p-tolyl(trichloromethyl)carbinol acetate | 66681-70-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-tolyl(trichloromethyl)carbinol acetate
• 英文别名: acetic acid-(2,2,2-trichloro-1-p-tolyl-ethyl ester)；Essigsaeure-(2,2,2-trichlor-1-p-tolyl-aethylester)；(+/-)-2.2.2-Trichlor-1-acetoxy-1-p-tolyl-aethan；(+/-)-(2.2.2-Trichlor-1-p-tolyl-aethyl)-acetat；[2,2,2-Trichloro-1-(4-methylphenyl)ethyl] acetate
• CAS: 66681-70-7
• 化学式: C₁₁H₁₁Cl₃O₂
• 分子量: 281.566
• InChiKey: RPASHMXAISBXDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  p-tolyl(trichloromethyl)carbinol acetate 在 samarium diiodide 作用下， 以 四氢呋喃 为溶剂， 反应 0.05h， 以92%的产率得到1-(2,2-二氯乙烯基)-4-甲基苯
  参考文献：
  名称：

  SmI2-mediated elimination reaction of trichloromethyl carbinols: a facile method to synthesize vinyl dichlorides

  摘要：

  Samarium diiodide-mediated elimination reaction provides a simple and general method to synthesize vinyl dichlorides from trichloromethyl carbinols directly in good to excellent yields. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2003.10.085
• 作为产物：
  描述：

  1-(p-methylphenyl)-2,2,2-trichloroethyl p-toluenesulphonate 以 乙醇 、 水 为溶剂， 生成 p-tolyl(trichloromethyl)carbinol acetate
  参考文献：
  名称：

  Lima, Carmem de; Santos, Isaias dos; Rosa, Sergio Mauro Cordova da, Journal of the Chemical Society. Perkin transactions II, 1990, p. 2099 - 2102

  摘要：

  DOI：

文献信息

• Reeve, Wilkins; McKee, James R.; Brown, Robert, Canadian Journal of Chemistry, 1980, vol. 58, p. 485 - 493
  作者：Reeve, Wilkins、McKee, James R.、Brown, Robert、Lakshmanan, Sitarama、McKee, Gertrude A.

  DOI：——

  日期：——
• Aryltrichloromethylcarbinols
  作者：Ernst D. Bergmann、David Ginsburg、David Lavie

  DOI：10.1021/ja01167a051

  日期：1950.11
• DE2644590
  申请人：——

  公开号：——

  公开（公告）日：——
• A general model for short-term interest rates
  作者：Ching-Fan Chung、Mao-Wei Hung

  DOI：10.1080/000368400322813

  日期：2000.2

  A general one-factor model for short-term interest rates is proposed. Besides the long memory fractionally integrated mean process, the model also consists of a power function: of the interest rate as well as the GARCH effect in the conditional variance. The estimation results show that, while there is no evidence for fractional integration in the mean beyond the well-known martingale property, both the power function of the interest rate: and the GARCH effect (but not the ARCH effect) are highly significant in-the formation of the conditional variance. Test results also confirm a structure change in October 1979 due to the shift in the Federal Reserve monetary policy.
• Insecticidal Action of Heterocyclic Analogs of 2,2,2-Trichloro - 1 - (p-chlorophenyl)-ethanol¹
  作者：R. C. Blinn、F. A. Gunther、R. L. Metcalf

  DOI：10.1021/ja01630a009

  日期：1954.1