2,6-diacetoxy-anthraquinone | 1747-94-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,6-diacetoxy-anthraquinone
• 英文别名: 2,6-Diacetoxy-anthrachinon；2,6-Dihydroxy-anthrachinondiacetat；2,6-Diacetoxy-9,10-anthrachinon；2,6-Diacetoxy-9,10-anthraquinone；(6-acetyloxy-9,10-dioxoanthracen-2-yl) acetate
• CAS: 1747-94-0
• 化学式: C₁₈H₁₂O₆
• 分子量: 324.29
• InChiKey: BHWZEQPVLJDOIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  86.7
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 海关编码：
  2915390090

反应信息

• 作为反应物：
  描述：

  2,6-diacetoxy-anthraquinone 在 盐酸 、 溶剂黄146 、 苯 作用下， 生成 1-chloro-9,10-diphenyl-anthracene-2,6-diol
  参考文献：
  名称：

  Etienne; Salmon, Bulletin de la Societe Chimique de France, 1954, p. 1127,1131

  摘要：

  DOI：
• 作为产物：
  描述：

  2,6-二羟基蒽醌 、 乙酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以58%的产率得到2,6-diacetoxy-anthraquinone
  参考文献：
  名称：

  动态硼酸酯键自组装胶囊的客体封装特性

  摘要：

  两分子四（二羟基硼基）-空腔和 1a 作为芳香腔，四分子 1,2-双（3,4-二羟基苯基）乙烷 2 作为赤道连接体通过形成八动态硼酸酯自组装成胶囊 3a CDCl(3) 或 C(6)D(6) 中的键。胶囊 3a 在高度选择性识别事件中封装了一个客体分子，例如 4,4'-二取代-联苯和 2,6-二取代-蒽衍生物，其中客体取代基定向到 3a 的两个芳香腔末端，如证实通过 (1)H NMR 研究和 X 射线晶体学分析。胶囊 3a 显示出对客体封装的显着溶剂效应。3a 与客人在 C(6)D(6) 中的关联常数 (K(a)) 比在 CDCl(3) 中的要大得多（450-48,000 倍）。C(6)D(6) 中 3a 内客体的封装是由焓驱动的，而CDCl(3) 中的趋向于同时受焓和熵驱动。热力学研究表明，CDCl(3) 中较小的 K(a) 值源于 CDCl(3) 作为 3a 的竞争客体分子的特性，而不是源于

  DOI：

  10.1021/ja9084918

文献信息

• Thermotropic polyesters of 2,6-dihydroxy-anthraquinone, the production thereof, moulding powders, fibres and melts produced from these polyesters
  申请人：CELANESE CORPORATION

  公开号：EP0018709A1

  公开（公告）日：1980-11-12

  A thermotropic wholly aromatic polyester is provided which is capable of forming an anisotropic melt phase. This novel polyester displays surprising tractability and may be used as a moulding resin or may be melt spun into fibres. The aromatic polyester of the present invention consists essentially of the recurring units (a) 2,6,-dioxyanthraquinone moiety, (b) 4-oxybenzoyl moiety, and (c) aromatic diacid moiety. The resulting polyester exhibits a melting point below approximately 375°C, and preferably below approximately 350°C. Fibres which are melt spun from the polyester exhibit unexpectedly good thermal stability. The desirable tractability properties of the polyester are attributed to its anisotropic melt phase, which is due to the inclusion of the 2,6-dioxyanthraquinone moiety in the polymer.

  我们提供了一种可形成各向异性熔融相的热致性全芳香族聚酯。这种新型聚酯具有惊人的可塑性，可用作模塑树脂，也可熔融纺丝成纤维。本发明的芳香族聚酯主要由以下重复单元组成：(a) 2,6,-二氧蒽醌分子；(b) 4-氧苯甲酰基分子；(c) 芳香族二酸分子。所得聚酯的熔点低于约 375°C，最好低于约 350°C。用这种聚酯熔融纺丝制成的纤维具有出乎意料的良好热稳定性。这种聚酯之所以具有理想的可塑性，是因为聚合物中含有 2,6-二氧蒽醌分子，从而形成了各向异性的熔融相。
• Wholly aromatic polyester capable of forming an anisotropic melt phase at an advantageously reduced temperature
  申请人：CELANESE CORPORATION

  公开号：EP0067618A2

  公开（公告）日：1982-12-22

  An improved wholly aromatic polyester is provided which exhibits an anisotropic melt phase and which is capable of readily undergoing melt processing. The wholly aromatic polyester consists essentially of the recurring units (a) p-oxybenzoyl moiety, (b) 2,6-dioxynaphthalene moiety, (c) 2,6-dioxyanthraquinone moiety and (d) terephthaloyl moiety in the concentrations indicated. The resulting polymer is substantially free of aromatic rings possessing ring substitution and meta disposed linkages in the polymer chain. The present invention represents an improvement over the polyester of U.S. Patent No. 4,184,996 since the melt phase may be formed at an advantageously reduced temperature, thereby better facilitating the use of standard melt processing equipment when forming fibres, films, three-dimensional shaped articles, etc. The reduction in possible melt processing temperature is accomplished without any significant diminution in melt anisotropy such as that which would result if non-symmetrical meta disposed linkages were present in the polymer chain. Also, the present polyester does not rely upon the presence of ring substitution as a means for producing the desired melt anisotropy.

  本发明提供了一种改进的全芳香族聚酯，该聚酯具有各向异性的熔融相，并易于进行熔融加工。这种全芳香族聚酯主要由以下重复单元组成：(a) 对氧苯甲酰基；(b) 2,6-二氧萘基；(c) 2,6-二氧蒽醌基；(d) 对苯二甲酰基，其浓度如图所示。所得聚合物基本上不含芳香环，在聚合物链中具有环置换和元置换连接。本发明是对美国专利第 4,184,996 号聚酯的改进，因为熔融相可以在较低的温度下有利地形成，从而在形成纤维、薄膜、三维形状物品等时更有利于使用标准熔融加工设备。在降低熔融加工温度的同时，熔体的各向异性也不会明显降低，例如，如果聚合物链中存在非对称的偏置链节，熔体的各向异性就会明显降低。此外，本聚酯并不依赖于环取代的存在来产生所需的熔体各向异性。
• Perkin, Journal of the Chemical Society, 1873, vol. 26, p. 20
  作者：Perkin

  DOI：——

  日期：——
• Self-Assembled Boronic Ester Cavitand Capsule as a Photosensitizer and a Guard Nanocontainer against Photochemical Reactions of 2,6-Diacetoxyanthracene
  作者：Naoki Nishimura、Kenji Kobayashi

  DOI：10.1021/jo101255g

  日期：2010.9.17

  The optical properties of 2,6-diacetoxyanthracene 4 encapsulated in the self-assembled boronic ester cavitand capsule 3 in C(6)H(6) are described. Upon excitation at 285 nm, the encapsulated 4 showed strong fluorescence emission as a result of the energy transfer from the excited 3 to the encapsulated 4, while 4 alone in C(6)H(6) exhibited very weak emission. Upon photoirradiation at 365 nm, the encapsulated 4 also showed strong fluorescence emission and remained almost intact, whereas 4 alone in C(6)H(6) gradually underwent photodimerization and photooxygenation to afford photodimers 5 and 5' and 9,10-anthraquinone 6 via 9,10-endoperoxide 7, respectively. Thus, the capsule 3 serves as a photosensitizer for the encapsulated 4 as well as a guard nanocontainer to protect against the photochemical reactions of 4.
• US4224433A
  申请人：——

  公开号：US4224433A

  公开（公告）日：1980-09-23