1,4-dicyano-2,6-dimethylbenzene | 95216-09-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-dicyano-2,6-dimethylbenzene
• 英文别名: 1,4-Dicyan-2,6-dimethylbenzol；2,6-dimethyl-terephthalonitrile；2,6-Dimethyl-terephthalonitril；2,6-Dimethylterephthalonitrile；2,6-dimethylbenzene-1,4-dicarbonitrile
• CAS: 95216-09-4
• 化学式: C₁₀H₈N₂
• 分子量: 156.187
• InChiKey: VODNMFZZKATZHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2926909090

反应信息

• 作为反应物：
  描述：

  1,4-dicyano-2,6-dimethylbenzene 在 sodium hydroxide 、 N-溴代丁二酰亚胺(NBS) 、 双氧水 、 过氧化苯甲酰 作用下， 以 四氯化碳 、 乙醇 、 氯仿 、 溶剂黄146 、 叔丁醇 、 苯 为溶剂， 反应 62.0h， 生成 15,18-Dicyan-6,9-dimethoxy-2,11-dithia<3.3>metacyclophan-2,2,11,11-tetraoxid
  参考文献：
  名称：

  Staab, Heinz A.; Schanne, Lothar; Krieger, Claus, Chemische Berichte, 1985, vol. 118, # 3, p. 1204 - 1229

  摘要：

  DOI：
• 作为产物：
  描述：

  15,18-Dicyan-6,9-dimethoxy-2,11-dithia<3.3>metacyclophan 在 双氧水 作用下， 以 氯仿 、 溶剂黄146 为溶剂， 20.0~500.0 ℃ 、1.33 Pa 条件下， 反应 42.0h， 生成 1,4-dicyano-2,6-dimethylbenzene
  参考文献：
  名称：

  Staab, Heinz A.; Schanne, Lothar; Krieger, Claus, Chemische Berichte, 1985, vol. 118, # 3, p. 1204 - 1229

  摘要：

  DOI：

文献信息

• PHOTOCHEMICAL AMINATION OF TETRACYANOBENZENE WITH ACETONITRILE IN THE PRESENCE OF ALIPHATIC AMINE
  作者：Shuzo Yamada、Yoshiki Nakagawa、Oserojoin Watabiki、Shin-ichi Suzuki、Mamoru Ohashi

  DOI：10.1246/cl.1986.361

  日期：1986.3.5

  dicyanodurene in acetonitrile in the presence of triethylamine gave mainly substitution and reduction products respectively, whereas a photochemical reaction of 1,2,4,5-tetracyanobenzene in the presence of N-methylpyrrolidine or nicotine gave tricyanoaniline, an amination product, as well as substitution products.

  在三乙胺的存在下，二氰基二甲苯和二氰基杜烯在乙腈中的辐照分别主要产生取代和还原产物，而 1,2,4,5-四氰基苯在 N-甲基吡咯烷或尼古丁存在下的光化学反应产生了三氰基苯胺，一种胺化产物，以及替代产品。
• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• Fluorinated Dicarboxylic Acid Derivative and Polymer Obtained Therefrom
  申请人：Isono Yoshimi

  公开号：US20110301305A1

  公开（公告）日：2011-12-08

  According to the present invention, a polymer is obtained by polycondensation of a fluorinated dicarboxylic acid derivative of the general formula (M-1) or an acid anhydride of the fluorinated dicarboxylic acid with a polyfunctional compound having two to four reactive groups corresponding in reactivity to carbonyl moieties of the fluorinated dicarboxylic acid derivative or acid anhydride. [Chem. 134] AOCF 2 C-Q-CF 2 COA′  (M-1) In the above formula, Q represents a divalent organic group having a substituted or unsubstituted aromatic ring; and A and A′ each independently represent an organic group. This polymer exhibits a sufficiently low dielectric constant for use as a semiconductor protection film and has the capability of forming a film at a relatively low temperature of 250° C. or lower.

  根据本发明，通过将通式(M-1)的含氟二羧酸衍生物或含氟二羧酸酸酐与具有与含氟二羧酸衍生物或酸酐的羰基部分相对应的两到四个反应性基团的多官能化合物进行聚合缩合反应，可以得到一种聚合物。[Chem. 134]AOCF2C-Q-CF2COA′  (M-1)在上述公式中，Q代表具有取代或未取代芳香环的二价有机基团; A和A'各自独立地表示有机基团。该聚合物表现出足够低的介电常数，可用作半导体保护膜，并具有在相对较低的温度下（250℃或更低）形成膜的能力。
• Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins
  申请人：Chevron Phillips Chemical Company LP

  公开号：US10144752B2

  公开（公告）日：2018-12-04

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物。还公开了制造 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的方法。还公开了利用 N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的催化剂体系，以及 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物在烯烃的低聚和/或聚合中的用途。
• Cachia; Wahl, Bulletin de la Societe Chimique de France, 1958, p. 310,313
  作者：Cachia、Wahl

  DOI：——

  日期：——