Mn(η-cyclopentadienyl)(carbonyl)2(py) | 12088-91-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Mn(η-cyclopentadienyl)(carbonyl)2(py)
• 英文别名: CpMn(CO)₂(pyridine)；(cyclopentadienyl)Mn(CO)2(pyridine)；(η6-C5H5)Mn(CO)2(pyridine)；CpMn(CO)2(pyridine)
• CAS: 12088-91-4
• 化学式: C₁₂H₁₀MnNO₂
• 分子量: 255.155
• InChiKey: PHUAFGPDXCUCNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.32
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  14.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Mn(η-cyclopentadienyl)(carbonyl)2(py) 在 sodium naphthalenide 作用下， 以 四氢呋喃 为溶剂， 生成 Na2(Mn(η-cyclopentadienyl)(carbonyl)2)
  参考文献：
  名称：

  Leong, Voon S.; Cooper, N. John, Organometallics, 1988, vol. 7, # 9, p. 2080 - 2081

  摘要：

  DOI：
• 作为产物：
  描述：

  dicarbonyl(η(2)-hydroxypropyne)(η(5)-cyclopentadienyl)manganese 在 吡啶 作用下， 以 吡啶 为溶剂， 生成 三羰基(η-环戊二烯基)合锰 、 Mn(η-cyclopentadienyl)(carbonyl)2(py)
  参考文献：
  名称：

  Synthesis and properties of (?5-cyclopentadienyl)-(?2-2-propyn-1-ol)dicarbonylmanganese

  摘要：

  DOI：

  10.1007/bf00955989

文献信息

• Displacement Kinetics of η²-Bound Furan and 2,3-Dihydrofuran from Mn and Cr Centers: Evidence for the Partial Dearomatization of the Furan Ligand
  作者：Jeremy R. Andreatta、G. Benjamin Cieslinski、Madeeha Batool、Xue-Zhong Sun、Michael W. George、Edward N. Brothers、Donald J. Darensbourg、Ashfaq A. Bengali

  DOI：10.1021/ic900724f

  日期：2009.8.17

  The displacement of eta(2)-coordinated ligands from the photolytically generated CpMn(CO)(2)L and BzCr(CO)(2)L [Cp = eta(5)-C5H5, Bz = eta(6)-C6H6, L =2,3-dihydrofuran (DHF), furan] complexes by pyridine has been studied. The displacement reactions span a wide range of time scales from microseconds to hours and were studied using a range of time-resolved IR spectroscopic techniques. The substitution reactions follow a dissociative pathway and the measured activation enthalpies provide an estimate for the strength of the metal-(eta(2)-furan) and metal-(eta(2)-DHF) interactions. In these complexes, the Cr center binds both ligands weaker than the Mn center, There is a similar to 6-10 kcal/mol difference in the binding enthalpies of eta(2)-furan and eta(2)-DHF to both metals suggesting that this difference is the result of a partial loss of resonance energy in the case of the aromatic furan ligand upon interaction with the metal.
• KALININ, V. N.;DERUNOV, V. V.;LUSENKOVA, M. A.;PETROVSKY, P. V.;KOLOBOVA,+, J. ORGANOMET. CHEM., 379,(1989) N, C. 303-309
  作者：KALININ, V. N.、DERUNOV, V. V.、LUSENKOVA, M. A.、PETROVSKY, P. V.、KOLOBOVA,+

  DOI：——

  日期：——
• Reactions of vinylidene and allenylidene cymantrene derivatives with isonitriles
  作者：V.N. Kalinin、V.V. Derunov、M.A. Lusenkova、P.V. Petrovsky、N.E. Kolobova

  DOI：10.1016/0022-328x(89)85170-8

  日期：1989.12