N-(4-methoxyphenyl)-N-[4-[4-(N-(4-methoxyphenyl)-4-methylanilino)phenyl]phenyl]-4-methylaniline | 122527-64-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(4-methoxyphenyl)-N-[4-[4-(N-(4-methoxyphenyl)-4-methylanilino)phenyl]phenyl]-4-methylaniline
• CAS: 122527-64-4
• 化学式: C₄₀H₃₆N₂O₂
• 分子量: 576.738
• InChiKey: GHWVBHUAVLCMTD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.7
• 重原子数：
  44
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  双三甲基硅氧基甲基硅烷 、 N-(4-methoxyphenyl)-N-[4-[4-(N-(4-methoxyphenyl)-4-methylanilino)phenyl]phenyl]-4-methylaniline 在 三(五氟苯基)硼烷 作用下， 以 甲苯 为溶剂， 以69%的产率得到4-methyl-N-[4-[methyl-bis(trimethylsilyloxy)silyl]oxyphenyl]-N-[4-[4-(4-methyl-N-[4-[methyl-bis(trimethylsilyloxy)silyl]oxyphenyl]anilino)phenyl]phenyl]aniline
  参考文献：
  名称：

  Liquid Triarylamines: The Scope and Limitations of Piers–Rubinsztajn Conditions for Obtaining Triarylamine–Siloxane Hybrid Materials

  摘要：

  New liquid triarylamine-siloxane hybrid materials are produced using the Piers-Rubinsztajn reaction. Under mild conditions, liquid analogues of conventional and commonly crystalline triarylamines are easily synthesized from readily available or accessible intermediates. Using a diverse selection of triarylamines, we explored the effects of siloxane group and substitution pattern on the physical properties of these materials, and we have demonstrated that relatively large molecular liquids with desirable electrochemical properties can be produced. The interactions between the strongly Lewis acidic catalyst used for this transformation, tris(pentafluorophenyl)borane (BCF), and the Lewis basic triarylamine substrates were studied. Through UV-vis-NIR and F-19 NMR spectroscopy, we have proposed that the catalyst undergoes a reversible redox reaction with the substrates to produce a charge transfer complex. The formation of this charge transfer complex is sensitive to the oxidation potential of the triarylamine and can greatly affect the kinetics of the Piers-Rubinsztajn reaction.

  DOI：

  10.1021/jo2020906
• 作为产物：
  描述：

  乙烷,三氯氟- 在 三叔丁基膦 、 palladium diacetate 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 4.0h， 生成 N-(4-methoxyphenyl)-N-[4-[4-(N-(4-methoxyphenyl)-4-methylanilino)phenyl]phenyl]-4-methylaniline
  参考文献：
  名称：

  Liquid Triarylamines: The Scope and Limitations of Piers–Rubinsztajn Conditions for Obtaining Triarylamine–Siloxane Hybrid Materials

  摘要：

  New liquid triarylamine-siloxane hybrid materials are produced using the Piers-Rubinsztajn reaction. Under mild conditions, liquid analogues of conventional and commonly crystalline triarylamines are easily synthesized from readily available or accessible intermediates. Using a diverse selection of triarylamines, we explored the effects of siloxane group and substitution pattern on the physical properties of these materials, and we have demonstrated that relatively large molecular liquids with desirable electrochemical properties can be produced. The interactions between the strongly Lewis acidic catalyst used for this transformation, tris(pentafluorophenyl)borane (BCF), and the Lewis basic triarylamine substrates were studied. Through UV-vis-NIR and F-19 NMR spectroscopy, we have proposed that the catalyst undergoes a reversible redox reaction with the substrates to produce a charge transfer complex. The formation of this charge transfer complex is sensitive to the oxidation potential of the triarylamine and can greatly affect the kinetics of the Piers-Rubinsztajn reaction.

  DOI：

  10.1021/jo2020906

文献信息

• Organic electroluminescent polymer having 9,9-di(fluorenyl)-2,7-fluorenyl unit and organic electroluminescent device manufactured using the same
  申请人：You Hong

  公开号：US20070093643A1

  公开（公告）日：2007-04-26

  Disclosed herein is an organic electroluminescent polymer having 9,9-di(fluorenyl)-2,7-fluorenyl unit and an electroluminescent device using the same. Specifically, the current invention provides an organic electroluminescent polymer having 9,9-di(fluorenyl)-2,7-fluorenyl unit, which can be used as a blue electroluminescent polymer and host material by introducing the substituted fluorenyl group at the 9-position of fluorene, and an electroluminescent device using the electroluminescent polymer. The electroluminescent polymer is applicable as a host material for highly pure blue, green and red, having high solubility, high heat stability and high quantum efficiency.

