5-acetoxyisophthaloyl acid dichloride | 137374-13-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 5-acetoxyisophthaloyl acid dichloride
• 英文别名: 5-Acetoxy-isophthalsaeuredichlorid；5-acetoxyisophthaloyl dichloride；3,5-bis(chlorocarbonyl)phenyl acetate；1,3-Benzenedicarbonyl dichloride, 5-(acetyloxy)-；(3,5-dicarbonochloridoylphenyl) acetate
• CAS: 137374-13-1
• 化学式: C₁₀H₆Cl₂O₄
• 分子量: 261.061
• InChiKey: XTEUILVYNKREOP-UHFFFAOYSA-N

物化性质

• 沸点：
  371.3±32.0 °C(Predicted)
• 密度：
  1.451±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  60.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5-acetoxyisophthaloyl acid dichloride 在 potassium carbonate 、 三乙胺 、 甲胺 作用下， 以 四氢呋喃 、 甲醇 、 水 为溶剂， 反应 36.5h， 生成 Methyl 3,5-bis[[3,5-bis[bis(2-methoxyethyl)carbamoyl]phenoxy]methyl]benzoate
  参考文献：
  名称：

  Dendrimers with Alternating Amine and Ether Generations

  摘要：

  Dendrimers having alternating aryl benzyl ether and tertiary amine generations and up to 16 bis-(2-methoxyethyl)amine end groups and four internal tertiary amines were synthesized by sequential etherification, amidation of secondary amines, and LiAlH4 reduction to tertiary amines. The bis-(2-methoxyethyl)amine dendrimers are soluble in common organic solvents and in aqueous buffer solutions at pH < 4.7. At 2.8 mM, the dendrimer increases the solubility of pyrene in water 30-fold, and the solvated pyrene is not aggregated.

  DOI：

  10.1021/jo991042c
• 作为产物：
  描述：

  5-羟基间苯二甲酸 在 氯化亚砜 作用下， 以 甲苯 为溶剂， 反应 13.0h， 生成 5-acetoxyisophthaloyl acid dichloride
  参考文献：
  名称：

  Dendrimers with Alternating Amine and Ether Generations

  摘要：

  Dendrimers having alternating aryl benzyl ether and tertiary amine generations and up to 16 bis-(2-methoxyethyl)amine end groups and four internal tertiary amines were synthesized by sequential etherification, amidation of secondary amines, and LiAlH4 reduction to tertiary amines. The bis-(2-methoxyethyl)amine dendrimers are soluble in common organic solvents and in aqueous buffer solutions at pH < 4.7. At 2.8 mM, the dendrimer increases the solubility of pyrene in water 30-fold, and the solvated pyrene is not aggregated.

  DOI：

  10.1021/jo991042c

文献信息

• [EN] ROMP-POLYMERIZABLE ELECTRON TRANSPORT MATERIALS BASED ON A BIS-OXADIAZOLE MOIETY<br/>[FR] MATIÈRES DE TRANSPORT D'ÉLECTRONS POLYMÉRISABLES PAR OUVERTURE DE CYCLE PAR MÉTATHÈSE(ROMP) À BASE D'UNE FRACTION BIS-OXADIAZOLE
  申请人：GEORGIA TECH RES INST

  公开号：WO2009080797A1

  公开（公告）日：2009-07-02

  This invention relates generally to a solution processable norbornene monomer, poly(norbornene) homopolymer, and poly(norbornene) copolymer compounds containing a functionalized bis -oxadiazole side chain, and to an electron injecting/transporting layer, a hole -blocking layer, or an emissive material, organic electronic devices and compositions which include these compounds.

