2,2-二氟-2-[1,1,2,2-四氟-2-[1,1,2,2-四氟-2-(三氟甲氧基)乙氧基]乙氧基]-乙酸 | 151772-59-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2,2-二氟-2-[1,1,2,2-四氟-2-[1,1,2,2-四氟-2-(三氟甲氧基)乙氧基]乙氧基]-乙酸
• 中文别名: 全氟-3,6,9-三氧杂葵酸
• 英文名称: perfluoromethoxydi(ethyleneoxy)acetic acid
• 英文别名: perfluoro(3,6,9-trioxadecanoic) acid；perfluoro-3,6,9-trioxadecanoic acid；2,2-difluoro-2-[1,1,2,2-tetrafluoro-2-[1,1,2,2-tetrafluoro-2-(trifluoromethoxy)ethoxy]ethoxy]acetic acid
• CAS: 151772-59-7
• 化学式: C₇HF₁₃O₅
• 分子量: 412.061
• InChiKey: GNQWOKPKDHCUSB-UHFFFAOYSA-N

物化性质

• 沸点：
  170-171°C
• 密度：
  1.8

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  25
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  65
• 氢给体数：
  1
• 氢受体数：
  18

安全信息

• TSCA：
  N
• 危险等级：
  CORROSIVE
• 海关编码：
  2918990090
• 危险品运输编号：
  UN 3265

反应信息

• 作为反应物：
  描述：

  2,2-二氟-2-[1,1,2,2-四氟-2-[1,1,2,2-四氟-2-(三氟甲氧基)乙氧基]乙氧基]-乙酸 在 electrolysis 作用下， 以 乙腈 为溶剂， 以98%的产率得到1,1,2,2-Tetrafluoro-1,2-bis[1,1,2,2-tetrafluoro-2-[1,1,2,2-tetrafluoro-2-(trifluoromethoxy)ethoxy]ethoxy]ethane
  参考文献：
  名称：

  Chechina, O. N.; Berenblit, V. V.; Levin, A. L., Russian Journal of Applied Chemistry, 1999, vol. 72, # 3, p. 425 - 430

  摘要：

  DOI：

文献信息

• Application of cyclodextrins (CDS) for remediation of perfluoroalkyl substances (PFASS)
  申请人：O'Shea Kevin E.

  公开号：US11149135B2

  公开（公告）日：2021-10-19

  A system for remediation of perfluoroalkyl substances (PFASs) has a multiplicity of β-cyclodextrins (β-CDs) and/or modified β-CDs combined with a vehicle additive, and a delivery device. Modified β-CDs can contain a single amine functionality at a single primary carbon or single secondary carbon of the β-CD. The vehicle additive can be powdered activated carbon (PAC). The delivery device is a column, a pouch, a packet, or a sheet that can permit the contacting of a fluid environment with the β-CDs and vehicle additive. The system of remediation can be used for a fluid environment or for biological organisms. CD-based fluorescent sensors can detect PFASs in the environment.

  一种用于修复全氟烷基物质（PFASs）的系统由多种 β-环糊精（β-CDs）和/或改性 β-CDs 与载体添加剂和输送装置组合而成。改性的 β-CD 可以在 β-CD 的单个伯碳或单个仲碳上含有单个胺官能团。载体添加剂可以是粉末活性炭（PAC）。输送装置可以是柱状、袋状、包状或片状，允许流体环境与 β-CD 和载体添加剂接触。修复系统可用于流体环境或生物有机体。基于 CD 的荧光传感器可以检测环境中的 PFAS。
• Lithography composition, a method for forming resist patterns and a method for making semiconductor devices
  申请人：Ridgefield Acquisition

  公开号：US11156920B2

  公开（公告）日：2021-10-26

  The present invention relates to a new lithography composition, the forming of resist patterns using the lithography composition, and a semiconductor device manufacturing method using the lithography composition in a photolithography method.

  本发明涉及一种新的光刻组合物、使用该光刻组合物形成抗蚀图案，以及在光刻方法中使用该光刻组合物的半导体器件制造方法。
• Fullerene compound, lubricant for magnetic recording medium, and magnetic recording medium
  申请人：SHOWA DENKO K.K.

  公开号：US11261395B2

  公开（公告）日：2022-03-01

  The invention provides a fullerene compound; a lubricant that is for a magnetic recording medium and that contains the fullerene compound; and a magnetic recording medium. The fullerene compound is an ionic liquid that is represented by general formula (1) and is formed from a Bronsted acid (Hn1X) and a Bronsted base ([R2R3)N—]m1—R1); wherein one of the Brønsted acid and the Broønsted base contains a group having a fullerene; and the other contains a perfluoroalkyl chain.

  本发明提供了一种富勒烯化合物；一种用于磁记录介质且含有该富勒烯化合物的润滑剂；以及一种磁记录介质。富勒烯化合物是一种离子液体，由通式（1）表示，并由布氏酸（Hn1X）和布氏碱（[R2R3)N-]m1-R1）形成；其中布氏酸和布氏碱中的一个含有富勒烯基团；另一个含有全氟烷基链。
• Composition and method for capture and degradation of PFAS
  申请人：Battelle Memorial Institute

  公开号：US11518689B2

  公开（公告）日：2022-12-06

  Materials for binding per- and polyfluoroalkyl substances (PFAS) are disclosed. A fluidic device comprising the materials for detection and quantification of PFAS in a sample is disclosed. The fluidic device may be configured for multiplexed analyses. Also disclosed are methods for sorbing and remediating PFAS in a sample. The sample may be groundwater containing, or suspected of containing, one or more PFAS.

  本发明公开了用于结合全氟和多氟烷基物质（PFAS）的材料。还公开了一种流体装置，其中包含用于检测和定量样品中 PFAS 的材料。该流体装置可用于多重分析。还公开了吸附和修复样品中 PFAS 的方法。样品可以是含有或怀疑含有一种或多种 PFAS 的地下水。
• Heavy fluorous phosphine-free ruthenium catalysts for alkene metathesis
  作者：Mario Babuněk、Ondřej Šimůnek、Jan Hošek、Markéta Rybáčková、Josef Cvačka、Anna Březinová、Jaroslav Kvíčala

  DOI：10.1016/j.jfluchem.2014.03.003

  日期：2014.5

  Second generation Grubbs catalyst was modified stepwise with perfluoroalkylated isopropoxystyrene and two perfluoroalkanoate or perfluoropolyoxaalkanoate ligands to afford heavy fluorous phosphine-free ruthenium complexes, which displayed high activity in model ring-closing metathesis reactions. Surprisingly, substitution with linear perfluoropolyether chains led to the complexes of higher activity and fluorophilicity compared to perfluoroalkyl chains, while the use of branched perfluoropolyether ponytails resulted in significantly inferior activity probably due to increased steric hindrance around the active ruthenium centre. Similar reactivity pattern with slightly lower activity was observed for the second generation Hoveyda-Grubbs catalysts bearing perfluoroalkanoate or perfluoropolyoxaalkanoate groups and non-fluorinated isopropoxybenzylidene ligand. Depending on the reaction system, unactivated precatalysts can be recycled by heavy fluorous extraction with perfluoro(methylcyclohexane). (C) 2014 Elsevier B.V. All rights reserved.