1-phenylbutyl acrylate | 1369493-65-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenylbutyl acrylate
• 英文别名: 1-Phenylbutyl prop-2-enoate
• CAS: 1369493-65-1
• 化学式: C₁₃H₁₆O₂
• 分子量: 204.269
• InChiKey: ZSHODRAAOQTCOV-UHFFFAOYSA-N

物化性质

• 沸点：
  272.4±9.0 °C(Predicted)
• 密度：
  1.000±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-phenylbutyl acrylate 在 Lipase Amano AK 作用下， 反应 62.0h， 生成 (R)-(+)-1-苯基-1-丁醇 、 (S)-(-)-1-苯基-1-丁醇 、 (R)-1-phenylbutyl acrylate 、 (S)-1-phenylbutyl prop-2-enoate
  参考文献：
  名称：

  First example of hydrolytic kinetic resolution of acrylate of secondary alcohols by lipase Amano AK

  摘要：

  Lipase Amano AK is found to be extremely efficient catalyst for hydrolytic kinetic resolution of acrylates of secondary alcohols in aqueous phosphate buffer at pH 7.0. Both aliphatic and benzylic secondary alcohols show good to excellent E values. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcatb.2011.06.015
• 作为产物：
  描述：

  1-苯基-1-丁醇 、 丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以73%的产率得到1-phenylbutyl acrylate
  参考文献：
  名称：

  First example of hydrolytic kinetic resolution of acrylate of secondary alcohols by lipase Amano AK

  摘要：

  Lipase Amano AK is found to be extremely efficient catalyst for hydrolytic kinetic resolution of acrylates of secondary alcohols in aqueous phosphate buffer at pH 7.0. Both aliphatic and benzylic secondary alcohols show good to excellent E values. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcatb.2011.06.015

文献信息

• Low water content, high refractive index, flexible, polymeric compositions
  申请人：——

  公开号：US20030236375A1

  公开（公告）日：2003-12-25

  Optically transparent, relatively high refractive index polymeric compositions and ophthalmic devices such as intraocular lenses and corneal inlays made therefrom are described herein. The preferred polymeric compositions are produced through the polymerization of one or more copolymers with one or more hydrophilic monomers and optionally one or more aromatic-based monomers, hydrophobic monomers or a combination thereof.

  本文描述了光学透明、折射率相对较高的聚合物组合物以及由其制成的眼科设备，例如眼内透镜和角膜镶嵌物。优选的聚合物组合物是由一种或多种共聚物与一种或多种亲水性单体、一种或多种芳香族单体、疏水性单体或它们的组合聚合而成。
• Thermoplastic molding compositions
  申请人：——

  公开号：US20040054078A1

  公开（公告）日：2004-03-18

  Thermoplastic molding compositions essentially comprise (A) from 20 to 99% by weight of at least one graft copolymer, (B) from 1 to 80% by weight of a copolymer obtainable from at least one alpha-olefin and from at least one polar comonomer, with the proviso that the monomers used are not vinyl acetate or any vinylaromatic monomer, and (C) from 0 to 80% by weight of a thermoplastic polymer, obtainable by polymerizing a monomer mixture, essentially consisting of (c1) from 50 to 100% by weight of at least one vinylaromatic monomer and/or of a C 1 -C 8 -alkyl (meth)acrylate, and (c2) from 0 to 50% by weight of at least one monofunctional comonomer, and (D) from 0.1 to 15% by weight of a three-block polymer made from (d1) from 5 to 90% by weight of polyethylene oxide and (d2) from 95 to 10% by weight of polypropylene oxide and having a central polypropylene oxide block with a molar mass of from 800 to 5 000 g/mol and terminal blocks made from polyethylene oxide, where components A to D give 100% by weight in total. A process for preparing the thermoplastic molding compositions is also described, as is their use.

  热塑性模塑组合物主要包括 (A) 至少一种接枝共聚物，重量百分比为 20%至 99%、 (B) 1%至 80%（按重量计）由至少一种α-烯烃和至少一种极性共聚单体组成 的共聚物，但所使用的单体不得是醋酸乙烯酯或任何乙烯芳香族单体， 以及 (C) 0 至 80%（按重量计）的热塑性聚合物，可通过聚合单体混合物获得，该混 合物主要包括 (c1) 至少一种乙烯基芳香族单体和/或一种 C 1 -C 8 -烷基（甲基）丙烯酸酯，以及 (c2) 至少一种单官能团单体，重量百分比为 0 至 50%，以及 (D) 0.1 至 15%（按重量计）的三嵌段聚合物，由以下物质制成 (d1) 5%至 90%（按重量计）的聚环氧乙烷和 (d2) 95-10%（按重量计）的聚环氧丙烷 并具有摩尔质量为 800 至 5 000 克/摩尔的聚环氧丙烷中心嵌段和由聚环氧乙烷制成的终端嵌段、 其中 A 至 D 组份的总重量为 100%。 此外，还介绍了制备热塑性模塑组合物的工艺及其用途。
• METHOD OF PREPARING FOLDABLE HIGH REFRACTIVE INDEX ACRYLIC OPHTHALMIC DEVICE MATERIALS
  申请人：ALCON LABORATORIES, INC.

  公开号：EP1002244A1

  公开（公告）日：2000-05-24
• LOW WATER CONTENT HIGH REFRACTIVE INDEX, FLEXIBLE, POLYMERIC COMPOSITIONS
  申请人：BAUSCH & LOMB INCORPORATED

  公开号：EP1519968A1

  公开（公告）日：2005-04-06
• Particle perfume delivery system
  申请人：The Procter & Gamble Co.

  公开号：US20020016269A1

  公开（公告）日：2002-02-07

  The present invention relates to a fragrance raw material delivery system comprising: A) particles having: i) an average particle size of from about 5 microns; ii) a density of from about 0.9 g/cm 3 to about 1.5 g/cm 3 ; and B) a fragrance or fragrance accord component. The fragrance delivery systems of the present invention are suitable for use in delivering a fragrance or fragrance accord to a situs, inter alia, fabric in a manner which sustains the delivery of the aesthetic elements while providing a completely vehicle.