2,2-[(1,3-dimethyl-1,3-propanediylidene)dinitrilo]bis-benzenethiol | 59862-11-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: 2,2-[(1,3-dimethyl-1,3-propanediylidene)dinitrilo]bis-benzenethiol
• 英文别名: di(2-benzenethiol)acetylacetone；2,4-bis-(2-mercaptophenylimino)pentane；bis(2-aminothiophenol)acetylacetimine；(2-HSC6H4NC)2CH2；2-({-1-Methyl-3-[(2-sulfanylphenyl)imino]butylidene}-amino)-1-benzenethiol；2-[4-(2-sulfanylphenyl)iminopentan-2-ylideneamino]benzenethiol
• CAS: 59862-11-2
• 化学式: C₁₇H₁₈N₂S₂
• 分子量: 314.475
• InChiKey: QEIXQOPGYRQBJI-UHFFFAOYSA-N

物化性质

• 沸点：
  453.7±45.0 °C(Predicted)
• 密度：
  1.14±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  26.7
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,2-[(1,3-dimethyl-1,3-propanediylidene)dinitrilo]bis-benzenethiol 在 RuHCl(CO)(PPh₃)2(C₅H₁₁N) or RuHClCO(AsPh₃)2C₅H₁₁N 、 or RuH₂(CO)(PPh₃)2C₅H₁₁N or RuH₂(CO)(AsPh₃)2C₅H₁₁N 作用下， 以 苯 为溶剂， 生成 [Ru(CO)(piperidine)(atpacac)]
  参考文献：
  名称：

  Viswanathamurthi; Geetha; Karvembu, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2005, vol. 44, # 1, p. 90 - 93

  摘要：

  DOI：
• 作为产物：
  描述：

  2-氨基苯硫醇 、 乙酰丙酮 以 乙醇 为溶剂， 生成 2,2-[(1,3-dimethyl-1,3-propanediylidene)dinitrilo]bis-benzenethiol
  参考文献：
  名称：

  Novel selective thiocyanate PVC membrane electrode based on new Schiff base complex of 2.2-[(1,3-dimethyl-1,3-propanediylidene)dinitrilo]bis-benzenethiolato cadmium(ii)

  摘要：

  本研究介绍了一种以络合物为离子载体的硫氰酸盐离子选择性电极。研究了膜成分、pH 值和干扰阴离子的影响。该传感器对硫氰酸盐的响应在 1 × 10-6-1 × 10-1 M 的线性范围内，斜率为 -58.9 ± 0.5 mV 10-1。检测限为 5 × 10-7 M SCN-。用固定干扰法（FIM）测定的选择性系数表明，与其他阴离子相比，SCN- 离子具有良好的鉴别能力。所提出的传感器响应速度快，约为 5-20 秒，至少可使用 2 个月而不会出现电位偏差。它被用作指示电极，用于用 Ag+ 滴定硫氰酸盐，以及唾液和尿液样品中硫氰酸盐的电位测定。

  DOI：

  10.1039/b400681j

文献信息

• SYNTHESIS AND CHARACTERIZATION OF NEW RUTHENIUM(III) COMPLEXES CONTAINING TETRADENTATE SCHIFF BASES
  作者：T. Daniel Thangadurai、K. Natarajan

  DOI：10.1081/sim-100104786

  日期：2001.4.30

  Several new hexa-coordinated ruthenium(Ill) complexes of the type [RuX(EPh3)(LL')] (X = Cl, Br; E = P, As; LL' = anthacac, anthdibm, 2-amtpacac or 2-amtpdibm) have been synthesised by reacting [RUCl3(PPh3)(3)], [RUCl3(AsPh3)(3)], [RuBr3(AsPh3)(3)] or [RuBr3(PPh3)(2)(MeOH)] with tetradentate Schiff bases such as bis(anthranilic acid)acetylacetimine (H-2-anthacac), bis(anthranilic acid)dibenzoylmethimine (H-2-anthdibm), bis(2-aminothiophenol)acetylacetimine (H-2-2-amptacac) or bis(2-aminothiophenol)dibenzoylmethimine (H-2-2-amtpdibm). All of the complexes have been characterised by elemental analyses, IR, electronic spectra, EPR, magnetic moment and cyclic voltammetric data. An octahedral structure has been tentatively proposed for the complexes. These complexes were also tested for their antibacterial properties.
• Pathak, A. K.; Mittal, A. K.; Shukla, P. L., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 163 - 182
  作者：Pathak, A. K.、Mittal, A. K.、Shukla, P. L.

  DOI：——

  日期：——
• Mittal, A. K.; Shukla, A.; Shukla, P. R., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 739 - 760
  作者：Mittal, A. K.、Shukla, A.、Shukla, P. R.、Pathak, A. K.、Ahmad, N.

  DOI：——

  日期：——
• SYNTHESIS AND CHARACTERIZATION OF SOME NEW MONOPHENYLANTIMONY(III) DERIVATIVES OF BIFUNCTIONAL TETRADENTATE LIGANDS
  作者：Rajendra K. Sharma、Yashpal Singh、Audhesh K. Rai

  DOI：10.1081/sim-100002228

  日期：2001.3.31

  Monophenylantimony(III) derivatives of bifunctional tetradentate ligands having the general formula PhSb[RC(NC6H4S)CH2 (NC6H4S) CR1] where R=CH3, R'=CH3,C6H5 and 4-CH3C6H4; R=CF3, R-1=CF3 and -C=CH-CH=CHS have been prepared by the reactions of triphenylantimony(III) and the corresponding ligands. These compounds have been characterised by elemental analyses, molecular weight determinations, IR,H-1, C-13 and F-19 NMR spectral studies.
• IRON CONTROL COMPOSITION, MAKE, AND USE IN CARBONATE STIMULATION
  申请人：King Fahd University of Petroleum and Minerals

  公开号：US20200332178A1

  公开（公告）日：2020-10-22

  Well stimulating fluids and methods use a first and a second chelating agent, e.g., diethylene triamine pentaacetic acid (DTPA), glutamic diacetic acid (GLDA), and/or hydroxyethyl ethylene diamine triacetic acid (HEDTA), particularly in amounts of from 1 to 10 wt. %, to control iron precipitation during the stimulation process. Such fluids can stabilize iron ions without precipitation to manage the efficiency and performance of the stimulation fluid. Such stimulation fluids can be used with for highly concentrated HCl solutions, e.g., more than 20 up to 28 wt. % or more, that is useful in emulsified acid formulations in acid fracturing or acidizing of carbonate formations.