4-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-3-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-hydroxyphenyl]methyl]-2-hydroxyphenyl]methyl]-6-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-hydroxyphenyl]methyl]phenol | 156578-23-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 4-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-3-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-hydroxyphenyl]methyl]-2-hydroxyphenyl]methyl]-6-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-hydroxyphenyl]methyl]phenol
• CAS: 156578-23-3
• 化学式: C₇₉H₁₀₄O₈Si₄
• 分子量: 1294.03
• InChiKey: ZXYDAUQKWVLUOO-UHFFFAOYSA-N

物化性质

• 沸点：
  1036.3±65.0 °C(predicted)
• 密度：
  1.070±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  21.18
• 重原子数：
  91.0
• 可旋转键数：
  22.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  117.84
• 氢给体数：
  4.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  4-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-3-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-hydroxyphenyl]methyl]-2-hydroxyphenyl]methyl]-6-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-hydroxyphenyl]methyl]phenol 在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 反应 0.17h， 以83%的产率得到6,6'-bis(2-hydroxy-5-(4-hydroxybenzyl))benzyl-4,4'-bis(4-hydroxybenzyl)-2,2'-methylenediphenol
  参考文献：
  名称：

  Strategic synthesis of model novolac resins

  摘要：

  Model novolac resins which contain the maximum number of free ortho positions for reaction with the curing agent hexamethylenetetramine (HMTA) have been prepared. The key transformation was the ion assisted ortho-specific phenol-formaldehyde oligomerization of suitably protected precursors.

  DOI：

  10.1016/s0040-4039(00)60747-5
• 作为产物：
  描述：

  4-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]phenol 在 乙基溴化镁 作用下， 反应 41.0h， 生成 4-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-3-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-hydroxyphenyl]methyl]-2-hydroxyphenyl]methyl]-6-[[5-[[4-[tert-butyl(dimethyl)silyl]oxyphenyl]methyl]-2-hydroxyphenyl]methyl]phenol
  参考文献：
  名称：

  Strategic synthesis of model novolac resins

  摘要：

  Model novolac resins which contain the maximum number of free ortho positions for reaction with the curing agent hexamethylenetetramine (HMTA) have been prepared. The key transformation was the ion assisted ortho-specific phenol-formaldehyde oligomerization of suitably protected precursors.

  DOI：

  10.1016/s0040-4039(00)60747-5

文献信息

• de Bruyn Pauline J., Lim Audrey S. C., Looney Mark G., Solomon David H., Tetrahedron Lett, 35 (1994) N 26, S 4627-4630
  作者：de Bruyn Pauline J., Lim Audrey S. C., Looney Mark G., Solomon David H.

  DOI：——

  日期：——