3-[(hexyloxy)methyl]thiophene | 119142-28-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 3-[(hexyloxy)methyl]thiophene
• 英文别名: 3-hexyloxymethylthiophene；3-(Hexoxymethyl)thiophene
• CAS: 119142-28-8
• 化学式: C₁₁H₁₈OS
• 分子量: 198.329
• InChiKey: AOXYKLSLPWRGNA-UHFFFAOYSA-N

物化性质

• 沸点：
  256.6±15.0 °C(Predicted)
• 密度：
  0.988±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  37.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-[(hexyloxy)methyl]thiophene 在 iron(III) chloride 、 N-氯代丁二酰亚胺 作用下， 以 乙腈 为溶剂， 以49%的产率得到2-chloro-3-[(hexyloxy)methyl]thiophene
  参考文献：
  名称：

  C–H Functionalization Polycondensation of Chlorothiophenes in the Presence of Nickel Catalyst with Stoichiometric or Catalytically Generated Magnesium Amide

  摘要：

  Polymerization of 2-chloro-3-substituted thiophenes proceeded with a stoichiometric amount of magnesium amide, TMPMgCl center dot LiCl, or a combination of a Grignard reagent and a catalytic amount of secondary amine in the presence of a nickel catalyst. Although the nickel-catalyzed polymerization with NiCl(2)dppe, which exhibited high catalytic activity in the reaction of bromothiophenes, was less effective, use of a nickel catalyst bearing N-heterocyclic carbene as a ligand was found to induce polymerization with controlled molecular weight and molecular weight distribution.

  DOI：

  10.1021/ja2033525
• 作为产物：
  描述：

  3-噻吩甲醛 在 sodium hydroxide 、 sodium tetrahydroborate 、 苄基三乙基氯化铵 作用下， 以 甲醇 为溶剂， 反应 8.0h， 生成 3-[(hexyloxy)methyl]thiophene
  参考文献：
  名称：

  Sasabe, H.; Wada, T.; Hosoda, M., Molecular Crystals and Liquid Crystals (1969-1991), 1990, vol. 189, # 1, p. 155 - 168

  摘要：

  DOI：

文献信息

• CONDUCTIVE POLYMER FOR SOLID ELECTROLYTIC CAPACITOR
  申请人：Solvay USA Inc.

  公开号：EP2855554A2

  公开（公告）日：2015-04-08
• CONDUCTIVE POLYMER FOR SOLID ELECTROLYTE CAPACITOR
  申请人：Plextronics, Inc.

  公开号：US20140014881A1

  公开（公告）日：2014-01-16

  [Problem] To provide a conductive polymer for solid electrolyte capacitor having outstanding solubility in solvents or dispersibility in solvents and which can produce a capacitor having outstanding capacitor characteristics in high-temperature environments. [Means Used to Resolve the Problem] A conductive polymer (A) for solid electrolyte capacitor containing substituted polythiophene (P) having thiophene repeating units (D) substituted by a least one type of group (s) selected from a group made up of a polyether group (a) indicated in general formula (1); an alkoxy group (b) having 1 to 15 carbon atoms; an alkoxy alkyl group (c) indicated in general formula (2); an alkyl group (d) having 1 to 15 carbon atoms; and a group (e) indicated in general formula (3); as well as thiophene repeating units (E) wherein the hydrogen atoms at position 3 and position 4 on the thiophene ring have been substituted by group (s) and sulfo group (—SO 3 H) (f). —(OR 1 ) k —OR 2 (1) —R 3 —OR 4 (2) —R 5 —(OR 6 ) m —OR 7 (3)
• US9224540B2
  申请人：——

  公开号：US9224540B2

  公开（公告）日：2015-12-29
• [EN] CONDUCTIVE POLYMER FOR SOLID ELECTROLYTIC CAPACITOR<br/>[FR] POLYMÈRE CONDUCTEUR POUR CONDENSATEUR ÉLECTROLYTIQUE SOLIDE
  申请人：PLEXTRONICS INC

  公开号：WO2013181165A2

  公开（公告）日：2013-12-05

  [Problem] To provide a conductive polymer for solid electrolyte capacitor having outstanding solubility in solvents or dispersibility in solvents and which can produce a capacitor having outstanding capacitor characteristics in high-temperature environments. [Means Used to Resolve the Problem] A conductive polymer (A) for solid electrolyte capacitor containing substituted polythiophene (P) having thiophene repeating units (D) substituted by a least one type of group (s) selected from a group made up of a polyether group (a) indicated in general formula (1); an alkoxy group (b) having 1 to 15 carbon atoms; an alkoxy alkyl group (c) indicated in general formula (2); an alkyl group (d) having 1 to 15 carbon atoms; and a group (e) indicated in general formula (3); as well as thiophene repeating units (E) wherein the hydrogen atoms at position 3 and position 4 on the thiophene ring have been substituted by group (s) and sulfo group (-SO3H) (f).