1,1,2,2,3,3,4,4,4a,5,5,6,6,7,8,8,8a-十七氟-7-(三氟甲基)萘 | 306-95-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 1,1,2,2,3,3,4,4,4a,5,5,6,6,7,8,8,8a-十七氟-7-(三氟甲基)萘
• 中文别名: 1-丙胺,N-(1-甲基乙基)-3-(4-甲基苯氧基)-
• 英文名称: Perfluor-2-methyl-decalin
• 英文别名: 1,1,2,2,3,3,4,4,4a,5,5,6,6,7,8,8,8a-Heptadecafluorodecahydro-7-(trifluoromethyl)naphthalene；1,1,2,2,3,3,4,4,4a,5,5,6,6,7,8,8,8a-heptadecafluoro-7-(trifluoromethyl)naphthalene
• CAS: 306-95-6
• 化学式: C₁₁F₂₀
• 分子量: 512.089
• InChiKey: DVPQLHWKBCBNDB-UHFFFAOYSA-N

物化性质

• 沸点：
  160-161 °C
• 密度：
  1.9632 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  31
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为反应物：
  描述：

  1,1,2,2,3,3,4,4,4a,5,5,6,6,7,8,8,8a-十七氟-7-(三氟甲基)萘 在 铁粉 三氯化铝 、 硫酸 、 碳酸氢钠 、 乙酰氯 作用下， 生成 1,3,4,5,6,7,8-heptafluoronaphthalene
  参考文献：
  名称：

  37.多环氟芳族化合物。第二部分全氟甲基萘及其衍生化合物

  摘要：

  DOI：

  10.1039/jr9620000190
• 作为产物：
  描述：

  2-甲基萘 在 cobalt (III) fluoride 作用下， 生成 1,1,2,2,3,3,4,4,4a,5,5,6,6,7,8,8,8a-十七氟-7-(三氟甲基)萘
  参考文献：
  名称：

  715.有机氟化物。第五部分：三氟化钴对烃类的氟化

  摘要：

  DOI：

  10.1039/jr9500003617

文献信息

• Process for making oriented film of fluorinated polymer
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0145426A2

  公开（公告）日：1985-06-19

  A process for making oriented film of perfluorinated polymer which is either an ion exchange polymer or a melt-fabricable precursor thereto, which has been extended in the range of about 1.3X to 3X in at least one planar direction, is disclosed. Such film is made by swelling a film in melt-fabricable form in a liquid organic compound and either restraining it while drying, or stretching it followed by drying under restraint. The oriented melt-fabricable film can be converted to ion-exchange film by hydrolysis under restraint. The resulting film has good anion rejection properties, strength and flatness, and remains taut in use after being mounted dry in a chloralkali cell.

  本发明公开了一种用于制造全氟聚合物定向薄膜的工艺，该薄膜是一种离子交换聚合物或其可熔融成型的前体，至少在一个平面方向上延伸了约 1.3 倍至 3 倍。这种薄膜是通过在液态有机化合物中溶胀可熔融成型的薄膜，并在干燥过程中对其进行约束，或在约束下拉伸薄膜然后进行干燥而制成的。拉伸后的可熔融薄膜可在限制条件下通过水解作用转化为离子交换薄膜。得到的薄膜具有良好的阴离子排斥性能、强度和平整度，在氯碱池中干燥后仍能保持紧绷状态。
• Perfluorinated propyl derivative compounds
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0304808A1

  公开（公告）日：1989-03-01

  Novel compositions include compounds of the formula: wherein the carbon rings are fully fluorinated and R is selected from the group consisting of fluorine, -CF₃ or -CF(CF₃)₂.

  新型组合物包括如下式的化合物 其中碳环完全氟化，R 选自由氟、-CF₃ 或 -CF(CF₃)₂ 组成的组。
• Perfluorinated butyl derivative compounds
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0304809A1

  公开（公告）日：1989-03-01

  Novel compositions of matter are disclosed having the formula wherein the carbon rings are fully fluorinated to remove all hydrogens and olefinic character. The compositions have utility as heat transfer agents, hydraulic fluids, vapor phase soldering fluids, gas (O₂, N₂, CO₂, H₂, etc.) transport agents, such as in biological and medical fields, as well as utility as burn-in test fluid.

  公开了具有以下式子的新型物质组合物 其中的碳环已完全氟化，去除了所有的氢和烯烃特性。这些组合物可用作热传导剂、液压油、气相焊接液、气体（O₂、N₂、CO₂、H₂等）输送剂，如生物和医疗领域，还可用作烧损测试液。
• Curable mixtures for forming a lubricious surface of fluorinated lubricants and articles made therefrom
  申请人：Adaptive Surface Technologies, Inc.

  公开号：US10913877B2

  公开（公告）日：2021-02-09

  Curable compositions are provided for forming highly lubricious and long-lasting surfaces with optical clarity useful, for example, in optical applications in harsh environmental conditions. In some aspects, the curable formulations include an end-group modified perfluoropolyether (PFPE), a fluorinated lubricant, and a compatibilizer. The mixtures are curable to form a solid having an exposed surface. In some aspects, the fluorinated lubricant is chemically and physically matched to the resin such that, when cured, at least a portion of the fluorinated lubricant spontaneously forms a lubricious surface on the exposed surface. In some aspects, the compatibilizer is present in an amount sufficient to make the curable mixture miscible and to make the solid optically transparent while still spontaneously forming the lubricious surface. The lubricious surface can also be self-replenishing such that, when the lubricant is removed from the exposed surface, additional lubricant migrates to the surface to replenish the lubricious overlayer.

  所提供的可固化组合物用于形成具有光学清晰度的高润滑性和长效表面，例如在恶劣环境条件下的光学应用中。在某些方面，可固化配方包括端基改性全氟聚醚 (PFPE)、含氟润滑剂和相容剂。混合物可固化形成具有外露表面的固体。在某些方面，氟化润滑剂在化学和物理上与树脂相匹配，因此固化时，至少有一部分氟化润滑剂会在暴露表面自发形成润滑表面。在某些方面，相容剂的用量足以使可固化混合物混溶并使固体具有光学透明性，同时仍能自发形成润滑表面。润滑表面还可以自我补充，当润滑剂从暴露表面移除时，额外的润滑剂会迁移到表面以补充润滑覆盖层。
• Preparation of Fused-Ring Fluorocarbons
  作者：E. McBee、L. Bechtol

  DOI：10.1021/ie50447a630

  日期：1947.3