  本文公开了一种具有9,9-二(芴基)-2,7-芴基单元的有机电致发光聚合物及其使用的电致发光装置。具体来说，本发明提供了一种具有9,9-二(芴基)-2,7-芴基单元的有机电致发光聚合物，通过在芴的9位引入取代芴基团，可用作蓝色电致发光聚合物和主体材料，并提供使用该电致发光聚合物的电致发光装置。该电致发光聚合物可作为高纯度蓝、绿和红的主体材料，具有高溶解度、高热稳定性和高量子效率。
• ELECTROCHROMIC ELEMENT
  申请人：Ricoh Company, Ltd.

  公开号：EP3889130A1

  公开（公告）日：2021-10-06

  An electrochromic element including a first electrode, a second electrode facing the first electrode with gap, an electrolyte layer between the first and second electrodes, and a layer including a compound represented by General Formula (1) where the layer is on or above the first electrode, where R1 to R4 are each a monovalent organic group wherein no hydrogen atom is at a benzyl site where the monovalent group may include a polymerizable functional group; and R5 to R28 are each a hydrogen atom, alkyl or alkoxy group where R25 and R28, or R26 and R27 may be bonded to form a structure represented by General Formula (2), where R29 and R30 are each an alkyl, alkoxy or aryl group, and R29 and R30 may be bonded via a common bond to form a cyclic structure when R29 and R30 are aryl groups.

  一种电致变色元件，包括一个第一电极、一个面对第一电极并带有间隙的第二电极、一个位于第一和第二电极之间的电解质层，以及一个包括通式（1）所代表的化合物的层，其中该层位于第一电极上或其上方、 其中 R1 至 R4 各为单价有机基团，其中没有氢原子位于苄基位点，单价基团可包括可聚合官能团；R5 至 R28 各为氢原子、烷基或烷氧基，其中 R25 和 R28 或 R26 和 R27 可键合形成通式（2）表示的结构、 其中 R29 和 R30 各为烷基、烷氧基或芳基，当 R29 和 R30 为芳基时，R29 和 R30 可通过共键结合形成环状结构。
• Electrochromic compound, electrochromic composition, and electrochromic element
  申请人：RICOH COMPANY, LTD.

  公开号：US11370963B2

  公开（公告）日：2022-06-28

  An electrochromic compound having a structure represented by the following general formula (1): where each of X1 to X3 independently represents a carbon atom or a silicon atom, and each of R1 to R15 independently represents a member selected from the group consisting of a hydrogen atom, a halogen atom, a monovalent organic group, and a polymerizable functional group.

  具有以下通式（1）所代表结构的电致变色化合物： 其中 X1 至 X3 各自独立地代表一个碳原子或硅原子，R1 至 R15 各自独立地代表一个选自氢原子、卤素原子、一价有机基团和可聚合官能团组成的组的成员。
• POLYMER COMPOUND, NET-LIKE POLYMER COMPOUND PRODUCED BY CROSSLINKING THE POLYMER COMPOUND, COMPOSITION FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC EL DISPLAY, AND ORGANIC EL LIGHTING
  申请人：Iida Koichiro

  公开号：US20110108814A1

  公开（公告）日：2011-05-12

  An object of the invention is to provide a polymer compound having a high hole transport capacity, excellent in electrochemical stability, and suitable to film formation according to a wet film formation method. Another object of the invention is to provide an organic electroluminescence element having a high current efficiency, a low drive voltage, and a long derive lifetime. The polymer compound has a crosslinking group bonding to the arylamine moiety in the repeating unit via at least one single bond therebetween.
• ELECTROCHROMIC COMPOUND, ELECTROCHROMIC COMPOSITION, AND ELECTROCHROMIC ELEMENT
  申请人：GOTO Daisuke

  公开号：US20210198564A1

  公开（公告）日：2021-07-01

  An electrochromic compound having a structure represented by the following general formula (1):where each of X 1 to X 3 independently represents a carbon atom or a silicon atom, and each of R 1 to R 15 independently represents a member selected from the group consisting of a hydrogen atom, a halogen atom, a monovalent organic group, and a polymerizable functional group.