Acid Violet 43

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: Acid Violet 43
• 英文别名: Sodium;4-(4-methyl-2-sulfoanilino)-9,10-dioxoanthracen-1-olate；sodium;4-(4-methyl-2-sulfoanilino)-9,10-dioxoanthracen-1-olate
• 化学式: C₂₁H₁₄NO₆S*Na
• 分子量: 431.401
• InChiKey: GTKIEPUIFBBXJQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.13
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  132
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4-溴邻苯二甲腈 、 Acid Violet 43 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以65%的产率得到sodium 5-methyl-2-{[4-(3,4-dicyanophenoxy)-9,10-dioxo-9,10-dihydroanthracen-1-yl]amino}benzenesulfonate
  参考文献：
  名称：

  Synthesis and Properties of Metal Phthalocyanines Containing Anthraquinone Chromophores

  摘要：

  Nucleophilic substitution of bromine in 4-bromophthalonitrile gave anthraquinone-substituted nitriles, sodium 2-{[4-(3,4-dicyanophenoxy)-9,10-dioxo-9,10-dihydroanthracen-1-yl]amino}-5-methylbenzenesulfonate and 4-[(2-hydroxy-9,10-dioxo-9,10-dihydroanthracen-1-yl)oxy]phthalonitrile, which were used to obtain the corresponding cobalt phthalocyanines by the nitrile method.

  DOI：

  10.1134/s107036322009011x

文献信息

• Bridged diaminopyrazole compounds and dye compositions containing same
  申请人：——

  公开号：US20020170125A1

  公开（公告）日：2002-11-21

  The new diaminopyrazole compounds are bridged 4,5-diaminopyrazole compounds or salts thereof. These diaminopyrazole compounds have the formula (I): 1 wherein R1 represents hydrogen, a C 1 - to C 6 -alkyl, a C 1 - to C 4 -hydroxyalkyl, a C 1 - to C 4 -aminoalkyl, a C 1 - to C 8 -alkylamino, a di(C 1 - to C 8 -alkyl)amino, a C 1 - to C 4 -alkylamino-(C 1 - to C 4 -alkyl), a di(C 1 - to C 4 -alkylamino)-C 1 - to C 4 -alkyl, an aryl or a heteroaryl; R2 and R3 each represent hydrogen, a straight-chain or branched C 1 - to C 6 -alkyl, an aryl, a heteroaryl, a carboxylic acid, a carboxylic acid ester, an unsubstituted or substituted carboxylic acid amide, a hydroxy or a C 1 - to C 4 -hydroxyalkyl group, or R2 and R3 together represent a C 1 - to C 6 -alkylene group; Z represents a C 1 - to C 10 -alkyl diradical, optionally interrupted by a heteroatom, an aromatic or heteroaromatic diradical, optionally substituted with a hydroxy group, a C 1 - to C 6 -alkyl group and/or is subjected to a benzocondensation once or twice; or Z is —Ar(Alk) n —Ar—, wherein Ar represents an arylene group or a heteroarylene group, Alk represents a —CH 2 — group and n is 0 to 6; and x and y are 0 or 1.

  新的二氨基吡唑化合物是桥联的4,5-二氨基吡唑化合物或其盐。这些二氨基吡唑化合物的化学式为（I）：其中R1代表氢、C1至C6烷基、C1至C4羟基烷基、C1至C4氨基烷基、C1至C8烷基氨基、双（C1至C8烷基）氨基、C1至C4烷基氨基（C1至C4烷基）、双（C1至C4烷基氨基）-C1至C4烷基、芳基或杂芳基；R2和R3各自代表氢、直链或支链的C1至C6烷基、芳基、杂芳基、羧酸、羧酸酯、未取代或取代的羧酸酰胺、羟基或C1至C4羟基烷基，或者R2和R3一起代表C1至C6烷基烯基；Z代表C1至C10烷基二基团，可由杂原子中断，芳香或杂芳二基团，可取代一个羟基、一个C1至C6烷基团和/或经过一次或两次苯环缩合；或Z为—Ar(Alk)n—Ar—，其中Ar代表芳基团或杂芳基团，Alk代表—CH2—基团，n为0至6；x和y为0或1。
• Process for making 1,4-diamino-2-methoxymethylbenzene and salts thereof and compositions and methods for dyeing keratin fibers containing same
  申请人：——

