1-(4-hydroxylphenyl)-1-(4-methylphenyl)-1-(6-oxido-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)ethane | 1577219-53-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-hydroxylphenyl)-1-(4-methylphenyl)-1-(6-oxido-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)ethane
• 英文别名: 4-[1-(4-Methylphenyl)-1-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl]phenol
• CAS: 1577219-53-4
• 化学式: C₂₇H₂₃O₃P
• 分子量: 426.452
• InChiKey: GCXDLNAHGYCLDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.63
• 重原子数：
  31.0
• 可旋转键数：
  3.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  46.53
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  1-(4-hydroxylphenyl)-1-(4-methylphenyl)-1-(6-oxido-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)ethane 、 乙酸酐 在 sodium acetate 作用下， 反应 12.0h， 以92%的产率得到1-(4-acetoxyphenyl)-1-(4-methylphenyl)-1-(6-oxido-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)ethane
  参考文献：
  名称：

  次膦酸乙酰氧基苯甲酸的合成及其在提高聚对苯二甲酸乙二醇酯的Tg和阻燃性中的应用

  摘要：

  一种新的次膦酸乙酰氧基苯甲酸1-（4-乙酰氧基苯基）-1-（4-羧基苯基）-1-（6-氧化-6H-二苯甲 <1,2>氧代磷酰-6-6基）乙烷（ 3）是通过三步过程准备的。制备了基于（3）与聚对苯二甲酸乙二醇酯（PET）的酸解和缩聚反应的磷化共聚酯。共聚酯的结晶度随着（3）含量的增加而逐渐降低，如广角X射线衍射图和差示扫描量热法热分析图所示。动态力学分析和热力学分析显示T g随着（3）的内容而增加。UL‐94阻燃测试表明，随着（3）含量的增加，PET的阻燃性得到了提高，磷含量低至1.43 wt％时，可以获得UL‐94 V-0级的共聚酯。©2013 Wiley Periodicals，Inc. J. Polym。科学，A部分：Polym。化学 2014，52，424-434

  DOI：

  10.1002/pola.27017
• 作为产物：
  描述：

  对甲基苯乙酮 、 苯酚 、 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 在 对甲苯磺酸 作用下， 反应 12.0h， 以50%的产率得到1-(4-hydroxylphenyl)-1-(4-methylphenyl)-1-(6-oxido-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)ethane
  参考文献：
  名称：

  次膦酸乙酰氧基苯甲酸的合成及其在提高聚对苯二甲酸乙二醇酯的Tg和阻燃性中的应用

  摘要：

  一种新的次膦酸乙酰氧基苯甲酸1-（4-乙酰氧基苯基）-1-（4-羧基苯基）-1-（6-氧化-6H-二苯甲 <1,2>氧代磷酰-6-6基）乙烷（ 3）是通过三步过程准备的。制备了基于（3）与聚对苯二甲酸乙二醇酯（PET）的酸解和缩聚反应的磷化共聚酯。共聚酯的结晶度随着（3）含量的增加而逐渐降低，如广角X射线衍射图和差示扫描量热法热分析图所示。动态力学分析和热力学分析显示T g随着（3）的内容而增加。UL‐94阻燃测试表明，随着（3）含量的增加，PET的阻燃性得到了提高，磷含量低至1.43 wt％时，可以获得UL‐94 V-0级的共聚酯。©2013 Wiley Periodicals，Inc. J. Polym。科学，A部分：Polym。化学 2014，52，424-434

  DOI：

  10.1002/pola.27017

文献信息

• MONOFUNCTIONAL, BIFUNCTIONAL, AND MULTIFUNCTIONAL PHOSPHINATED PHENOLS AND THEIR DERIVATIVES AND PREPARATION METHOD THEREOF
  申请人：LIN CHING-HSUAN

  公开号：US20130012668A1

  公开（公告）日：2013-01-10

  The present invention provides novel phosphinated compounds of monofunctional, bifunctional, multifunctional phenols represented by the following formulae and their derivatives, and preparation methods thereof:

  本发明提供了以下通式表示的新型磷酸化单官能、双官能、多官能酚化合物及其衍生物，以及它们的制备方法：
• PHOSPHORUS-CONTAINING BISPHENOLS AND PREPARING METHOD THEREOF
  申请人：LIN Ching-Hsuan

  公开号：US20100016585A1

  公开（公告）日：2010-01-21

  The Phosphorus-containing bisphenols and preparing method thereof are disclosed. A method for producing the phosphorus-containing bisphenol of the general formula (1) includes reacting compounds respectively defined by a general formula (a), (b), (c) and an acid catalyst to yield compounds of phosphorus-containing bisphenol.

  揭示了含磷双酚类化合物及其制备方法。一种生产一般式（1）所定义的含磷双酚类化合物的方法包括将分别由一般式（a）、（b）、（c）定义的化合物与酸催化剂反应，得到含磷双酚类化合物。
• STABLE SOLUTION OF RING-OPENED POLYMER AND THE USE THEREOF
  申请人：Wu Hsin-Ho

  公开号：US20130101862A1

  公开（公告）日：2013-04-25

  A stable solution of a ring-opened polymer is provided. The stable solution can be prepared using the following steps: (d) adding an N,O-heterocyclic compound of formula I or II and a DOPO-based compound into an organic solvent to provide a reaction solution: wherein R1 to R3, W1, W2, m, n, p and q are as defined in the specification. (e) heating the reaction solution to carry out a ring-opening reaction to provide a polymer solution; and (f) cooling the polymer solution to obtain the stable solution, wherein the organic solvent is unreactive to the N,O-heterocyclic compound and the DOPO-based compound, and the amount of the DOPO-based compound is about 0.01 wt % to about 50 wt % based on the total weight of the N,O-heterocyclic compound and the DOPO-based compound. The stable solution is useful as a self-crosslinkable resin or a hardener for hardening epoxies.
• RESIN COMPOSITION AND USES OF THE SAME
  申请人：Wu Hsin-Ho

  公开号：US20130122308A1

  公开（公告）日：2013-05-16

  A resin composition is provided. The resin composition comprises: an epoxy resin; and a hardener, which is a stable solution obtainable from the following steps: (a) adding a N,O-heterocyclic compound of formula I or II and a DOPO-based compound into an organic solvent to provide a reaction solution: wherein R1 to R3, W1, W2, m, n, p and q are as defined in the specification; (b) heating the reaction solution to carry out a ring-opening reaction to provide a polymer solution; and (c) cooling the polymer solution to obtain the stable solution, wherein the organic solvent is unreactive to the N,O-heterocyclic compound and the DOPO-based compound, and the amounts of the DOPO-based compound and the hardener are as defined in the specification.
• US8134021B2
  申请人：——

  公开号：US8134021B2

  公开（公告）日：2012-03-13