methoxycarbonyl-methanesulfonic acid | 63409-57-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: methoxycarbonyl-methanesulfonic acid
• 英文别名: Sulfoessigsaeure-methylester；Methoxycarbonyl-methansulfonsaeure；Essigsaeuremethylester-sulfonsaeure；Acetic acid, sulfo-, 1-methyl ester；2-methoxy-2-oxoethanesulfonic acid
• CAS: 63409-57-4
• 化学式: C₃H₆O₅S
• 分子量: 154.144
• InChiKey: GLIZCTQNRHOAEH-UHFFFAOYSA-N

物化性质

• 密度：
  1.540±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -1
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  89
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  溴乙酸甲酯 在 sodium sulfite 作用下， 以 乙醇 为溶剂， 生成 methoxycarbonyl-methanesulfonic acid
  参考文献：
  名称：

  A Knoevenagel-Type Synthesis of Styrene-ω-sulfonanilides

  摘要：

  DOI：

  10.1055/s-1975-23742

文献信息

• Analysis of the vascular anatomy of the palm and its clinical relevance in Morbus Dupuytren
  作者：Triinu Elsner、Uda Schramm、Marianne Schrader

  DOI：10.1016/s0940-9602(01)80186-2

  日期：2001.7

  The triangular center of the palm is supposedly hypovascularized. Intraoperative clinical studies have shown numerous vessels and nerves rising through the palmar aponeurosis into the skin in this area. To investigate these findings we have dissected 7 cadaver hands in order to analyze the vascular and neural structure of the palm. On an average we have found 30 bundles in the center of the palm. At least half of them were vascular-nerve bundles, the other bundles consisted either of a nerve, an artery or a vein. By means of histological testing we have also found lymphatic vessels accompanying the blood vessels and the nerves. Our study shows a greater number of vessels rising into the skin than has been previously described in the literature, so that we cannot confirm the triangular hypovascular zone in the center of the palm.
• A Knoevenagel-Type Synthesis of Styrene-ω-sulfonanilides
  作者：James E. OLIVER、Albert B. DEMILO

  DOI：10.1055/s-1975-23742

  日期：——