  这项发明涉及一种可溶解的去甲基环戊烯单体、聚（去甲基环戊烯）均聚物和含有功能化双-噁二唑侧链的聚（去甲基环戊烯）共聚物化合物，以及电子注入/传输层、阻挡孔层或发光材料、有机电子器件和包括这些化合物的组合物。
• A Modular “Toolbox” Approach to Flexible Branched Multimacrocyclic Hosts as Precursors for Multiply Interlocked Architectures
  作者：Bilge Baytekin、Sascha S. Zhu、Boris Brusilowskij、Jens Illigen、Jenni Ranta、Juhani Huuskonen、Luca Russo、Kari Rissanen、Lena Kaufmann、Christoph A. Schalley

  DOI：10.1002/chem.200801289

  日期：2008.11.10

  cross-coupling reactions. A modular "toolbox" strategy is presented that allows 1) several tetralactam macrocycles to be covalently connected with each other or with a central spacer, 2) the macrocycles to be substituted with or connected to different chromophores, and 3) metal-coordination sites to be attached to the macrocycles. With this approach a series of different oligo-macrocyclic hosts was obtained with

  四内酰胺大环化合物可以通过多种交叉偶联反应进行官能化。提出了一种模块化的“工具箱”策略，该策略允许1）几个四内酰胺大环彼此或与一个中心间隔基共价连接，2）大环被不同的发色团取代或连接，以及3）金属配位位点附加到大环。通过这种方法，获得了一系列不同的寡聚-大环宿主，它们具有巨大的结构多样性和巨大的进一步功能化潜力。已经合成了基于这些大环化合物制备的轮烷，以证明其在构建更复杂的超分子体系中的效用。
• Columnar mesomorphism of bent-rod mesogens containing 1,2,4-oxadiazole rings
  作者：Hugo Gallardo、Marli Ferreira、André A. Vieira、Eduard Westphal、Fernando Molin、Juliana Eccher、Ivan H. Bechtold

  DOI：10.1016/j.tet.2011.10.019

  日期：2011.12

  In this study, the synthesis, characterization, and mesomorphic properties of ten new bent-rod compounds containing two units of 1,2,4-oxadiazoles are reported. In order to understand the relationship between the structure and the mesomorphic behavior, molecules containing a variety of polar substituents (i.e., I, NO2, NH2, OH) on the central rigid core were prepared. The hexagonal columnar mesomorphism

  在这项研究中，报道了含有两个单元的1,2,4-恶二唑的十种新的弯曲杆化合物的合成，表征和介晶性质。为了理解结构与介晶行为之间的关系，制备了在中央刚性核上包含多种极性取代基（即I，NO 2，NH 2，OH）的分子。通过DSC和POM表征六边形柱状的同质性，并通过XRD研究确定了中间相的性质。自组装的驱动力可以通过脂族部分和极性部分之间的微分离来解释，从而在单个圆盘内产生二聚体，三聚体和四聚体。
• PHOTOLYTIC ACID-GENERATING POLYMERS AND MONOMERS FOR THEIR CONSTRUCTION
  申请人：BRAINARD Robert L.

  公开号：US20110130538A1

  公开（公告）日：2011-06-02

  Polymers for photoresists and monomers for incorporation into those polymers are disclosed. The polymers comprise a photoacid generator (PAG) component and at least a second component that is photolytically stable and acid-stable. The polymers may also contain a third, acid-labile component. The photoacid generator is based on N-sulfoxyimides and related moieties that contain photolabile oxygen-heteroatom and oxygen-aromatic carbon bonds.

  本发明揭示了用于光刻胶的聚合物和用于纳入这些聚合物的单体。聚合物包括光酸发生器（PAG）组分和至少第二个组分，该组分具有光解稳定性和酸稳定性。聚合物还可以包含第三种酸不稳定的组分。光酸发生器基于N-磺酰氧亚胺和相关的含有光敏氧杂原子和氧芳香碳键的基团。
• Hyperbranched ether-ketone co-polymers
  申请人：The United States of America as represented by the Secretary of the Air Force

  公开号：US06743889B1

  公开（公告）日：2004-06-01

  Novel ether-ketone hyperbranched co-polymers are prepared by co-polymerizing 3,5-bis(4-fluorobenzoyl)phenol and 4-fluoro-4′-hydroxybenzophenone. The resulting copolymer has repeating units of the formula: wherein n has a value of 0.25 to 0.99.

  通过共聚合3,5-双(4-氟苯甲酰)苯酚和4-氟-4'-羟基苯酮，制备了新型的醚酮超支化共聚物。得到的共聚物具有以下重复单元的结构式：其中n的值为0.25至0.99。