7-decyl-1,5,7-triazabicyclo[4.4.0]decane-5-ene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 7-decyl-1,5,7-triazabicyclo[4.4.0]decane-5-ene
• 英文别名: 7-decyl-1,5,7-triazabicyclo[4.4.0]-5-decene；7-decyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene；7-Decyl-1,5,7-triazabicyclo[4.4.0]dec-5-en；1-Decyl-2,3,4,6,7,8-hexahydropyrimido[1,2-a]pyrimidine
• 化学式: C₁₇H₃₃N₃
• 分子量: 279.469
• InChiKey: NSCKQAVTPSAALQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  18.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  癸基溴 、 1,5,7-三氮杂双环[4.4.0]癸-5-烯 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以78%的产率得到7-decyl-1,5,7-triazabicyclo[4.4.0]decane-5-ene
  参考文献：
  名称：

  N-TYPE DOPANTS FOR EFFICIENT SOLAR CELLS

  摘要：

  Triazabicylodecene可以有效地n-掺杂各种有机半导体，包括PCBM，从而增加平面导电性。我们通过N-烷基化反应合成了一系列基于TBD的n-掺杂剂，并研究了各种烷基链对掺杂剂的物理和器件性质的影响。将两个TBD基团结合在长烷基链上形成了固体掺杂剂2TBD-C10，其热稳定性高于250°C。经2TBD-C10掺杂的PCBM薄膜对热退火最具耐受性，并达到了6.5×10^−2S/cm的平面导电性。此外，在甲胺铅三碘化物（MAPbI3）基光伏器件中将2TBD-C10掺杂的PCBM作为电子传输层（ETL），性能提高了23%，从11.8%提高到14.5%的能量转换效率。

  公开号：

  US20200194686A1

文献信息

• CURABLE-ON-DEMAND COMPOSITION COMPRISING DUAL REACTIVE SILANE FUNCTIONALITY
  申请人：Yang Yu

  公开号：US20130178553A1

  公开（公告）日：2013-07-11

  A curable composition comprises (a) at least one inorganic or organic compound comprising reactive silane functionality comprising at least one hydrosilyl moiety; (b) at least one inorganic or organic compound comprising reactive silane functionality comprising at least one hydroxysilyl moiety, the hydroxysilyl moiety optionally being generated in situ by hydrolysis of at least one hydrosilyl moiety; and (c) at least one photoactivatable composition that, upon exposure to radiation, generates at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; with the proviso that, when component (a) is an organic polymer, then component (b) is different from component (a) and is not generated in situ by hydrolysis of component (a).

  一种可治愈的组合物包括：（a）至少一种含有反应性硅烷官能团的无机或有机化合物，其中硅烷官能团包括至少一个氢硅烷基；（b）至少一种含有反应性硅烷官能团的无机或有机化合物，其中硅烷官能团包括至少一个羟基硅烷基，羟基硅烷基可以通过至少一个氢硅烷基的水解而在原位生成；以及（c）至少一种光活性组合物，当暴露于辐射下时，生成至少一种从氨基甲酸酰胺、鸟嘌呤、磷氮烷、丙氨酸磷酸酯和其组合物中选择的碱，前提是当组分（a）是有机聚合物时，组分（b）与组分（a）不同，并且不是通过组分（a）的水解在原位生成的。
• CURABLE-ON-DEMAND POLYSILOXANE COATING COMPOSITION
  申请人：Yang Yu

  公开号：US20130101841A1

  公开（公告）日：2013-04-25

  A curable composition comprises (a) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydroxysilyl moieties; (b) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydrosilyl moieties; and (c) at least one photoactivatable composition that, upon exposure to radiation, generates at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; wherein at least one of the components (a) and (b) has an average reactive silane functionality of at least three.

  可治疗组合物包括：(a)至少一种聚二甲基硅氧烷、氟代聚二甲基硅氧烷或二者的组合物，其包含具有至少两个羟基硅基的反应性硅烷官能团；(b)至少一种聚二甲基硅氧烷、氟代聚二甲基硅氧烷或二者的组合物，其包含具有至少两个氢硅基的反应性硅烷官能团；以及(c)至少一种光致活性组分，当暴露于辐射下时，会产生从氨基化合物、胍化合物、磷氮化合物、脲基磷杂环丙烷和它们的组合物中选择的至少一种碱；其中，组分(a)和/或(b)中至少有一种的平均反应性硅烷官能团为至少三个。
• CURABLE COMPOSITION COMPRISING DUAL REACTIVE SILANE FUNCTIONALITY
  申请人：Yang Yu

  公开号：US20130102728A1

  公开（公告）日：2013-04-25

  A curable composition comprises (a) at least one inorganic or organic compound comprising reactive silane functionality comprising at least one hydrosilyl moiety; (b) at least one inorganic or organic compound comprising reactive silane functionality comprising at least one hydroxysilyl moiety, the hydroxysilyl moiety optionally being generated in situ by hydrolysis of at least one hydrosilyl moiety; and (c) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; with the proviso that, when component (a) is an organic polymer, then component (b) is different from component (a) and is not generated in situ by hydrolysis of component (a).

