2-羟乙基乙烯基亚硝胺 | 705-75-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代羰基化合物
• 中文名称: 2-羟乙基乙烯基亚硝胺
• 英文名称: O-Ethyl N-Cyclohexylthiocarbamate
• 英文别名: N-Cyclohexyl-aethylthioncarbamat；cyclohexyl-thiocarbamic acid O-ethyl ester；Cyclohexyl-thiocarbamidsaeure-O-aethylester；Cyclohexlthiocarbamidsaeure-O-aethylester；Cyclohexylthiourethan；O-ethyl N-cyclohexylcarbamothioate
• CAS: 705-75-9
• 化学式: C₉H₁₇NOS
• 分子量: 187.306
• InChiKey: UYANNGUAFHMQBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  53.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-羟乙基乙烯基亚硝胺 、 乙二胺 反应 6.0h， 生成 2-(2'-Aminoethylamino)-Δ²-imidazoline
  参考文献：
  名称：

  Reynaud, Pierre; Brion, Jean-Daniel; Davrinche, Catherine, Journal of Heterocyclic Chemistry, 1980, vol. 17, p. 1789 - 1792

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N'-二环己基硫脲 在 氢氧化钾 、 glassy phosphoric acid 作用下， 生成 2-羟乙基乙烯基亚硝胺
  参考文献：
  名称：

  Skita; Rolfes, Chemische Berichte, 1920, vol. 53, p. 1255

  摘要：

  DOI：

文献信息

• Syntheses of N-alkyl, N,N-dialkyl, and N-(4-substituted phenyl) O-ethyl thioncarbamates: a kinetic study
  作者：Milutin M. Milosavljević、Aleksandar D. Marinković、Vlada B. Veljković、Dragan D. Milenković

  DOI：10.1007/s00706-011-0596-1

  日期：2012.1

  AbstractThe kinetics of the syntheses of N-alkyl, N,N-dialkyl, and N-(4-substituted phenyl) O-ethyl thioncarbamates from sodium ethyl xanthogenacetate, ten alkylamines, and eight substituted anilines were studied at 25, 30, 35, and 40 °C. The reactions were found to follow second-order kinetics. The kinetic (Arrhenius) parameters, such as the activation energy and the frequency factor, as well as the

  摘要N-烷基，N，N-二烷基和N-（4-取代的苯基）O的合成动力学在25、30、35和40°C下研究了由黄原酸乙酯钠，十个烷基胺和八个取代的苯胺生成的亚乙基乙基氨基甲酸酯。发现反应遵循二级动力学。由二阶速率计算出动力学（Arrhenius）参数，例如活化能和频率因子，以及Eyring参数，例如标准熵，标准吉布斯能量和标准活化焓。常数。根据提出的动力学研究和使用MOPAC PM6半经验方法对反应机理进行了优化，推测了反应机理。 图形概要
• Impregnated porous granules with slow-release pore membranes, and process for the manufacture thereof
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0005302A2

  公开（公告）日：1979-11-14

  Open-ended pores of a porous granule are filled with a liquid material which is at least partially immiscible with water, and sealed with a porous polyurea membrane which limits the release rate of the material into the surrounding medium. The membrane is formed by (a) applying to the bare granule an organic solution comprising the liquid material and an organic polyisocyanate, followed by (b) applying to the granule an aqueous solution comprising water and a catalytic amount of a catalyst selected from the group consisting of a basic organic tertiary amine and an alkyl tin carboxylate.

  在多孔颗粒的开口孔中填充至少部分与水不相溶的液态材料，并用多孔聚脲膜密封，以限制材料释放到周围介质中的速度。聚脲膜的形成过程如下 (a) 在裸颗粒上涂抹由液态材料和有机多异氰酸酯组成的有机溶液，然后 (b) 对颗粒施加水溶液，该水溶液由水和一定量的催化剂组成，催化剂选自碱性有机叔胺和烷基羧酸锡。
• A method for the control of Galium Aparine
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0147683A2

  公开（公告）日：1985-07-10

  @ Disclosed herein is a method of controlling undesirable vegetation which comprises the application to the locus desired of a herbicidal composition comprising a herbicide selected from the group consisting of S-benzyl dipropylthiocarbamate, S-benzyl 2,5-dimethylpiperidine-1-carbothioate, S-benzyl methyl isopropyl thiocarbamate, S-benzyl propyl allyl thiocarbamate, S-benzyl ethyl cyclohexyl thiocarbamate, s-benzyl ethyl-sec-butyl thiocarbamate, S-(4-chlorobenzyl) dipropyl thiocarbamate, and S-benzyl isopropylsec-butyl thiocarbamate.

  本文公开了一种控制不良植被的方法，该方法包括向所需位置施用除草组合物，该组合物包含选自以下组别的除草剂：S-苄基二丙基硫代氨基甲酸酯、S-苄基 2,5-二甲基哌啶-1-硫代甲酸酯、S-苄基甲基异丙基硫代氨基甲酸酯、S-苄基丙基烯丙基硫代氨基甲酸酯、S-苄基乙基环己基硫代氨基甲酸酯、S-苄基乙基仲丁基硫代氨基甲酸酯、S-(4-氯苄基)二丙基硫代氨基甲酸酯和 S-苄基异丙基仲丁基硫代氨基甲酸酯。
• Substituted 4-fluorothiocarbanilide herbicidal compounds and methods of use
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0174680A1

  公开（公告）日：1986-03-19

  A compound having the structural formula R1 is C1-C4 alkyl, preferably ethyl and isopropyl and C1-C4 alkenyl, preferably C3-alkenyl ; and R2 is selected from the group consisting of C1-C3 alkyl, preferably ethyl and C2-C3 alkoxyalkyl; and its use as a herbicide.

  结构式如下的化合物 R1 是 C1-C4 烷基（最好是乙基和异丙基）和 C1-C4 烯基（最好是 C3-烯基）；以及 R2 选自 C1-C3 烷基（最好是乙基）和 C2-C3 烷氧基烷基组成的组；及其作为除草剂的用途。
• Sladowska; Bartoszko-Malik; Zawisza, Il Farmaco, 1990, vol. 45, # 1, p. 111 - 121
  作者：Sladowska、Bartoszko-Malik、Zawisza

  DOI：——

  日期：——