1,4-bis(triphenylstannyl)butane | 5274-40-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis(triphenylstannyl)butane
• 英文别名: Ph3Sn(CH2)4SnPh3；hexa-Sn-phenyl-Sn,Sn'-butanediyl-bis stannane；Hexa-Sn-phenyl-Sn,Sn'-butandiyl-bis-stannan；1,4-Bis-triphenylstannyl-butan
• CAS: 5274-40-8
• 化学式: C₄₀H₃₈Sn₂
• 分子量: 756.162
• InChiKey: ORIOFDWKAKXJIR-UHFFFAOYSA-N

物化性质

• 熔点：
  149-150.5 °C
• 沸点：
  695.0±65.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.11
• 重原子数：
  42
• 可旋转键数：
  11
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,4-bis(triphenylstannyl)butane 在 氢溴酸 作用下， 以 二氯甲烷 为溶剂， 以75%的产率得到1,4-bis(bromodiphenylstannyl)butane
  参考文献：
  名称：

  含有锡的大环。1,1,6,6,11,11,11,16,16-八环烷-1,6,11,16-十四烷环二十烷的两个合成和1,1,6,6-四苯基-1,6-二烷环癸烷的合成

  摘要：

  DOI：

  10.1021/om00073a039
• 作为产物：
  描述：

  三苯基氯化锡 、 (butane-1,4-diyl)dimagnesium dibromide 生成 1,4-bis(triphenylstannyl)butane
  参考文献：
  名称：

  Zimmer; Mosle, Chemische Berichte, 1954, vol. 87, p. 1255

  摘要：

  DOI：

文献信息

• Spacer-bridged ladder compounds—syntheses, structures and synthetic applications
  作者：Michael Mehring、Markus Schürmann、Ingo Paulus、Dagmar Horn、Klaus Jurkschat、Akihiro Orita、Junzo Otera、Dainis Dakternieks、Andrew Duthie

  DOI：10.1016/s0022-328x(98)00935-8

  日期：1999.2

  is obtained by reaction of 22 with silver acetate or by treatment of the organotin oxide [R(O)SnCH2]2CH2 (R=Me3SiCH2) with acetic acid. The crystal structures of 23, 24, and 28 are described and reveal that these compounds adopt double ladder structures. Depending on the identity of Z and R in chloroform solution the compounds are either dimers (n=2, 25–28) or tetramers (n=4, 22–24). Also reported are

  的反应α，ω -双（organodichlorostannyl）烷烃[R（CL 2）SNCH 2 ] 2 Z，使用有机锡对应其氧化物[R（O）SNCH 2 ] 2 Z或（吨-Bu 2的SnO）3提供了新的间隔桥四有机二锡氧烷[R（Cl）SnCH 2 ] 2 Z] O} n（22，Z = CH 2，R = Me 3 SiCH 2 ; 23，Z = CH 2，R = Me 3 CCH 2 ; 24， Z = CH2 CH 2，R ＝ Me 3 SiCH 2；25，Z = CH 2 CH 2，R = Me 3 CCH 2；26，Z = CH 2 CH 2，R = Me 2 CHCH 2；在图27中，Z ＝ Me 2 Si，R ＝ Me 3 SiCH 2）。乙酸酯取代的衍生物28 [R（AcO）SnCH 2 ] 2 CH 2 ] O} n（R = Me 3 SiCH 2）通过以下反应获得22用
• Devaud, Marguerite; Lepousez, Patrice, Journal of Chemical Research - Part S
  作者：Devaud, Marguerite、Lepousez, Patrice

  DOI：——

  日期：——
• Macrocycles containing tin. Syntheses of symmetrical macrocycles containing two or four diphenylstanna units
  作者：Yutaka Azuma、Martin Newcomb

  DOI：10.1021/om00079a003

  日期：1984.1
• α,ω-Bis(trichlorostannyl)alkanes:  Unravelling the Hydrolysis Pathway to Organotin-oxo Oligomers
  作者：Bernhard Zobel、Andrew Duthie、Dainis Dakternieks、Edward R. T. Tiekink

  DOI：10.1021/om010202j

  日期：2001.6.1

  New alpha,omega -bis(trichlorostannyl)alkanes, Cl3Sn(CH2)(n)SnCl3 [n = 3-5, 8], have been synthesized via tin-phenyl bond cleavage reactions on alpha,omega -bis(triphenylstannyl)alkanes, Ph3Sn(CH2)(n)SnPh3 [n = 3-5, 8], using either SnCl4 or concentrated hydrochloric acid. Some key missing links, (H2O)Cl3Sn(CH2)(3)SnCl3(H2O) (1a) and (H2O)(2)Cl3Sn(CH2)(3)SnCl3(H2O)(2) (6), in the hydrolysis pathway of organotin trichlorides were identified. Crystal structures of the nonassociated di-tin compounds (H2O)Cl3Sn(CH2)(3)SnCl3(H2O) (1a) and (H2O)(2)Cl3Sn(CH2)(3)SnCl3(H2O)(2) (6, isolated as the 18-crown-6 cocrystal acetonitrile solvate) as well as the polymeric hydrolysis product [H2O(OH)Cl2Sn(CH2)(3)SnCl2(OH)H2O . 2H(2)O](n) (7 . 2H(2)O) are reported.
• Synthesis, structures and preliminary biological screening of bis(diphenyl)chlorotin complexes and adducts: Ph2ClSn–CH2–R–CH2–SnClPh2, R=p-C6H4, CH2CH2
  作者：Srawan K. Thodupunoori、Israel A. Alamudun、Francisco Cervantes-Lee、Fabiola D. Gomez、Yazmin P. Carrasco、Keith H. Pannell

  DOI：10.1016/j.jorganchem.2005.12.040

  日期：2006.4

  The reaction between ClCH2-R-CH2Cl, R = p-C6H4, and [Ph3Sn]Li--(+) yields Ph3Sn-CH2-R-CH2-SnPh3 (1) in high yield. The related known compound R = CH2CH2 (1a) is synthesized by the reaction of the di-Grignard reagent BrMg(CH2)(4)MgBr with two equivalents of Ph3SnCl. Cleavage of a single Sn-Ph group at each tin centre of both compounds using HCl/Et2O yields the corresponding bis-chlorostannanes Ph2ClSn-CH2-R-CH2-SnClPh2, R = (CH2)(4) (2) and R = C6H4 (3), respectively. Compounds 1, 2 and 3 are crystalline solid materials and their single crystal X-ray structures are reported. In the solid state both 2 and 3 form self-assembled ladder structures involving alternating intermolecular Cl-(SnCl)-Cl-... and (ClSn)-Sn-...-Cl bonded chains at both ends of the distannanes with 5-coordinate tin atoms. Recrystallization of 3 from CH2Cl2 in the presence of DMF yields the bis-DMF adduct (4) in which no self-assembled structures were noted. Evaluation of the chlorostannanes 2 and 3 against a suite of bacteria, Staphylococcus aureus, Escherichia coli and Photobacterium phosphoreum is reported and compared to the related mono-chlorostannanes Ph-2(CH3)SnCl and Ph-2(PhCH2)SnCl. (c) 2006 Published by Elsevier B.V.