N-methoxyethylcarbamic acid trifluoroethyl ester | 1209447-22-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-methoxyethylcarbamic acid trifluoroethyl ester
• 英文别名: N-methoxyethyl trifluoroethyl carbamate；2,2,2-trifluoroethyl N-(2-methoxyethyl)carbamate
• CAS: 1209447-22-2
• 化学式: C₆H₁₀F₃NO₃
• mdl: MFCD13195848
• 分子量: 201.146
• InChiKey: WJYWLIYZVZAXMJ-UHFFFAOYSA-N

物化性质

• 沸点：
  203.9±40.0 °C(Predicted)
• 密度：
  1.236±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.833
• 拓扑面积：
  47.6
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-(2,4-二甲氧基苯基)吡咯烷 、 N-methoxyethylcarbamic acid trifluoroethyl ester 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 乙腈 为溶剂， 反应 4.0h， 生成 2-(2,4-dimethoxyphenyl)-N-(2-methoxyethyl)pyrrolidine-1-carboxamide
  参考文献：
  名称：

  Bis(2,2,2-trifluoroethyl) Carbonate as a Condensing Agent in One-Pot Parallel Synthesis of Unsymmetrical Aliphatic Ureas

  摘要：

  One-pot parallel synthesis of unsymmetrical aliphatic ureas was achieved with bis(2,2,2-trifluoroethyl) carbonate. The procedure worked well for both the monosubstituted and functionalized alkyl amines and required no special conditions (temperature control, order, or rate of addition). A library of 96 diverse ureas was easily synthesized.

  DOI：

  10.1021/co500025f
• 作为产物：
  描述：

  二(2,2,2-三氟乙基)碳酸酯 、 2-甲氧基乙胺 在 N,N-二异丙基乙胺 作用下， 以 乙腈 为溶剂， 反应 2.0h， 生成 N-methoxyethylcarbamic acid trifluoroethyl ester
  参考文献：
  名称：

  Bis(2,2,2-trifluoroethyl) Carbonate as a Condensing Agent in One-Pot Parallel Synthesis of Unsymmetrical Aliphatic Ureas

  摘要：

  One-pot parallel synthesis of unsymmetrical aliphatic ureas was achieved with bis(2,2,2-trifluoroethyl) carbonate. The procedure worked well for both the monosubstituted and functionalized alkyl amines and required no special conditions (temperature control, order, or rate of addition). A library of 96 diverse ureas was easily synthesized.

  DOI：

  10.1021/co500025f

文献信息

• ELECTROLYTE COMPRISING AN AMIDE COMPOUND, AND ELECTROCHEMICAL DEVICE COMPRISING THE ELECTROLYTE
  申请人：LG Chem, Ltd.

  公开号：EP2525433A2

  公开（公告）日：2012-11-21

  Disclosed is an electrolyte. The electrolyte includes an amide compound and an ionizable lithium salt. The amide compound has a specific structure in which an amine group is substituted with at least one alkoxyalkyl group and at least one halogen atom is present. The electrolyte has good thermal and chemical stability, a low resistance and a high ionic conductivity. In addition, the electrolyte has a high upper limit of electrochemical window due to its improved oxidation stability. Therefore, the electrolyte can be useful for the fabrication of an electrochemical device. Further disclosed is an electrochemical device including the electrolyte.

  公开了一种电解质。该电解液包括一种酰胺化合物和一种可电离的锂盐。酰胺化合物具有特定的结构，其中的胺基被至少一个烷氧基烷基取代，并含有至少一个卤素原子。该电解质具有良好的热稳定性和化学稳定性、低电阻和高离子导电性。此外，这种电解质还具有较高的电化学窗口上限，这是因为它的氧化稳定性得到了改善。因此，该电解质可用于制造电化学装置。进一步公开的是一种包括该电解质的电化学装置。
• ELECTROLYTE CONTAINING AN AMIDE COMPOUND, AND ELECTROCHEMICAL DEVICE COMPRISING THE SAME
  申请人：LG Chem, Ltd.

  公开号：EP2525433B1

  公开（公告）日：2016-12-07
• ELECTROLYTE INCLUDING AMIDE COMPOUND AND ELECTROCHEMICAL DEVICE INCLUDING THE SAME
  申请人：LEE Byoung-Bae

  公开号：US20120077091A1

  公开（公告）日：2012-03-29

  Disclosed is an electrolyte. The electrolyte includes an amide compound and an ionizable lithium salt. The amide compound has a specific structure in which an amine group is substituted with at least one alkoxyalkyl group and at least one halogen atom is present. The electrolyte has good thermal and chemical stability, a low resistance and a high ionic conductivity. In addition, the electrolyte has a high upper limit of electrochemical window due to its improved oxidation stability. Therefore, the electrolyte can be useful for the fabrication of an electrochemical device. Further disclosed is an electrochemical device including the electrolyte.
• US8703345B2
  申请人：——

  公开号：US8703345B2

  公开（公告）日：2014-04-22
• Bis(2,2,2-trifluoroethyl) Carbonate as a Condensing Agent in One-Pot Parallel Synthesis of Unsymmetrical Aliphatic Ureas
  作者：Andrey V. Bogolubsky、Yurii S. Moroz、Pavel K. Mykhailiuk、Dmitry S. Granat、Sergey E. Pipko、Anzhelika I. Konovets、Roman Doroschuk、Andrey Tolmachev

  DOI：10.1021/co500025f

  日期：2014.6.9

  One-pot parallel synthesis of unsymmetrical aliphatic ureas was achieved with bis(2,2,2-trifluoroethyl) carbonate. The procedure worked well for both the monosubstituted and functionalized alkyl amines and required no special conditions (temperature control, order, or rate of addition). A library of 96 diverse ureas was easily synthesized.