbstractThe name Neoligiagen.nov. is proposed for the "Oligia" semicana (Walker) species group in North America and 12 species, N. rubirena sp.nov., N. pagosa sp.nov., N. hardwicki sp.nov、N. inermis sp.nov.、N. invenusta sp.nov.、N. albirena sp.nov.、N. lancea sp.nov.、N. elephas sp.nov.、N. lillooet sp.nov.、N. surdirena sp.nov.、N. canadensis sp.nov.和 N. atlantica sp.nov.等 12 个种。Hadenella laevigata Smith 与 Hadena tonsa Grote 同源（同义恢复），Hadena hausta Grote 与 Miana semicana Walker 同源（同义恢复）。所有物种的成体以及已知的雄性和雌性生殖器均附有插图。

  DOI：

  10.4039/ent134157-2
• 作为产物：
  描述：

  2-苯基戊烷 在 硫酸 、 硝酸 作用下， 生成 4-戊烷-2-基苯胺
  参考文献：
  名称：

  Identification of Alkylbenzenes. II. Identification of the Eight Amylbenzenes and Cyclopentylbenzene by Means of Their Mono- and Diacetamino and Monobenzamino Derivatives

  摘要：

  DOI：

  10.1021/ja01273a060

文献信息

• [EN] PROCESSES FOR THE PREPARATION OF NIRAPARIB AND INTERMEDIATES THEREOF<br/>[FR] PROCÉDÉS DE PRÉPARATION DE NIRAPARIB ET INTERMÉDIAIRES DE CELUI-CI
  申请人：TEVA PHARMA

  公开号：WO2019036441A1

  公开（公告）日：2019-02-21

  The present invention relates to novel procedures and novel intermediates useful in the synthesis of Niraparib or any salt thereof.

  本发明涉及用于合成尼拉帕尼布或其任何盐的新型程序和新型中间体。
• Novel ortho-quinone diazide photoresist sensitizers
  申请人：RCA Corporation

  公开号：US04207107A1

  公开（公告）日：1980-06-10

  Ortho-quinone diazide compounds of the formula ##STR1## wherein R is an organic radical are useful sensitizers for photoresist compositions and intermediates for novel dyes.

  式为##STR1##其中R为有机基团的正醌二重氮化合物是光刻胶组合物的有用敏化剂，也是新型染料的中间体。
• Catalytic Access to 4-(sec-Alkyl)Anilines via 1,6-Conjugate Addition of Grignard Reagents to <i>in Situ</i> Generated aza-<i>p</i>-Quinone Methides
  作者：Mercedes Zurro、Luo Ge、Syuzanna R. Harutyunyan

  DOI：10.1021/acs.orglett.2c02786

  日期：2022.9.16

  The synthesis of aniline derivatives, common building blocks in many pharmaceuticals, agrochemicals, dyes or polymers, has been limited to reactions based on benzene-toluene-xylene derivatives (BTX) due to their ample availability. Despite the large number of existing methodologies, the synthesis of chiral 4-(sec-alkyl)anilines has not been accomplished so far. In this work, a tandem strategy based

  苯胺衍生物是许多药物、农用化学品、染料或聚合物中的常见组成部分，但由于其可用性充足，其合成仅限于基于苯-甲苯-二甲苯衍生物 (BTX) 的反应。尽管现有的方法有很多，但手性4-(仲烷基)苯胺的合成迄今为止尚未完成。在这项工作中，开发了一种串联策略，该策略基于生成反应性氮杂对醌甲基化物 (aza -p -QM) 中间体，然后通过 Cu(I) 催化加成格氏试剂。
• Crystalline polypropylene resin composition and amide compounds
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0557721A2

  公开（公告）日：1993-09-01

  Disclosed are a crystalline polypropylene resin composition comprising a crystalline polyproplylene resin and a β-nucleating agent, and a method of increasing the proportion of β-form crystals in a crystalline polypropylene resin molding comprising molding the composition, the β-nucleating agent being a diamide compound.

  本发明公开了一种结晶聚丙烯树脂组合物，该组合物由结晶聚丙烯树脂和 β 成核剂组成；还公开了一种增加结晶聚丙烯树脂模塑中 β 形晶体比例的方法，该方法包括模塑该组合物，β 成核剂为二酰胺化合物。
• Porous stretched article of polypropylene-based resin and process for its preparation
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0632095A2

  公开（公告）日：1995-01-04

  Disclosed are a process for producing a porous stretched article of β-crystalline polypropylene-based resin, the process comprising the steps of crystallizing a melt of a polypropylene-based resin composition at a temperature of 15 to 140°C to form a solidified product containing β-form crystals and stretching the resulting solidified product at a temprature which is higher than 20 °C but lower than the melting point of the β-form crystals in said solidified product, the polypropylene-based resin composition comprising a polypropylene-based resin and 0.0001 to 5 parts by weight, per 100 parts by weight of the polypropylene-based resin, of at least one specific amide compound; and a porous stretched article produced by the process.

  本发明公开了一种用β-结晶聚丙烯基树脂生产多孔拉伸制品的工艺，该工艺包括以下步骤：在15至140℃的温度下使聚丙烯基树脂组合物的熔体结晶，形成含有β-结晶的固化物，并在高于20℃但低于所述固化物中β-结晶的熔点的温度下拉伸所得固化物，所述聚丙烯基树脂组合物包括聚丙烯基树脂和0.0001至5份（按每100份聚丙烯基树脂的重量计）的至少一种特定酰胺化合物；以及由该工艺生产的多孔拉伸制品。

表征谱图