trans-bis((diphenylthio)ethane)dichlororuthenium(II) | 32648-33-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-bis((diphenylthio)ethane)dichlororuthenium(II)
• 英文别名: dichlororuthenium;2-phenylsulfanylethylsulfanylbenzene
• CAS: 32648-33-2
• 化学式: C₂₈H₂₈Cl₂RuS₄
• 分子量: 664.77
• InChiKey: NSVGNIAZMKWIHY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  10.52
• 重原子数：
  35.0
• 可旋转键数：
  4.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  trans-bis((diphenylthio)ethane)dichlororuthenium(II) 、 lithium iodide 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and spectroscopic studies of ruthenium(II) selenoether complexes: Structure oftrans-[Ru&{PhSe(CH2)2SePh}2Cl2]

  摘要：

  The complexes trans-[Ru(L-L)2X2] [X = Cl, Br or I; L-L = bidentate ligand including PhSe(CH2)2SePh, MeSe(CH2)2SeMe and o-C6H4(TeMe)2] have been prepared by reaction of RuCl3 . xH2O and LiX with the ligand in alcoholic solvents in the presence of a reducing agent. The complexes have been characterized by analysis, IR, UV-vis and Se-77 or Te-125 NMR spectroscopies and the Ru(II)-Ru(III) redox potentials established by cyclic voltammetry. The crystal structure of trans-[Ru{PhSe(CH2)2SePh}2Cl2] has been determined, giving Ru-Cl 2.413(1), 2.444(1), Ru-Se 2.433(1)-2.460(1) angstrom.

  DOI：

  10.1016/s0277-5387(00)83004-1
• 作为产物：
  描述：

  水合三氯化钌 、 1,2-联苯硫基乙烷 在 hypophosphorous acid 作用下， 以 乙二醇甲醚 为溶剂， 生成 trans-bis((diphenylthio)ethane)dichlororuthenium(II)
  参考文献：
  名称：

  较高氧化态的配位化学。第41部分。阳离子钌（III）15和16供体配体配合物的合成，光谱和电化学研究。的结构的反式- [{茹Ç 6 ˚F 4（ASME 2）2 - ø } 2溴2 ] BF 4

  摘要：

  配合物反式-[Ru（L–L）2 X 2 ] BF 4 [X = Cl或Br; L–L =双齿配体，包括C 6 H 4（PMe 2）2 - o，C 6 H 4（AsMe 2）2 - o，C 6 F 4（AsMe 2）2 - o，Me 2 PCH 2 CH 2 PMe 2，苯2 PCH 2 CH 2 PPh2，Ph 2 AsCHCHAsPh 2，C 6 H 4（PPh 2） 2 - o，C 6 F 4（PPh 2） 2 - o，MeSCH 2 CH 2 SMe，PhSCH 2 CH 2 SPh和PhSeCH 2 CH 2 SePh]具有通过在HBF 4水溶液中硝酸氧化相应的[Ru（L–L） 2 X 2 ]制备以及其他方式。通过分析，IR和UV / VIS光谱，磁测量以及通过循环伏安法建立的Ru II –Ru III氧化还原电位来表征复合物。确定了反式-[Ru {C 6 F 4（AsMe 2）2

  DOI：

  10.1039/dt9920003243

文献信息

• Curtis, Jeff C.; Bernstein, James S.; Meyer, Thomas J., Inorganic Chemistry, 1985, vol. 24, # 3, p. 385 - 397
  作者：Curtis, Jeff C.、Bernstein, James S.、Meyer, Thomas J.

  DOI：——

  日期：——
• Synthesis and characterization of dithioethers, and their RuII and RuIII complexes
  作者：Elizabeth L.S. Cheu、Donald T.T. Yapp、Brian O. Patrick、Brian R. James

  DOI：10.1016/j.ica.2019.04.056

  日期：2019.8

  The syntheses of nine, new dithioethers of the type RS(CH2)(x)SR, where x = 2 or 3 and R is an alkyl chain, as well as the known x = 2, R = phenyl or cyclohexyl compounds, are reported. The known dithioethers react with RuCl3 center dot 3H(2)O to form trans-RuCl2(dithioether) 2 complexes 1 (R = Ph) and 2 (R = C6H11), whereas from the other dithioethers RuCl2[RS(CH2)(x)SR](2)(mu-Cl)(2) complexes have been isolated, where x = 3, and R = Et (complex 3), Pr-n (complex 4), Bu-n (complex 5), and R = (n)pentyl (complex 6). The complexes are well characterized, including X-ray structures for complexes 1-4. The interest in these compounds stems from oxidation of the dithioethers to the corresponding disulfoxides and their Ru complexes.
• ——
  作者：K. Q. Shawakfeh、N. A. F. Al-Rawashdeh、S. Khader

  DOI：10.1023/a:1021158931775

  日期：——

  The complexation reaction of trans-[RuCl2(Dpte)(2)] (Dpte - (diphenylthio)ethane) with mixed diimine ligands 2,2'-bipyridine, pyridylquinoline, 4,6-dichloro-2-(2-pyridyl)pyrimidine, 4,6-dichloro-5-methyl-2-(2-pyridyl)pyrimidine, and 4,6-dichloro-5-phenyl-2-(2-pyridyl)pyrimidine produces new Ru(II) mixed-ligand complexes. These complexes exhibit maximum photo- and chemical stability and high absorptivity. The above complexes have been characterized using IR, H-1 and C-13 NMR, electronic absorption spectroscopy, and elemental analysis.