methyl benzoyl(phenyl)phosphinate | 18106-76-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl benzoyl(phenyl)phosphinate
• 英文别名: methyl benzoylphenylphosphinate；Benzoyl-phenyl-phosphinsaeure-methylester；Benzoyl-phenylphosphinsaeure-methylester；Methylbenzoylphenylphosphinat；Phosphinic acid, benzoylphenyl-, methyl ester, (S)-；[methoxy(phenyl)phosphoryl]-phenylmethanone
• CAS: 18106-76-8
• 化学式: C₁₄H₁₃O₃P
• 分子量: 260.229
• InChiKey: GKMKJRYNJIFULH-UHFFFAOYSA-N

物化性质

• 熔点：
  78.5 °C
• 沸点：
  147-147.5 °C(Press: 3.25 Torr)
• 密度：
  1.22±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  methyl benzoyl(phenyl)phosphinate 在 羟胺 作用下， 生成 苯基膦酸甲酯
  参考文献：
  名称：

  Schlossman, Ada; Gibson, Dan; Breuer, Eli, Phosphorus, Sulfur and Silicon and the Related Elements, 1990, vol. 49/50, p. 81 - 84

  摘要：

  DOI：
• 作为产物：
  描述：

  dimethyl phenylphosphonite 、 苯甲酰氯 以80%的产率得到methyl benzoyl(phenyl)phosphinate
  参考文献：
  名称：

  Breuer, Eli; Schlossman, Ada; Safadi, Muhammad, Journal of the Chemical Society. Perkin transactions I, 1990, # 12, p. 3263 - 3269

  摘要：

  DOI：

文献信息

• Nucleophilic Fluorination of α-Aroylphosphinates with Morpholinosulfur Trifluoride
  作者：Sergiy V. Zasukha、Olexandr I. Guzyr、Yuriy G. Shermolovich

  DOI：10.1002/hc.21171

  日期：2014.7

  Nucleophilic fluorination of aroyl-phenyl-phosphinates is highly dependent on the nature of the alkoxy substituents attached to the phosphoryl group. A reaction of aroyl-phenyl-phosphinates with morpholinosulfur trifluoride was shown to be a convenient synthetic method for high-yield synthesis of α,α-difluorobenzyl-phenyl-phosphinates using steric protection of the phosphoryl group by a bulky isopropoxy

  芳酰基-苯基-次膦酸酯的亲核氟化高度依赖于连接到磷酰基的烷氧基取代基的性质。芳酰基-苯基-次膦酸盐与吗啉代三氟化硫的反应被证明是一种方便的合成方法，可通过庞大的异丙氧基取代基对磷酰基进行空间保护，从而高产合成 α,α-二氟苄基-苯基-次膦酸盐。芳酰基次膦酸甲酯在相同反应条件下产生(氟-二芳基-甲基)-五氟磷酸盐作为主要反应产物。
• METHODS FOR SOLID FREEFORM FABRICATION
  申请人：Ricoh Company, Ltd.

  公开号：EP3064526A1

  公开（公告）日：2016-09-07

  The present invention provides methods, processes, and systems for the manufacture of three-dimensional articles (35) of polymer materials using 3D printing. A syringe or an inkjet print head (30, 31) prints a solution of prepolymer onto a build plate (37). The printed prepolymer is exposed to a stimulus whereby the prepolymer is converted to the polymer. After a predetermined time, sequential layers are printed to provide the three-dimensional article (35). The three-dimensional article (35) can be cured to produce the 3D article made from the final polymer.

  本发明提供了利用三维打印技术制造聚合物材料三维制品（35）的方法、工艺和系统。注射器或喷墨打印头（30、31）将预聚物溶液打印到构建板（37）上。打印出的预聚物暴露在刺激下，预聚物转化为聚合物。经过预定时间后，打印出连续的层，以提供三维物品（35）。三维物品 (35) 可以固化，以生产由最终聚合物制成的三维物品。
• METHOD FOR SOLID FREEFORM FABRICATION
  申请人：Ricoh Company, Ltd.

  公开号：EP3064340A2

  公开（公告）日：2016-09-07

  The present invention provides methods, processes, and systems for the manufacture of three-dimensional articles made of polymers using 3D printing. A layer of prepolymer is deposited on a build plate to form a powder bed. The deposited powder bed is heated to about 50 °C to about 170 °C. Then, a solution of activating agent is printed on the powder bed in a predetermined pattern, and a stimulus is applied converting the prepolymer to the final polymer. After a predetermined period of time, sequential layers are printed to provide the three-dimensional article. The three-dimensional object can be cured to produce the three-dimensional article composed of the final polymers.

  本发明提供了利用三维打印技术制造聚合物三维物品的方法、工艺和系统。在构建板上沉积一层预聚物以形成粉末床。将沉积的粉末床加热至约 50°C 至约 170°C。然后，将活化剂溶液按预定图案印在粉末床上，并施加刺激，使预聚物转化为最终聚合物。经过一段预定的时间后，印刷出连续的层，形成三维物体。三维物体可以固化，以生产由最终聚合物组成的三维物品。
• Method for solid freeform fabrication
  申请人：Ricoh Company, LTD.

  公开号：US10066119B2

  公开（公告）日：2018-09-04

  The present invention provides methods, processes, and systems for the manufacture of three-dimensional articles made of polymers using 3D printing. A layer of prepolymer is deposited on a build plate to form a powder bed. The deposited powder bed is heated to about 50° C. to about 170° C. Then, a solution of activating agent is printed on the powder bed in a predetermined pattern, and a stimulus is applied converting the prepolymer to the final polymer. After a predetermined period of time, sequential layers are printed to provide the three-dimensional article. The three-dimensional object can be cured to produce the three-dimensional article composed of the final polymers.

  本发明提供了利用三维打印技术制造聚合物三维物品的方法、工艺和系统。在构建板上沉积一层预聚物以形成粉末床。将沉积的粉末床加热至约 50°C 至约 170°C。然后，将活化剂溶液按预定图案印在粉末床上，并施加刺激，将预聚物转化为最终聚合物。经过一段预定的时间后，印刷出连续的层，形成三维物体。三维物体可以固化，以生产由最终聚合物组成的三维物品。
• Methods of solid freeform fabrication
  申请人：Boydston Andrew J.

  公开号：US10683393B2

  公开（公告）日：2020-06-16

  The present invention provides methods, processes, and systems for the manufacture of three-dimensional articles of polymer materials using 3D printing. A syringe or an inkjet print head prints a solution of prepolymer onto a build plate. The printed prepolymer is exposed to a stimulus whereby the prepolymer is converted to the polymer. After a predetermined time, sequential layers are printed to provide the three-dimensional article. The three-dimensional article can be cured to produce the 3D article made from the final polymer.

  本发明提供了利用三维打印技术制造聚合物材料三维制品的方法、工艺和系统。注射器或喷墨打印头将预聚物溶液打印到构建板上。打印出的预聚物暴露在刺激物中，预聚物由此转化为聚合物。经过预定时间后，打印出连续的层，形成三维制品。三维物品可以固化，以生产由最终聚合物制成的三维物品。