n-propyl p-styrene sulfonate | 16736-99-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: n-propyl p-styrene sulfonate
• 英文别名: 4-vinyl-benzenesulfonic acid propyl ester；4-Vinyl-benzolsulfonsaeure-propylester；p-Vinyl-benzolsulfonsaeure-n-propylester；n-Propyl p-styrene sulphonate；propyl 4-ethenylbenzenesulfonate
• CAS: 16736-99-5
• 化学式: C₁₁H₁₄O₃S
• 分子量: 226.296
• InChiKey: HCVDTJYOICHYBR-UHFFFAOYSA-N

物化性质

• 沸点：
  70-71 °C(Press: 0.005 Torr)
• 密度：
  1.165 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  sodium p-styrenesulfonate 在 三乙烯二胺 、 氯化亚砜 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 生成 n-propyl p-styrene sulfonate
  参考文献：
  名称：

  Design, synthesis and thermal behaviour of a series of well-defined clickable and triggerable sulfonate polymers

  摘要：

  在印刷行业中，利用可在施加后沉积外部刺激时改变其表面特性的可触发材料对于生产坚固的层和图案至关重要。

  DOI：

  10.1039/c5ra13867a

文献信息

• PREPARATION OF ION-EXCHANGE RESINS
  作者：I. H. Spinner、J. Ciric、W. F. Graydon

  DOI：10.1139/v54-021

  日期：1954.2.1

  Ion-exchange resins as membranes and in granular form have been prepared by the copolymerization of divinylbenzene with various esters of p-styrene-sulphonic acid and subsequent hydrolysis. The synthesis of the sulphonated styrene monomers is described. Equilibrium data for the sodium–hydrogen ion exchange on a resin prepared in this manner are discussed in terms of postulated variations of sulphonate group environment.

  离子交换树脂作为膜和颗粒形式已经通过二乙烯基苯与各种对苯磺酸酯的共聚反应及随后的水解制备。本文描述了磺化苯乙烯单体的合成方法。钠离子和氢离子交换在这种树脂上的平衡数据是根据假设的磺酸基环境变化来讨论的。
• NANO-STRUCTURED POLYMER COMPOSITES AND PROCESS FOR PREPARING SAME
  申请人：Hillmyer Marc

  公开号：US20100292077A1

  公开（公告）日：2010-11-18

  A process for preparing a polymer composite that includes reacting (a) a multi-functional monomer and (b) a block copolymer comprising (i) a first block and (ii) a second block that includes a functional group capable of reacting with the multi-functional monomer, to form a crosslinked, nano-structured, bi-continuous composite. The composite includes a continuous matrix phase and a second continuous phase comprising the first block of the block copolymer.

  一种制备聚合物复合材料的方法，包括反应（a）多官能单体和（b）由（i）第一块和（ii）包括能够与多官能单体反应的官能基的第二块组成的嵌段共聚物，以形成交联的、纳米结构的、双连续复合材料。该复合材料包括一个连续的基质相和一个由嵌段共聚物的第一块组成的第二个连续相。
• Styrenic block copolymer and process for producing same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0570932A2

  公开（公告）日：1993-11-24

  There are disclosed a styrenic block copolymer having a reduced viscosity of 0.01 to 20 dl/g (0.05 g/l in 1,2,4-trichlorobenzene at 135°C) which comprises highly syndiotactic styrenic-polymer segments and 10⁻⁴ to 10 mol% of heteroatom-containing styrenic polymer segments; a resin composition comprising the above styrenic block copolymer and a thermoplastic resin, an inorganic filler or an organic filler; a multi-layer material comprising at least one layer composed of the above styrenic block copolymer or the above resin composition; and a process for producing the above styrenic block copolymer which comprises polymerizing a styrenic monomer in the presence of a specific catalyst and adding a heteroatom-containing styrenic monomer to successively proceed with copolymerizaiton reaction. The above-disclosed styrenic block copolymer and the resin composition exhibit excellent compatibiity and adhesivenesss, and the multi-layer material is expected to find a wide range of applications in automobile parts, electrical and electronic parts as well as film, sheet, etc.

  本发明公开了一种苯乙烯嵌段共聚物，其粘度降低至 0.01 至 20 dl/g （在 135°C 的 1，2，4-三氯苯中为 0.05 g/l in 1,2,4-trichlorobenzene at 135°C)的苯乙烯嵌段共聚物，它由高度齐聚的苯乙烯聚合物段和 10-⁴ 至 10 摩尔%的含杂原子的苯乙烯聚合物段组成；一种树脂组合物，它由上述苯乙烯嵌段共聚物和一种热塑性树脂、一种无机填料或一种有机填料组成；一种多层材料，其中至少一层由上述苯乙烯嵌段共聚物或上述树脂组合物构成；以及一种生产上述苯乙烯嵌段共聚物的工艺，该工艺包括在特定催化剂存在下聚合苯乙烯单体，并加入含杂原子的苯乙烯单体以连续进行共聚反应。上述苯乙烯嵌段共聚物和树脂组合物具有优异的相容性和粘合性，多层材料有望广泛应用于汽车部件、电子电气部件以及薄膜、板材等领域。
• Responsive microgel and methods related thereto
  申请人：——

  公开号：US20030152623A1

  公开（公告）日：2003-08-14

  A responsive microgel is provided which responds volumetrically and reversibly to a change in one or more aqueous conditions selected from the group consisting of (temperature, pH, and ionic conditions) comprised of an ionizable network of covalently cross-linked homopolymeric ionizable monomers wherein the ionizable network is covalently attached to an amphiphilic copolymer to form a plurality of ‘dangling chains’ and wherein the ‘dangling chains’ of amphiphilic copolymer form immobile micelle-like aggregates in aqueous solution. A responsive microgel is further provided that comprises at least one therapeutic entity and delivers a substantially linear and sustained release of the therapeutic entity under physiological conditions.

  本发明提供了一种响应型微凝胶，该微凝胶可对选自由温度、pH 值和离子条件组成的组中的一种或多种水性条件的变化作出体积上和可逆的响应、和离子条件）组成的共价交联均聚可离子化单体的可离子化网络，其中可离子化网络与两性共聚物共价连接，形成多条 "悬链"，两性共聚物的 "悬链 "在水溶液中形成不动的胶束状聚集体。还提供了一种响应性微凝胶，它包含至少一种治疗实体，并能在生理条件下提供治疗实体的线性和持续释放。
• PARTICLES COMPRISING AMPHIPHILIC COPOLYMERS, HAVING A CROSS-LINKED SHELL DOMAIN AND AN INTERIOR CORE DOMAIN, USEFUL FOR PHARMACEUTICAL AND OTHER APPLICATIONS
  申请人：G.D. Searle & Co.

  公开号：EP0907666A1

  公开（公告）日：1999-04-14