di-n-butyl-malonyl peroxide | 30842-78-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: di-n-butyl-malonyl peroxide
• 英文别名: 4,4-Dibutyldioxolane-3,5-dione；4,4-dibutyldioxolane-3,5-dione
• CAS: 30842-78-5
• 化学式: C₁₁H₁₈O₄
• 分子量: 214.262
• InChiKey: KNGIIYWBKONAQW-UHFFFAOYSA-N

物化性质

• 沸点：
  252.3±23.0 °C(Predicted)
• 密度：
  1.053±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  di-n-butyl-malonyl peroxide 以 gas 为溶剂， 450.0 ℃ 、79.99 Pa 条件下， 以70%的产率得到5-壬酮
  参考文献：
  名称：

  丙二酰过氧化物的真空快速热解（VFP）：中间α-内酯的脱羧与脱羰

  摘要：

  真空闪速热解（VFP）的温度约为 450–500°C左右 螺环过氧化丙二酰（2a，b）的0.1–0.3托可提供高产率的丙二烯（5a，b），而简单的丙二酰过氧化物（2c）则可生成酮（4），其分别源自中间α的脱羧和脱羰-内酯（3）。

  DOI：

  10.1016/s0040-4039(01)90274-6

文献信息

• Cobalt catalyst comprising a support comprising a mixed oxide phase including cobalt and/or nickel produced from a dilactone compound
  申请人：IFP Energies nouvelles

  公开号：US11235312B2

  公开（公告）日：2022-02-01

  The present invention relates to a catalyst containing an active cobalt phase, deposited on a support comprising alumina, silica or silica-alumina, said support containing a mixed oxide phase containing cobalt and/or nickel, said catalyst has been prepared by introducing at least one organic compound of the family of dilactones. The invention also relates to the process for the preparation thereof, and to the use thereof in the field of Fischer-Tropsch synthesis processes.

  本发明涉及一种含有活性钴相的催化剂，该催化剂沉积在由氧化铝、二氧化硅或二氧化硅-氧化铝组成的载体上，所述载体含有含钴和/或镍的混合氧化物相，所述催化剂是通过引入至少一种稀内酯族有机化合物制备的。本发明还涉及其制备工艺及其在费托合成工艺领域的应用。
• Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides
  作者：Oleg V. Bityukov、Vera A. Vil’、Nikita V. Lukashin、Aleksandr G. Cherednichenko、Gennady I. Nikishin、Alexander O. Terent’ev

  DOI：10.1016/j.mencom.2019.01.017

  日期：2019.1

  Silica gel was found to mediate decarboxylation of tetra carbonyl compounds with a free carboxylic group prepared from beta-dicarbonyl compounds and malonyl peroxides. Under solvent-free heterogeneous conditions silica gel effectively acts as a mediator of C-O coupling with further decarboxylation at 120 degrees C.
• Spontaneous reaction of malonyl peroxides with methanol
  作者：Margarita A. Lapitskaya、Vera A. Vil’、Ludmila L. Vasil’eva、Elena D. Daeva、Alexander O. Terent’ev、Kasimir K. Pivnitsky

  DOI：10.1016/j.mencom.2017.05.008

  日期：2017.5

  The spontaneous reaction of disubstituted malonyl peroxides (MPOs) with methanol affording monopermalonic acid monomethyl esters is fast (minutes) for lower homologues but is sharply decelerated (days) for the higher ones. Spirocyclopropyl-MPO is an exception in which the nucleophilic opening of the spiroactivated cyclopropane ring leads to 2,4-dimethoxy-2-carboxybutanoic acid.
• COBALT CATALYST COMPRISING A SUPPORT COMPRISING A MIXED OXIDE PHASE INCLUDING COBALT AND/OR NICKEL PRODUCED FROM A DILACTONE COMPOUND
  申请人：IFP Energies nouvelles

  公开号：US20200129966A1

  公开（公告）日：2020-04-30

  The present invention relates to a catalyst containing an active cobalt phase, deposited on a support comprising alumina, silica or silica-alumina, said support containing a mixed oxide phase containing cobalt and/or nickel, said catalyst has been prepared by introducing at least one organic compound of the family of dilactones. The invention also relates to the process for the preparation thereof, and to the use thereof in the field of Fischer-Tropsch synthesis processes.
• Vacuum flash pyrolysis (VFP) of malonyl peroxides: decarboxylation versus decarbonylation of the intermediary α-lactones
  作者：Waldemar Adam、Carlos Cadiz、Francois Mazenod

  DOI：10.1016/s0040-4039(01)90274-6

  日期：1981.1

  Vacuum Flash Pyrolysis (VFP) at ca. 450–500°C and ca. 0.1–0.3 Torr of the spirocyclic malonyl peroxides (2a,b) affords high yields of allenes (5a,b), while the simple malonyl peroxide (2c) leads to ketone (4), derived respectively from decarboxylation and decarbonylation of the intermediary α-lactones (3).

  真空闪速热解（VFP）的温度约为 450–500°C左右 螺环过氧化丙二酰（2a，b）的0.1–0.3托可提供高产率的丙二烯（5a，b），而简单的丙二酰过氧化物（2c）则可生成酮（4），其分别源自中间α的脱羧和脱羰-内酯（3）。