  公开号：US20030041392A1

  公开（公告）日：2003-03-06

  A process is described for making 1,4-diamino-2-methoxymethylbenzene of formula (I), or a physiologically compatible salt of 1,4-diamino-2-methoxy-methylbenzene, of formula (I): 1 wherein n is a number from 0 to 2 and HX represents an inorganic or organic acid. The process includes reacting 2-methoxymethyl-4-nitrophenol with a halogenacetamide to form 2-(2-methoxymethyl-4-nitrophenoxy)acetamide; rearranging the 2-(2-methoxymethyl-4-nitrophenoxy)acetamide to form 2-methoxymethyl-4-nitroaniline and then catalytically hydrogenating the 2-methoxymethyl-4-nitroaniline and, when n=1 or 2, subsequently reacting with the inorganic or organic acid, to form the 1,4-diamino-2-methoxymethylbenzene of formula (I), or the salt if n=1 or 2. Compositions and methods of dyeing hair containing the 1,4-diamino-2-methoxymethylbenzene or its salt are also described.

  描述了一种制备1,4-二氨基-2-甲氧甲基苯的过程，或者制备1,4-二氨基-2-甲氧甲基苯的生理兼容盐的过程，其中n是从0到2的数字，HX代表无机或有机酸。该过程包括将2-甲氧甲基-4-硝基苯酚与卤代乙酰胺反应，形成2-(2-甲氧甲基-4-硝基苯氧基)乙酰胺；将2-(2-甲氧甲基-4-硝基苯氧基)乙酰胺重排，形成2-甲氧甲基-4-硝基苯胺，然后催化氢化2-甲氧甲基-4-硝基苯胺，并且当n=1或2时，随后与无机或有机酸反应，形成1,4-二氨基-2-甲氧甲基苯的化学式(I)，或者如果n=1或2，则形成盐。还描述了含有1,4-二氨基-2-甲氧甲基苯或其盐的染发剂的组合物和染发方法。
• Use of cationic azacyanine dyes for coloring keratin fibers
  申请人：Javet Manuela

  公开号：US20070022545A1

  公开（公告）日：2007-02-01

  The present invention relates to the use of cationic azacyanine dyes of the formula (Ia) or (Ib) for coloring keratin fibers, and to a method of coloring hair with various degrees of damage.

  本发明涉及使用带正电的氮杂菁染料的化学式(Ia)或(Ib)来染色角蛋白纤维，以及使用各种程度受损的头发染色的方法。
• PROCESS FOR DYEING HAIR
  申请人：Henkel AG & Co. KGaA

  公开号：US20200397684A1

  公开（公告）日：2020-12-24

  The subject of the present disclosure is a process for dyeing human hair, in which a pretreatment agent (A) which contains at least one organic silicon compound of the formula (I) and/or (II) and contains no direct dyes and no pigments, and a colorant (B) which contains at least one organic silicon compound of the formula (I) and/or (II) and further contains at least one colorant compound from the group of direct dyes and/or pigments, can be applied to the hair, wherein the organic silicon compounds of formulae (I) and (II) are defined as follows R 1 R 2 N-L-Si(OR 3 ) a (R 4 ) b (I), (R 5 O) c (R 6 ) d Si-(A) e -[NR 7 -(A′)] f —[O-(A″)] g -[NR 8 -(A′″)] h —Si(R 6 ′) d′ (OR 5 ′) c′ (II).

  本公开的主题是一种染色人类头发的过程，其中可以将含有至少一种有机硅化合物公式(I)和/或(II)且不含有直接染料和颜料的预处理剂(A)，和含有至少一种有机硅化合物公式(I)和/或(II)且进一步含有直接染料和/或颜料化合物群中的至少一种颜料化合物的染料剂(B)应用于头发上。其中，公式(I)和(II)的有机硅化合物定义如下：R1R2N-L-Si(OR3)a(R4)b(I)，(R5O)c(R6)dSi-(A)e-[NR7-(A′)]f—[O-(A″)]g-[NR8-(A′″)]h—Si(R6′)d′(OR5′)c′(II)。
• Novel diaminopyrazole derivatives and dyes containing said compounds
  申请人：——

  公开号：US20030115684A1

  公开（公告）日：2003-06-26

  Diaminopyrazole derivatives of the general Formula (I) or their physiological tolerated, water-soluble salts with inorganic or organic acids, 1 and agents, containing these compounds, for the oxidative dyeing of fibers.

  通式（I）的二氨基吡唑衍生物或其生理耐受性、水溶性盐，包括这些化合物的无机或有机酸，以及用于纤维氧化染色的剂。

表征谱图