acetic 2-phenoxybenzoic anhydride | 1434906-71-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: acetic 2-phenoxybenzoic anhydride
• 英文别名: Acetyl 2-phenoxybenzoate
• CAS: 1434906-71-4
• 化学式: C₁₅H₁₂O₄
• 分子量: 256.258
• InChiKey: OHHDXYRHMRWHSG-UHFFFAOYSA-N

物化性质

• 沸点：
  383.1±34.0 °C(Predicted)
• 密度：
  1.211±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  acetic 2-phenoxybenzoic anhydride 在 acethylacetonato(1,5-cyclooctadiene)rhodium(I) 、 potassium iodide 作用下， 以 乙酸酐 为溶剂， 反应 10.0h， 以88%的产率得到二苯并呋喃
  参考文献：
  名称：

  Rhodium-Catalyzed Decarbonylative C–H Arylation of 2-Aryloxybenzoic Acids Leading to Dibenzofuran Derivatives

  摘要：

  Rhodium-catalyzed intramolecular C-H arylation of 2-aryloxybenzoic acids proceeded accompanied by decarbonylation to give dibenzofuran derivatives in high yields. The present reaction is widely applicable to substrates bearing various functionalities.

  DOI：

  10.1021/ol4010905
• 作为产物：
  描述：

  乙酸酐 、 苯氧苯甲酸 反应 12.0h， 以62%的产率得到acetic 2-phenoxybenzoic anhydride
  参考文献：
  名称：

  Rhodium-Catalyzed Decarbonylative C–H Arylation of 2-Aryloxybenzoic Acids Leading to Dibenzofuran Derivatives

  摘要：

  Rhodium-catalyzed intramolecular C-H arylation of 2-aryloxybenzoic acids proceeded accompanied by decarbonylation to give dibenzofuran derivatives in high yields. The present reaction is widely applicable to substrates bearing various functionalities.

  DOI：

  10.1021/ol4010905

文献信息

• ELECTROSTATICALLY-APPLICABLE, HEAT-FUSABLE POWDER COATINGS AND ADDITIVES
  申请人：W.R. GRACE & CO.-CONN.

  公开号：EP1979518A2

  公开（公告）日：2008-10-15
• DISSOLUTION OF MONOSODIUM URATE TO TREAT GOUT
  申请人：Hooper, Mark

  公开号：EP3723741A1

  公开（公告）日：2020-10-21
• Electrostatically-Applicable, Heat-Fusable Powder Coatings and Additives
  申请人：Berke Neal S.

  公开号：US20090007822A1

  公开（公告）日：2009-01-08

  Coatings for metal substrate surfaces comprise at least one film forming polymer is combined with microfine, substantially moisture-free cementitious particles. Preferred methods involve fusion bonded coating applications, wherein dry powder blends comprising polymer and the cementitious particles which preferably containing a corrosion inhibiting agent are electrostatically applied and heat-fused onto the metal.
• Methods of Treatment of Gout
  申请人：Hooper Mark

  公开号：US20210077420A1

  公开（公告）日：2021-03-18

  This invention provides a solubility enhancer for monosodium urate for use in the treatment of gout. The solubility enhancer may be a pharmaceutically acceptable base, a solvent, a lipid, a surfactant, a pharmaceutically acceptable acid, a cyclodextrin, at least one paraben or a combination thereof.
• [EN] ELECTROSTATICALLY-APPLICABLE, HEAT-FUSABLE POWDER COATINGS AND ADDITIVES<br/>[FR] ENDUITS ET ADDITIFS EN POUDRE POUVANT ETRE FONDUS THERMIQUEMENT ET APPLIQUES ELECTROSTATIQUEMENT
  申请人：GRACE W R & CO

  公开号：WO2007078526A2

  公开（公告）日：2007-07-12

  [EN] Coatings for metal substrate surfaces comprise at least one film forming polymer is combined with microfme, substantially moisture-free cementitious particles. Preferred methods involve fusion bonded coating applications, wherein dry powder blends comprising polymer and the cementitious particles which preferably containing a corrosion inhibiting agent are electrostatically applied and heat-fused onto the metal.
  [FR] La présente invention concerne des enduits pour des surfaces de substrats métalliques qui comprennent au moins un polymère filmogène combiné à des particules cimentaires microfines pratiquement exemptes d'humidité. Les procédés préférés comprennent des applications d'enduits collés par fusion dans lesquels des mélanges de poudres sèches comprenant le polymère et les particules cimentaires et contenant de préférence un agent anti-corrosion sont appliqués électrostatiquement et fondus thermiquement sur le métal.