(1E,3E,5E)-1-(4-chlorophenyl)-6-phenyl-1,3,5-hexatriene | 36288-11-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1E,3E,5E)-1-(4-chlorophenyl)-6-phenyl-1,3,5-hexatriene
• 英文别名: 1-chloro-4-[(1E,3E,5E)-6-phenylhexa-1,3,5-trienyl]benzene
• CAS: 36288-11-6
• 化学式: C₁₈H₁₅Cl
• 分子量: 266.77
• InChiKey: SNVBGMZDJVPHAI-HOXLXQKJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (1E,3E,5E)-1-(4-chlorophenyl)-6-phenyl-1,3,5-hexatriene 在 碘 作用下， 以 苯 为溶剂， 生成 3-chlorochrysene
  参考文献：
  名称：

  Photocyclization Reactions of Aryl Polyenes. V. Photochemical Synthesis of Substituted Chrysenes

  摘要：

  1,6-二对位取代苯基-1,3,5-己三烯的光环化-氧化反应产生了3,9-二取代蒽。类似地，对1-对位取代苯基-6-苯基-1,3,5-己三烯的辐射处理产生了3-取代蒽。通过1-α-萘基-2-对位取代苯乙烯的光环化-氧化，高产率地独立制备了3-取代蒽。

  DOI：

  10.1139/v72-081
• 作为产物：
  描述：

  5-苯基戊烷-2,4-双酸 、 2-溴-1-(4-氯苯基)乙烯 在 lithium acetate 、 silver(I) acetate 、 palladium diacetate 、 lithium chloride 作用下， 以66%的产率得到(1E,3E,5E)-1-(4-chlorophenyl)-6-phenyl-1,3,5-hexatriene
  参考文献：
  名称：

  桂皮酸与乙烯基溴化物在钯催化下的脱羧偶联反应合成α，ω-二芳基丁二烯和-十六碳二烯

  摘要：

  易得的肉桂酸衍生物（如阿魏酸）在钯催化下与β-溴苯乙烯和1-溴-4-苯基丁二烯偶合，并伴随脱羧反应分别生成相应的α，ω-二芳基丁二烯和-己三烯。一些产品表现出固态荧光。

  DOI：

  10.1021/ol9027896

文献信息

• TRIARYLAMINE DERIVATIVE, ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMEBER, AND IMAGE FORMING APPARATUS
  申请人：KYOCERA Document Solutions Inc.

  公开号：US20160062253A1

  公开（公告）日：2016-03-03

  A triarylamine derivative is represented by general formula (I). In general formula (I), R 1 and R 2 each represent, independently of one another, a chemical group selected from the group consisting of a halogen atom, an optionally substituted alkyl group having a carbon number of 1-6, an optionally substituted alkoxy group having a carbon number of 1-6, and an optionally substituted aryl group having a carbon number of 6-12. In general formula (I), k and l each represent an integer of at least 0 and no greater than 4. When k and l represent integers greater than 1, chemical groups R 1 bonded to the same aromatic ring and chemical groups R 2 bonded to the same aromatic ring may be the same or different to one another. In general formula (I), m and n each represent a different integer of at least 1 and no greater than 3.
• US9690217B2
  申请人：——

  公开号：US9690217B2

  公开（公告）日：2017-06-27
• Synthesis of α,ω-Diarylbutadienes and -Hexatrienes via Decarboxylative Coupling of Cinnamic Acids with Vinyl Bromides under Palladium Catalysis
  作者：Mana Yamashita、Koji Hirano、Tetsuya Satoh、Masahiro Miura

  DOI：10.1021/ol9027896

  日期：2010.2.5

  Readily available cinnamic acid derivatives such as ferulic acid couple with β-bromostyrenes and 1-bromo-4-phenylbutadiene under palladium catalysis accompanied by decarboxylation to produce the corresponding α,ω-diarylbutadienes and -hexatrienes, respectively. Some of the products exhibit solid-state fluorescence.

  易得的肉桂酸衍生物（如阿魏酸）在钯催化下与β-溴苯乙烯和1-溴-4-苯基丁二烯偶合，并伴随脱羧反应分别生成相应的α，ω-二芳基丁二烯和-己三烯。一些产品表现出固态荧光。
• Photocyclization Reactions of Aryl Polyenes. V. Photochemical Synthesis of Substituted Chrysenes
  作者：Clifford C. Leznoff、Roger J. Hayward

  DOI：10.1139/v72-081

  日期：1972.2.15

  The photocyclization-oxidation reaction of 1,6-di-p-substituted-phenyl-1,3,5-hexatrienes gave 3,9-disubstituted-chrysenes. Similarly, irradiation of 1-p-substituted-phenyl-6-phenyl-1,3,5-hexatrienes yielded 3-substituted-chrysenes. The 3-substituted-chrysenes were independently prepared in a high yield by the photocyclization-oxidation of 1-α-naphthyl-2-p-substituted-phenylethylenes.

  1,6-二对位取代苯基-1,3,5-己三烯的光环化-氧化反应产生了3,9-二取代蒽。类似地，对1-对位取代苯基-6-苯基-1,3,5-己三烯的辐射处理产生了3-取代蒽。通过1-α-萘基-2-对位取代苯乙烯的光环化-氧化，高产率地独立制备了3-取代蒽。