  一种可治愈的组合物包括：（a）至少一种含有反应性硅烷官能团的无机或有机化合物，其中该反应性硅烷官能团包括至少一个氢硅烷基；（b）至少一种含有反应性硅烷官能团的无机或有机化合物，其中该反应性硅烷官能团包括至少一个羟基硅烷基，该羟基硅烷基可以通过至少一个氢硅烷基的水解而在原位生成；以及（c）选自氨基甲酸酰胺、鸟氨酸、磷氮化物、丙磺酰膦杂环戊烷和其组合物中的至少一种碱，但当组分（a）为有机聚合物时，则组分（b）与组分（a）不同且不是通过组分（a）的水解在原位生成的。
• CURABLE COMPOSITION
  申请人：Matsushita Noriko

  公开号：US20090171025A1

  公开（公告）日：2009-07-02

  The present invention has its object to provide, by using a non-organotin curing catalyst, a curable composition having a practical level of curability. Furthermore, the present invention has its object to provide a curable composition excellent in adhesiveness while it secures a practical level of curability. The present invention relates to a curable composition which comprises: (A) an organic polymer containing a silicon-containing group capable of crosslinking by siloxane bond formation and (B) a silanol condensation catalyst: and that the silanol condensation catalyst is an amine compound and that an aqueous solution prepared by adding 5 millimoles of the amine compound to 100 g of a mixed solvent composed of isopropyl alcohol and water in a weight ratio of 10:3 has a pH value of not lower than 13.4 as measured at 23° C. according to JIS Z 8802.

  本发明的目的是提供一种可固化组合物，使用非有机锡固化催化剂，具有实用的固化水平。此外，本发明的目的是提供一种优异的粘附性可固化组合物，同时保证实用的固化水平。本发明涉及一种可固化组合物，其包括：（A）含有硅含基的有机聚合物，能够通过硅氧烷键形成交联，以及（B）硅醇缩合催化剂；所述硅醇缩合催化剂是胺化合物，并且将5毫摩尔的胺化合物加入到由异丙醇和水按重量比10:3组成的混合溶剂100克中制备的水溶液，在23℃下按照JIS Z 8802测量，其pH值不低于13.4。
• Curable composition having a special catalyst/softner system
  申请人：Henkel AG & Co. KGaA

  公开号：US10336863B2

  公开（公告）日：2019-07-02

  In a curable composition that contains at least one polymer having at least one terminal group of the general formula (I) -An-R—SiXYZ  (I), at least one cyclic compound that contains at least one structural motif of formula (II) as a constituent of the ring structure; and at least one cyclohexanedicarboxylic acid dialkyl ester in which the alkyl residues of the ester groups each, mutually independently, contain 1 to 20 carbon atoms. The curable composition can be used as an adhesive, sealant, and/or coating material. A combination of a cyclohexanedicarboxylic acid dialkyl ester, in which the alkyl residues of the ester groups each, mutually independently, contain 1 to 20 carbon atoms and a cyclic compound that contains at least one structural motif of the general formula (II) as a constituent of the ring structure, as a plasticizer/curing catalyst system in curable compositions.

  在含有至少一种具有通式 (I) 中至少一个末端基团的聚合物的可固化组合物中 -An-R-SiXYZ (I)、 至少一种环状化合物，该化合物含有至少一个式 (II) 的结构基团作为环结构的组成成分；以及 至少一种环己烷二羧酸二烷基酯，其中酯基的烷基残基各自独立地含有 1 至 20 个碳原子。固化组合物可用作粘合剂、密封剂和/或涂层材料。一种环己烷二羧酸二烷基酯（其中酯基的烷基残基各自独立地含有 1 至 20 个碳原子）与一种环状化合物的组合，该环状化合物含有至少一个通式（II）的结构基团作为环状结构的组成成分，作为可固化组合物中的增塑剂/固化催化剂体系。