1-(4-isopropenylphenoxy)-4-bromobutane | 194093-27-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-isopropenylphenoxy)-4-bromobutane
• 英文别名: 1-(4-Bromobutoxy)-4-(prop-1-EN-2-YL)benzene；1-(4-bromobutoxy)-4-prop-1-en-2-ylbenzene
• CAS: 194093-27-1
• 化学式: C₁₃H₁₇BrO
• 分子量: 269.181
• InChiKey: PKSOALHCEUMGRB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  壬酸 、 1-(4-isopropenylphenoxy)-4-bromobutane 在 三乙胺 作用下， 以 丙酮 为溶剂， 反应 5.0h， 以73.4%的产率得到4-(4-isopropenylphenoxy)butyl pelargonate
  参考文献：
  名称：

  Synthesis of 1-(4-isopropenylphenoxy)-bromo-C2-C4-alkanes and application of their transformation products

  摘要：

  Reaction of 4-isopropenylphenol with alpha,omega-dibromo-C-2-C-4-alkanes by the Willamson reaction in the presence of potassium iodide as promoter, aiming to synthesize the corresponding monobromosubstituted derivatives and to study their some chemical transformation. Optimal conditions to obtain 1-(4-isopropenylphenoxy)-2-bromoethane, 1-(4-isopropenylphenoxy)-3-bromopropane and 1-(4-isopropenylphenoxy)-4-bromobutane were found. The nitrogen-containing derivatives, inhibitors of a hydrosulfuric corrosion in the water-salt solutions, were obtained on the basis of the first two compounds. The derivatives involving multiple bond and ester-group were synthesized from the third compound. Their incorporation into the polystyrene chains in the process synthesis gives them plasticize properties.

  DOI：

  10.1134/s1070427209100243
• 作为产物：
  描述：

  1,4-二溴丁烷 、 4-异丙基苯酚 在 potassium hydroxide 、 potassium iodide 作用下， 以 异丙醇 为溶剂， 反应 0.5h， 以64.2%的产率得到1-(4-isopropenylphenoxy)-4-bromobutane
  参考文献：
  名称：

  Synthesis of 1-(4-isopropenylphenoxy)-bromo-C2-C4-alkanes and application of their transformation products

  摘要：

  Reaction of 4-isopropenylphenol with alpha,omega-dibromo-C-2-C-4-alkanes by the Willamson reaction in the presence of potassium iodide as promoter, aiming to synthesize the corresponding monobromosubstituted derivatives and to study their some chemical transformation. Optimal conditions to obtain 1-(4-isopropenylphenoxy)-2-bromoethane, 1-(4-isopropenylphenoxy)-3-bromopropane and 1-(4-isopropenylphenoxy)-4-bromobutane were found. The nitrogen-containing derivatives, inhibitors of a hydrosulfuric corrosion in the water-salt solutions, were obtained on the basis of the first two compounds. The derivatives involving multiple bond and ester-group were synthesized from the third compound. Their incorporation into the polystyrene chains in the process synthesis gives them plasticize properties.

  DOI：

  10.1134/s1070427209100243

文献信息

• Synthesis of 1-(4-isopropenylphenoxy)-bromo-C2-C4-alkanes and application of their transformation products
  作者：A. M. Magerramov、M. R. Bairamov、I. A. Aliev、M. A. Agaeva、M. G. Allakhverdieva、I. G. Mamedov、M. A. Dzhavadov

  DOI：10.1134/s1070427209100243

  日期：2009.10

  Reaction of 4-isopropenylphenol with alpha,omega-dibromo-C-2-C-4-alkanes by the Willamson reaction in the presence of potassium iodide as promoter, aiming to synthesize the corresponding monobromosubstituted derivatives and to study their some chemical transformation. Optimal conditions to obtain 1-(4-isopropenylphenoxy)-2-bromoethane, 1-(4-isopropenylphenoxy)-3-bromopropane and 1-(4-isopropenylphenoxy)-4-bromobutane were found. The nitrogen-containing derivatives, inhibitors of a hydrosulfuric corrosion in the water-salt solutions, were obtained on the basis of the first two compounds. The derivatives involving multiple bond and ester-group were synthesized from the third compound. Their incorporation into the polystyrene chains in the process synthesis gives them plasticize properties.