N,N'-bis(2,2'-dipyridyl)trimesoylamide | 557767-01-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(2,2'-dipyridyl)trimesoylamide
• 英文别名: 1-N,1-N,3-N,3-N,5-N,5-N-hexapyridin-2-ylbenzene-1,3,5-tricarboxamide
• CAS: 557767-01-8
• 化学式: C₃₉H₂₇N₉O₃
• 分子量: 669.702
• InChiKey: NNCAYPYRANJRGP-UHFFFAOYSA-N

物化性质

• 沸点：
  925.2±65.0 °C(Predicted)
• 密度：
  1.393±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.99
• 重原子数：
  51.0
• 可旋转键数：
  9.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  138.27
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 sodium perchlorate 、 N,N'-bis(2,2'-dipyridyl)trimesoylamide 以 乙醇 、 乙腈 为溶剂， 生成 [Cu2(2,2'-dipyridylamine)2(μ-chloride)(μ-hydroxy)(μ-formate)]ClO4
  参考文献：
  名称：

  Dinuclear copper(II) complexes with different bridging connectors

  摘要：

  One novel triply-bridged dicopper(II) complex formulated as [Cu-2(dpa)(2)(mu-Cl)(mu-OH)(mu-HCOO)](.)(ClO4) 1 and two terephthalate anions bridged 2,2'-bipyridine (2,2'-bpy) dicopper(II) complexes with formulae of [Cu-2(2,2-bpy)(4)( mu-terephthalate)].(NO3)(2) 2 and [Cu-2(2,2'-bpy)(4)(mu-terephthalate)](.)(terephthalate) 3, respectively, have been synthesized and characterized by infrared and electrospray mass spectra as well as X-ray single-crystal determination. In addition, thermal properties of all compounds have been studied. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00080-2
• 作为产物：
  描述：

  2,2'-二吡啶胺 、 1,3,5-苯三甲酰氯 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 N,N'-bis(2,2'-dipyridyl)trimesoylamide
  参考文献：
  名称：

  Dinuclear copper(II) complexes with different bridging connectors

  摘要：

  One novel triply-bridged dicopper(II) complex formulated as [Cu-2(dpa)(2)(mu-Cl)(mu-OH)(mu-HCOO)](.)(ClO4) 1 and two terephthalate anions bridged 2,2'-bipyridine (2,2'-bpy) dicopper(II) complexes with formulae of [Cu-2(2,2-bpy)(4)( mu-terephthalate)].(NO3)(2) 2 and [Cu-2(2,2'-bpy)(4)(mu-terephthalate)](.)(terephthalate) 3, respectively, have been synthesized and characterized by infrared and electrospray mass spectra as well as X-ray single-crystal determination. In addition, thermal properties of all compounds have been studied. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00080-2