P-dimethylamino-N-(2,4,6-tri-tert-butylphenyl)-λ³-iminophosphine | 118818-60-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: P-dimethylamino-N-(2,4,6-tri-tert-butylphenyl)-λ³-iminophosphine
• 英文别名: cis-N,N-dimethylamino-N'-<2,4,6-tri(tert-butyl)phenyl>iminophosphine；(Z)-N,N-dimethyl-N'-(2,4,6-tri-tert-butylphenyl)phosphenimidous amide；N,N-Dimethyl-N'-(2,4,6-tri-t-butylphenyl)aminoiminophosphine；P-dimethylamino-N-(2,4,6-tri-tert-butylphenyl)phosphinimine；N-methyl-N-(2,4,6-tritert-butylphenyl)iminophosphanylmethanamine
• CAS: 118818-60-3；125340-50-3；160720-94-5
• 化学式: C₂₀H₃₅N₂P
• 分子量: 334.485
• InChiKey: FONQGHKWYLJJLQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  15.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  P-dimethylamino-N-(2,4,6-tri-tert-butylphenyl)-λ³-iminophosphine 、 alkaline earth salt of/the/ methylsulfuric acid 生成 P-Dimethylamino-N-<2,4,6-tri(tert-butyl)phenyl>imino-C,C-bis(trimethylsilyl)methylenephosphorane
  参考文献：
  名称：

  Molecular structure of ?3?5

  摘要：

  DOI：

  10.1007/bf00753001
• 作为产物：
  描述：

  二甲基氯化磷胺 、 2,4,6-三叔丁基-N-(三甲基甲硅烷基)苯胺 在 正丁基锂 作用下， 生成 P-dimethylamino-N-(2,4,6-tri-tert-butylphenyl)-λ³-iminophosphine
  参考文献：
  名称：

  Markovskii, L. N.; Romanenko, V. D.; Ruban, A. V., Journal of general chemistry of the USSR, 1990, vol. 60, # 11, p. 2193 - 2200

  摘要：

  DOI：

文献信息

• Romanenko, V. D.; Ruban, A. V.; Reitel, G. V., Journal of general chemistry of the USSR, 1989, vol. 59, # 9.2, p. 1909 - 1910
  作者：Romanenko, V. D.、Ruban, A. V.、Reitel, G. V.、Povolotskii, M. I.、Markovskii, L. N.

  DOI：——

  日期：——
• Synthesis and characterization of new phosphanylium and phosphanetriylammonium salts. Molecular structures of [(Me₂N)PN(AlCl₃)R] and [P(NPrⁱ₂)(NHR)]⁺[CF₃SO₃]^–(R = C₆H₂Bu^t₃-2,4,6)
  作者：Andrei B. Drapailo、Alexander N. Chernega、Vadim D. Romanenko、Rachid Madhouni、Jean-Marc Sotiropoulos、Lydia Lamandé、Michel Sanchez

  DOI：10.1039/dt9940002925

  日期：——

  The new internal salts [(R(1)R(2)N)PN(ECl(3))R] (E = Al or Ga; R = 2,4,6-Bu(3)(t)C(6)H(2)) and phosphanylium salts [P(NR(1)R(2))(NHR)](+)[C6(3)SO(3)](-) have been synthesized by treating aminoiminophosphanes (R(1)R(2)N)P=NR with AlCl3, GaCl3 or CF3SO3H. Protonation of RHN-P=NR with trifluoromethanesulfonic acid led to the first stable phosphanylium salt [P(NHR)(2)](+)[CF3SO3](-) with two primary amino groups. In contrast, the reaction of AlCl3 with the (aryloxy) iminophosphane (R'O) P=NR (R' = 4.Me-2,6-Bu(2)(t)C(6)H(2)) led to the new aryl(phosphanetriyl)ammonium complex [PNR](+)[(R'O)AlCl3](-). All compounds were characterized by multinuclear NMR spectroscopy. The crystal structures of [(Me(2)N)PN(AlCl3)R] and [P(NPr2i)(NHR)](+)[(CFSO3)-S-3](-) have been determined by single-crystal X-ray diffractometry.
• Romanenko, V. D.; Ruban, A. V.; Chernega, A. N., Journal of general chemistry of the USSR, 1988, vol. 58, # 4, p. 842 - 844
  作者：Romanenko, V. D.、Ruban, A. V.、Chernega, A. N.、Povolotskii, M. I.、Antipin, M. Yu.、et al.

  DOI：——

  日期：——
• POMAHEHKO, V. D.;RUBAN, A. V.;REJTEL, G. V.;POVOLOTSKIJ, M. I.;MARKOVSKIJ+, ZH. OBSHCH. XIMII, 59,(1989) N, S. 2129-2131
  作者：POMAHEHKO, V. D.、RUBAN, A. V.、REJTEL, G. V.、POVOLOTSKIJ, M. I.、MARKOVSKIJ+

  DOI：——

  日期：——
• MARKOVSKIJ, L. N.;ROMANENKO, V. D.;RUBAN, A. V.;DRAPAJLO, A. B.;REJTEL, G+, ZH. OBSHCH. XIMII , 60,(1990) N1, S. 2453-2462
  作者：MARKOVSKIJ, L. N.、ROMANENKO, V. D.、RUBAN, A. V.、DRAPAJLO, A. B.、REJTEL, G+

  DOI：——

  日期：——